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Angewandte Chemie International Edition in English
Volumn 33, Issue 8, 1994, Pages 891-893
Electrostatic Activation of Hypervalent Organo‐Iodine Compounds: Bis(onio)‐Substituted Aryliodine(III) Salts
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Indexed keywords

EID: 33748224483     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199408911     Document Type: Article
Times cited : (74)
References (32)
  • 23
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    • Diplomarbeit, Universität Erlangen‐Nürnberg, 1992.
    • Seubert, J.1
  • 24
    • 84989594705 scopus 로고    scopus 로고
    • 3).
  • 25
    • 84989586286 scopus 로고    scopus 로고
    • The redox potentials of the other compounds are of the same order of magnitude. Due to the irreversibility of the acceptance of an electron, no precise value can be expected. A quantitative comparison of the values is thus not possible.
  • 26
    • 84989589310 scopus 로고
    • Methoden Org. Chem. (Houben‐Weyl) 4th edition 1952–, Bd V/2a
    • (1977) , pp. 188-193
    • Jäger, V.1    Viehe, H.G.2
  • 27
    • 84989589308 scopus 로고    scopus 로고
    • Thus, for example, a complex mixture of substances was obtained from the reaction of 3 with 11 a after several hours. In addition to small amounts of product 13a, large quantities of the starting material 3, and an as yet unidentified diazo compound were isolated.
  • 31
    • 84989586247 scopus 로고    scopus 로고
    • The yields were not optimized.
  • 32
    • 84989586245 scopus 로고    scopus 로고
    • In preliminary experiments electron‐deficient hydroquinones, for example o‐and p‐tetrachlorohydroquinone and even 2,3‐dichloro‐5,6‐dicyano‐1,4‐hydroquinone could be oxidized to the corresponding quinones. In reactions with activated arenes (e. g. anisole) under mild conditions (room temperature) the corresponding diaryliodonium systems were obtained.

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