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Volumn 34, Issue 13-14, 1995, Pages 1508-1510

Synthesis and X‐Ray Powder Structure of a Novel Porous Uranyl Phenylphosphonate Containing Unidimensional Channels Flanked by Hydrophobic Regions

Author keywords

microporosity; phosphonates; structure elucidation; uranyl phenylphosphonates

Indexed keywords


EID: 33748221955     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199515081     Document Type: Article
Times cited : (124)

References (20)
  • 15
    • 84989540468 scopus 로고    scopus 로고
    • 5OH consist of linear chains. Structural studies on two orthorhombic phases are also in progress.
  • 18
    • 84989500967 scopus 로고    scopus 로고
    • exp = 0.04. (see ref. [13] for definations).
  • 20
    • 84989524804 scopus 로고    scopus 로고
    • The phenyl rings are grouped about the sixfold axes, in such a way that three rings are in one plane (at z = 0) and the other three at a plane with z = 1/2 and vice versa. For a given phenyl group, there are two nearest neighboring phenyl groups, both at a plane shifted half along the c axis. The interactions between the groups from the same channel involve C2 and C3 atoms (C2–C2′ 3.78, C3–C3′ 3.9 Å), while that between neighboring channels involve C4 and C5 atoms (C4–C4′ 3.5, C5–C5′ 3.6, C4–C5′ 3.8, and C5–C4′ 3.8 Å). The C6 atoms of the adjacent phenyl rings are separated further apart to accommodate one of the uranyl oxygen atoms O1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.