Environmental significance of the diclofop-methyl and cyclodextrin inclusion complexes

Journal of Environmental Science and Health - Part B Pesticides, Food Contaminants, and Agricultural Wastes

Volumn 41, Issue 7, 2006, Pages 1115-1129

  Cai, Xiyun ^a   Zhang, Anping ^a   Liu, Weiping ^a  

^a ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Complexation; Cyclodextrins; Diclofop methyl; Hydrolysis; Solubility; Stability

Indexed keywords

ELECTRIC EXCITATION; ENVIRONMENTAL ENGINEERING; FLUORESCENCE; HERBICIDES; HYDROLYSIS; HYDROPHOBICITY; SOLUBILITY; STABILITY; ULTRAVIOLET RADIATION;

CYCLODEXTRINS; DICLOFOP-METHYL; FLUORESCENCE EXCITATION; ULTRA VIOLET (UV) ABSORPTION;

ORGANIC COMPOUNDS;

CYCLODEXTRIN; DEUTERIUM; DICLOFOP METHYL; HERBICIDE; PROPIONIC ACID DERIVATIVE; UNCLASSIFIED DRUG; WATER;

DEUTERIUM; FLUORESCENCE; HERBICIDE; HYDROLYSIS; HYDROPHOBICITY; ULTRAVIOLET RADIATION;

ARTICLE; BIOREMEDIATION; COMPLEX FORMATION; ENVIRONMENTAL IMPACT ASSESSMENT; FLUORESCENCE; HYDROLYSIS; HYDROPHILICITY; HYDROPHOBICITY; POLLUTION CONTROL; REACTION ANALYSIS; SOLUBILITY; ULTRAVIOLET SPECTROSCOPY;

ADSORPTION; BETA-CYCLODEXTRINS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; ENVIRONMENT; HERBICIDES; HYDROLYSIS; PHENYL ETHERS; SOIL; SOLUBILITY; SPECTROMETRY, FLUORESCENCE; ULTRAVIOLET RAYS;

EID: 33747745874     PISSN: 03601234     EISSN: 15324109     Source Type: Journal    
DOI: 10.1080/03601230600851216     Document Type: Article

References (25)

1. Petit, F.; Goff, L.G.; Cravede, J.P.; Valotaire, Y.; Pakdel, F. J. Mol. Endocrinol 1997, 19, 321-335.
2. Zhang, W.; Li, X.; Wang, C. Application Handbook of New Pesticides; Chinese Forestry Press: Beijing, 2000.
3. Saenger, W.; Jacob, J.; Gessler, K.; Steiner, T.; Hoffmann, D.; Sanbe, H.; Koizumi, K.; Smith, S.M.; Takaha, T. Structures of the common cyclodextrins and their larger analogues-beyond the doughnut. Chem. Rev 1998, 98, 1787-1802.
4. Duchêne, D. Cyclodextrin and their industrial uses; De Sańet: Paris, 1987.
5. Szejtli, J.; Tetenyi, P.; Kiniczky, M.; Bernath, J.; Teneyi nee Erdosi, M.; Dobos, E.; Bank nee Elod, E. Process for enhancing the activity of plant protecting agents by using cyclodextrin. USDA 4923853, 1990.
6. Koontz, J.L.; Marcy, J.E. Formation of natamycin: Cyclodextrin inclusion complexes and their characterization. J. Agric. Food Chem 2003, 51, 7106-7110.
7. Crini, G.; Morcellet, M. Syntheses and applications of adsorbents containing cyclodextrins. J. Sep. Sci 2002, 25, 789-813.
8. Gao, P.P.; Lu, G.Y. Preparation of Partially Methylated β-Cyclodextrin. Chin. J. Pharmace 1995, 26, 105-106.
9. Gao, S.X.; Wang, L.S.; Huang, Q.G. Synthesis of Carboxymethyl-β- Cyclodextrin and Its Solubilization on Halogenated Aromatic Hydrocarbons. Chin. Environ. Chem 1999, 18, 131-135.
10. Hao, A.Y.; Tong, L.H.; Zhang, F.S.; Jin, D.S. Preparation and NMR Spectra Studies of Mono 2-O-(2-Hydroxypropyl)-β-Cyclodextrin [Mono (2-HP-β-CD)] as a Solubilizing Agent For Hydrophobic Molecules. Chin. Syn. Chem 1995, 3, 369-371.
11. Shen, B.J.; Tong, L.H.; Zhang, H.W.; Jin, D.S. Regioselective Sulfonation of a C-2 Hydroxyl Group of β-Cyclodextrin. Chin. Org. Chem 1991, 11, 265-268
12. Smith, A.E. Esterification of the hydrolysis product of the herbicide Diclofopmethyl in methanol. J. Agric. Food Chem 1976, 24, 1077-1078.
13. Higuchi, T.; Connors, K.A. Phase-solubility techniques. Adv. Anal. Chem. Instrum 1965, 4, 117-212.
14. 2 type phase solubility diagrams, complex formation and chemical speciation of soluble species. J. Inclusion Phenom. Mol. Recognit. Chem 1998, 31, 243-264.
15. Szejtli, J. Cyclodextrins; Elsevier Science: Amsterdam, 1996.
16. Green, A.R.; Guillory, J.K. Heptakis(2,6-di-O-methyl)-β-cyclodextrin complexation with antitumor agent chlorambucil. J. Pharm. Sci 1989, 78, 427-431.
17. Abou-Hamdan, A.; Bugnon, P.; Saudan, C.; Lye, P.G.; Merbach, A.E. High-pressure studies as a novel approach in determining inclusion mechanisms: thermodynamics and kinetics of the host-guest interactions for α-cyclodextrin complexes. J. Am. Chem. Soc 2000, 122, 592-602.
18. Gazpio, C.; Sánchez, M.; Zornoza, A.; Martín, C.; Vélaz, I. A fluorimetric study of pindolol and its complexes with cyclodextrins. Talanta 2003, 60, 477-482.
19. Bender, M.L.; Komiyama, M. Cyclodextrin Chemistry; Springer Verlag: Berlin, 1978.
20. Szejtli, J. Cyclodextrins and their inclusion complexes; Akademiai Kiaco: Budapest, 1982.
21. Wade, D. Deuterium isotope effects on noncovalent interactions between molecules. Chemico-Biological Interactions 1999, 117, 191-217.
22. Manunza, B.; Deiana, S.; Pintore, M.; Delou, G.; Gessa, C. A molecular dynamics investigation on the inclusion of chiral agrochemical molecules in β-cyclodextrin complexes with dichlorprop, 2-phenoxypropionic acid and dioxabenzofos. Pestic. Sci 1998, 54, 68-74.
23. Campodonico, P.; Santos, J.G.; Andres, J.; Contreras, R. Relationship between nucleophilicity/electrophilicity indices and reaction mechanisms for the nucleophilic substitution reactions of carbonyl compounds. J. Phys. Org. Chem 2004, 17, 273-281.
24. Komiyama, M.; Bender, M.L. Effect of phenyl substituents on the hydrolysis of trifluoroacetanilides catalyzed by imidazolyl cation and hydroxide ion. J. Am. Chem. Soc 1978, 100, 4576-4579.
25. Fernández, M.A.; de Rossi, R.H. Changing mechanism in the β-cyclodextrin-mediated hydrolysis of phenyl esters of perfluoroalkanoic acids. J. Org. Chem 2003, 68, 6887-6893.