An improved oxidative cleavage method for large scale preparation of some acid-labile aglycones from glycosides

Journal of the Chinese Chemical Society

Volumn 49, Issue 1, 2002, Pages 103-106

  Wang, Perng Haur ^a   Jou, Sheng Jye ^a   Chen, Wen Chuan ^a   Lee, Shoei Sheng ^a  

^a NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

Acid labile aglycones; Cycloastragenol; Jujubogenin; Large scale preparation; Oxidative cleavage; Strongly basic and anhydrous conditions

Indexed keywords

EID: 33747676823     PISSN: 00094536     EISSN: None     Source Type: Journal    
DOI: 10.1002/jccs.200200017     Document Type: Article

References (11)

1. Takino, Y. Yakugaku Zasshi 1994, 114, 550-564.
2. Hasegawa, H.; Sung, J.-H.; Matsumiya, S.; Uchiyama, M. Planta Medica 1996, 62, 453-457.
3. Matsuura, H.; Kasai, R.; Tanaka, O.; Saruwatari, Y-I.; Fuwa, T.; Zhou, J. Chem. Pharm. Bull. 1983, 31, 2281-2287.
4. Shibata, S.; Tanaka, O.; Ando, T.; Sado, M.; Tsushima, S.; Ohsawa, T. Chem. Pharm. Bull. 1966, 14, 595-600.
5. Kitagawa, I.; Wang, H. K.; Takagi, A.; Fuchida, M.; Miura, I.; Yoshikawa, M. Chem. Pharm. Bull. 1983, 31, 689-697.
6. Kawai, K. I.; Akiyama, T.; Ogihara, Y.; Shibata, S. Phytochemistry 1974, 13, 2829-2832.
7. Cui, J. F.; Bystrom, S.; Eneroth, P.; Björkhem, I. J. Org. Chem. 1994, 59, 8251-8255.
8. Wagner, H.; Ott, S.; Jurcic, K.; Morton, J.; Neszmelyi, A. Planta Medica 1983, 48, 136-141.
9. Lee, S. S.; Chen, W.-C.; Chen, C.-H. J. Nat. Prod. 2000, 63, 1580-1583.
10. Asakawa, J.; Kasai, R.; Yamasaki, K.; Tanaka, O. Tetrahedron 1977, 33, 1935-1939, and references cited therein.
11. Fujioka, N.; Kohda, H.; Yamasaki, K.; Kasai, R.; Tanaka, O.; Shoyama, Y.; Nishioka, I. Phytochemistry 1989, 28, 1855-1858, and references cited therein.