Formation of unexpected selenium-rich compounds by selenation of the very bulky (PhMe2Si)3CLi: s-Tetraselenane, a novel polyseleno heterocycle

European Journal of Inorganic Chemistry

Volumn , Issue 15, 2006, Pages 2937-2941

  Klapötke, Thomas M ^a   Krumm, Burkhard ^a   Polborn, Kurt ^a   Scherr, Matthias ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Bulky substituents; DFT calculations; Selenium; Structure elucidation

Indexed keywords

CRYSTAL STRUCTURE; SILICON;

BULKY SUBSTITUENTS; CRYSTALS STRUCTURES; DFT CALCULATION; ELEMENTAL SELENIUM; HETEROCYCLES; SELENATION; SPECTROSCOPIC DATA; STRUCTURE ELUCIDATION;

SELENIUM COMPOUNDS;

EID: 33747484933     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200600497     Document Type: Article

References (25)

1. a) C. Eaborn, J. D. Smith, J. Chem. Soc. Dalton Trans. 2001, 1541-1552;
2. b) P. P. Power, J. Organomet. Chem. 2004, 689, 3904-3919.
3. M. Ostrowski, J. Jeske, P. G. Jones, W.-W. Du Mont, Chem. Ber. 1993, 126, 1355-1359.
4. F. Sladky, B. Bildstein, C. Rieker, A. Gieren, H. Betz, T. Hübner, J. Chem. Soc. Chem. Commun. 1985, 1800-1801.
5. I. Wagner, W.-W. Du Mont, S. Pohl, W. Saak, Chem. Ber. 1990, 123, 2325-2327.
6. M. Ostrowski, I. Wagner, W.-W. Du Mont, P. G. Jones, J. Jeske, Z. Anorg. Allg. Chem. 1993, 619, 1693-1698.
7. a) K. Giselbrecht, B. Bildstein, F. Sladky, Chem. Ber. 1989, 122, 4255-1256;
8. b) W. Fimml, F. Sladky, Chem. Ber. 1991, 124, 1131-1133.
9. T. M. Klapötke, B. Krumm, H. Nöth, J. C. Galvez-Ruiz, K. Polborn, I. Schwab, M. Suter, Inorg. Chem. 2005, 44, 5254-5265.
10. T. M. Klapötke, B. Krumm, K. Polborn, J. Am. Chem. Soc. 2004, 126, 710-711.
11. H. Eggert, O. Nielsen, L. Henriksen, J. Am. Chem. Soc. 1986, 108, 1725-1730.
12. F. Hansen, L. Henriksen, S. Larsen, L. Teuber, Acta Chem. Scand. 1989, 43, 450-457.
13. T. M. Klapötke, B. Krumm, P. Mayer, Z. Naturforsch. Teil B 2004, 59, 547-553.
14. B. J. McKinnon, P. De Mayo, N. C. Payne, B. Ruge, New J. Chem. 1978, 2, 91-94.
15. C. H. Bushweller, G. Bhat, L. J. Letendre, J. A. Brunelle, H. W. Bilofsky, H. Ruben, D. H. Templeton, A. Zalkin, J. Am. Chem. Soc. 1975, 97, 65-73.
16. J. D. Korp, I. Bernal, S. F. Watkins, F. R. Fronczek, Tetrahedron Lett. 1981, 22, 4767-4770.
17. a) T. G. Back, P. W. Codding, Can. J. Chem. 1983, 61, 2749-2752;
18. b) J. Jeske, A. Martens-Von Salzen, W.-W. Du Mont, P. G. Jones, Acta Crystallogr. Sect. C 1998, 54, 1873-1875;
19. c) T. M. Klapötke, B. Krumm, P. Mayer, H. Piotrowski, K. Polborn, J. Fluorine Chem. 2003, 123, 133-138.
20. a) N. L. Allinger, M. J. Hickey, J. Kao, J. Am. Chem. Soc. 1976, 98, 2741-2745;
21. b) R. Susilo, R. Gmelin, K. Roth, H. Bauer, Z. Naturforsch. Teil B 1982, 37, 234-235.
22. F. J. Berry, B. C. Smith, C. H. W. Jones, J. Organomet. Chem. 1976, 110, 201-203.
23. R. Lehnert, A. Porzel, K. Rühlmann, Z. Chem. 1988, 5, 190-192.
24. S. S. Al-Juaid, C. Eaborn, A. Habtemariam, P. B. Hitchcock, J. D. Smith, K. Tavakkoli, A. D. Webb, J. Organomet. Chem. 1993, 462, 45-55.
25. G. M. Sheldrick, University of Göttingen, Germany, 1997.