Isolation and characterization of the chelate exo-nido-ruthenacarborane intermediates formed in the thermal exo-nido-to-closo conversion of [exo-nido-5,6,10-{Cl(Ph3P)2Ru}-5,6,10-(μ-H) 3-10-H-7,8-R2-7,8-C2B9H6] (R = H or Me) upon the triphenylphosphine ligand displacement

Journal of Organometallic Chemistry

Volumn 691, Issue 19, 2006, Pages 3989-3996

  Cheredilin, Dmitri N ^a   Dolgushin, Fedor M ^a   Korlyukov, Alexander A ^a   Godovikov, Ivan A ^a   Kadyrov, Renat ^b   Balagurova, Elena V ^a   Solodovnikov, Stanislav P ^a   Chizhevsky, Igor T ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b EVONIK INDUSTRIES AG   (Germany)

Author keywords

CD spectroscopy; Chirality; Crystal structures; EPR spectroscopy; exo nido to closo conversion; Metallacarborane clusters; NMR spectroscopy; Paramagnetic closo ruthenacarboranes

Indexed keywords

CHELATION; CRYSTAL STRUCTURE; ISOMERS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAFFINS; PARAMAGNETIC MATERIALS; PARAMAGNETIC RESONANCE; THERMAL EFFECTS; X RAY DIFFRACTION;

CD SPECTROSCOPY; CHIRALITY; EXO-NIDO-TO-CLOSO CONVERSION; METALLACARBORANE CLUSTERS; PARAMAGNETIC CLOSO-RUTHENACARBORANES;

BORATE MINERALS;

EID: 33747201144     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.05.051     Document Type: Article

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