Ion and polymer dynamics in polymer electrolytes PPO-LiClO4. I. Insights from NMR line-shape analysis

Journal of Chemical Physics

Volumn 125, Issue 5, 2006, Pages

  Vogel, M ^a   Torbrugge T ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ANGLE MEASUREMENT; CONCENTRATION (PROCESS); IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SODIUM CHLORIDE; THERMAL EFFECTS;

DYNAMICAL HETEROGENEITIES; ECHO-PULSE SEQUENCE; POLYMER DYNAMICS; POLYMER ELECTROLYTES;

POLYELECTROLYTES;

EID: 33746904774     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2217945     Document Type: Article

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52. To determine the weighting factor W(T) we fit the central region [-15 kHz; +15 kHz] of the spectrum to a Lorentzian line on top of a curved base line, where the latter is meant to represent the spectral intensity resulting from the rigid-lattice spectrum. Furthermore, we calculate the total spectral intensity by integration of the experimental spectrum. Then, W(T) is the contribution of the intensity of the Lorentzian to the total spectral intensity. Due to the presence of different deuteron species, this approach allowed us to obtain more accurate results for W(T) than fitting of the whole spectrum with a superposition of line shapes.
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