Onsager reciprocal relations for Stefan-Maxwell diffusion

Industrial and Engineering Chemistry Research

Volumn 45, Issue 15, 2006, Pages 5361-5367

  Monroe, Charles W ^a,b   Newman, John ^a  

^a University of California   (United States)

^b IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

FLUCTUATION THEORY; ISOBARIC MASS DIFFUSION; MOLE FRACTION; STEFAN-MAXWELL COEFFICIENTS;

CONCENTRATION (PROCESS); ENTROPY; MASS TRANSFER; SOLUTIONS;

DIFFUSION;

CONCENTRATION (PROCESS); DIFFUSION; ENTROPY; MASS TRANSFER; SOLUTIONS;

EID: 33746862986     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie051061e     Document Type: Article

References (19)

1. Onsager, L. Reciprocal Relations in Irreversible Processes I. Phys. Rev. 1930, 37, 405-426.
2. Onsager, L. Reciprocal Relations in Irreversible Processes II. Phys. Rev. 1931, 38, 2265-2279.
3. Landau, L. D.; Lifschitz, E. M. Statistical Physics, Part 1, 3rd ed.; Pergamon Press: Oxford, U.K., 1980; p 365.
4. de Groot, S. R. Thermodynamics of Irreversible Processes; Interscience Publishers: New York, 1951; p 7.
5. Callen, H. B. Thermodynamics and an Introduction to Thermostatistics, 2nd ed.; John Wiley and Sons: New York, 1985; p 309.
6. Coleman, B. D.; Truesdell, C. A. On the Reciprocal Relations of Onsager. J. Chem. Phys. 1960, 33, 28-31.
7. Chapman, S.; Cowling, T. G. The Mathematical Theory of Nonuniform Gases, 2nd ed.; Cambridge University Press: Cambridge, U.K., 1964; Chapter 9.
8. Curtiss, C. F.; Hirschfelder, J. O. Transport Properties of Multicomponent Gas Mixtures. J. Chem. Phys. 1949, 17, 550-555.
9. Curtiss, C. F.; Bird, R. B. Multicomponent Diffusion. Ind. Eng. Chem. Res. 1999, 38, 2515-2522.
10. Onsager, L. Theories and Problems of Liquid Diffusion. Ann. N.Y. Acad. Sci 1945, 46, 241-265.
11. Lightfoot, E. N.; Cussler, E. L.; Rettig, R. L. Applicability of the Stefan-Maxwell Equations to Multicomponent Diffusion in Liquids. AIChE J. 1962, 8, 708-710.
12. Chapman, T. W. The Transport Properties of Concentrated Electrolytic Solutions. Ph.D. Thesis, University of California, Berkeley, CA, 1967; p 99.
13. Newman, J.: Chapman, T. W. Restricted Diffusion in Binary Solutions. AIChE J. 1973, 19, 343-348.
14. Diffusion Coefficient. In International Encyclopedia of Heat and Mass Transfer, Hewitt, G. F., Shires, G. L., Polezhaev, Y. V., Eds.; CRC Press: Boca Raton, FL, 1997; p 306.
15. Rossini, F. D., Ed. Selected Values of Physical and Thermodynamic Properties of Hydrocarbons and Related Compounds: American Petroleum Institute Research Project 44; Carnegie Press: Pittsburgh, PA, 1953; pp 162 and 226.
16. Tolman, R. C. The Principles of Statistical Mechanics; Oxford University Press: Oxford, U.K., 1962; p 48.
17. Jarzynski, C. Nonequilibrium Equality for Free Energy Differences. Phys. Rev. Lett. 1997, 78, 2690-2693.
18. Miller, D. G. Thermodynamics of Irreversible Processes: The Experimental Verification of the Onsager Reciprocal Relations. Chem. Rev. 1960, 60, 15-37.
19. Wheeler, D. R.; Newman, J. Molecular Simulations of Multicomponent Diffusion. 1. Equilibrium Method. J. Phys. Chem. B 2004, 108. 18353-18361.