Structure and ionic conductivity of porous polymer electrolytes based on PVDF-HFP copolymer membranes

Journal of Membrane Science

Volumn 281, Issue 1-2, 2006, Pages 446-453

  Cao, Jian Hua ^a   Zhu, Bao Ku ^a   Xu, You Yi ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Microporous membrane; Poly(vinylidene fluoride co hexafluoropropylene); Polymer electrolyte; Polyvinylpyrrolidone

Indexed keywords

GELS; IONIC CONDUCTION; MORPHOLOGY; OLEFINS; POLYELECTROLYTES; SOLVENTS;

MICROPOROUS MEMBRANE; POLYMER ELECTROLYTE; POLYVINYLIDENE FLUORIDE-CO-HEXAFLUOROPROPYLENE; POLYVINYLPYRROLIDONE;

POLYMERIC MEMBRANES;

ELECTROLYTE; LITHIUM; MACROGOL 200; PHTHALIC ACID DIBUTYL ESTER; POLY(VINYLIDENE FLUORIDE CO HEXAFLUOROPROPYLENE); POLYMER; POVIDONE; PROPYLENE; SOLVENT; UNCLASSIFIED DRUG;

GELS; IONIC CONDUCTION; MORPHOLOGY; OLEFINS; POLYELECTROLYTES; POLYMERIC MEMBRANES; SOLVENTS;

ARTICLE; CHEMICAL PROCEDURES; CHEMICAL STRUCTURE; CONDUCTANCE; CRYSTAL STRUCTURE; ELECTROLYTE TRANSPORT; GEL; IMPEDANCE; ION TRANSPORT; LIQUID; MEASUREMENT; MECHANICS; MEMBRANE POTENTIAL; MEMBRANE STRUCTURE; MORPHOLOGY; PHYSICAL CHEMISTRY; POROSITY; PRIORITY JOURNAL; STRENGTH; TEMPERATURE;

EID: 33746854608     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2006.04.013     Document Type: Article

References (35)

1. Magistris A., Mustarelli P., Quartarone E., Piaggio P., and Bottino A. Poly(vinylidene fluoride) based porous polymer electrolytes. Electrochim. Acta 46 (2001) 1635
2. Kim D.W., and Sun Y.K. Electrochemical characterization of gel polymer electrolytes prepared with porous membranes. J. Power Sources 102 (2001) 41
3. Zhang S.S., Ervin M.H., Xu K., and Jow T.R. Microporous poly(acrylonitrile-methacrylate) membrane as a separator of rechargeable lithium battery. Electrochim. Acta 49 (2004) 3339
4. Abraham K.M., and Jiang Z. PEO-like polymer electrolytes with high room temperature conductivity. J. Electrochem. Soc. 144 (1997) L136
5. 3. Electrochim. Acta 50 (2004) 289
6. Appetecchi G.B., Croce F., and Scrosati B. Kinetics and stability of the lithium electrode in poly(methylmethacrylate)-based gel electrolytes. Electrochim. Acta 40 (1995) 991
7. Tsuchida E., Ohno H., and Tsunemi K. Conduction of lithium ions in polyvinylidene fluoride and its derivatives, I. Electrochim. Acta 28 (1983) 591
8. Wang H.P., Huang H.T., and Stephanie L.W. Novel microporous poly(vinylidene fluoride) blend electrolytes for lithium-ion batteries. J. Electrochem. Soc. 147 (2000) 2853
9. Jiang Z., Carroll B., and Abraham K.M. Studies of some poly(vinylidene fluoride) electrolytes. Electrochim. Acta 42 (1997) 2667
10. 2. Solid State Ionics 131 (2000) 291
11. Lee C., Kim J.H., and Bae J.Y. Polymer gel electrolytes prepared by thermal curing of poly(vinylidene fluoride)-hexafluoropropene/poly(ethylene glycol)/propylene carbonate/lithium perchlorate blends. Polymer 44 (2003) 7143
12. Shi Q., Yu M.X., Zhou X., Yan Y.S., and Wan C.R. Structure and performance of porous polymer electrolytes based on P(VDF-HFP) for lithium ion batteries. J. Power Sources 103 (2002) 286
13. 4 polymer gel electrolytes. Electrochim. Acta 49 (2004) 2541
14. Michot T., Nishimoto A., and Watanabe M. Electrochemical properties of polymer gel electrolytes based on poly(vinylidene fluoride) copolymer and homopolymer. Electrochim. Acta 45 (2000) 1347
15. A.S. Gozdz, J.M. Tarascon, P.C. Warren, US Patent 5,418,091 (1995).
16. A.S. Gozdz, C.N. Schmutz, J.M. Tarascon, P.C. Warren, US Patent 5,540,741 (1997)
17. Arascon J.M., Gozdz A.S., Schmutz C.N., Shokooh F., and Warren P.C. Performance of Bellcore's plastic rechargeable Li-ion batteries. Solid State Ionics 86-88 (1996) 49
18. Munari S., Bottino A., and Capannelli G.V. Casting and performance of polyvinylidene fluoride based membranes. J. Membr. Sci. 16 (1983) 181
19. Cheng L.P., Lin D.J., Shin C.H., Dwan A.H., and Gryte C.C. PVDF membrane formation by diffusion-induced phase separation-morphology prediction based on phase behavior and mass transfer modeling. J. Polym. Sci. Polym. Phys. 37 (1999) 2079
20. Wang L.D., Li K., and Teo W.K. Preparation and characterization of polyvinylidene fluoride (PVDF) hollow fiber membranes. J. Membr. Sci. 163 (1999) 211
21. 4/water/DMF/PVDF system. Polymer 44 (2003) 413
22. Kim H.J., and Lee K.H. Effect of PEG additive on membrane formation by phase inversion. J. Membr. Sci. 138 (1998) 153
23. Kim J.H., Min B.R., Park H.C., Won J., and Kang Y.S. Phase behavior and morphological studies of polyimide/PVP/solvent/water systems by phase inversion. J. Appl. Polym. Sci. 81 (2001) 3481
24. Yoo S.H., Kim J.K., Jho J.Y., Won J., and Kang Y.S. Influence of the addition of PVP on the morphology of asymmetric polyimide phase inversion membranes: effect of PVP molecular weight. J. Membr. Sci. 236 (2004) 203
25. Mulder M. Basic Principles of Membrane Technology (1991), Kluwer Academic Publishers, Dordrecht, The Netherlands p. 54
26. Abraham K.M., Alamgir M., and Hoffman D.K. Polymer electrolytes reinforced by Celgard membrane. J. Electrochem. Soc. 142 (1995) 683
27. Song J.Y., Cheng C.L., Wang Y.Y., and Wan C.C. Microstructure of poly(vinylidene fluoride)-based polymer electrolyte and its effect on transport properties. J. Electrochem. Soc. 149 (2002) A1230
28. Wang Y.D., and Cakmak M. Hierarchical structure gradients development in injection-molded PVDF and PVDF-PMMA blends. I. Optical and thermal analysis. J. Appl. Polym. Sci. 68 (1998) 909
29. Tazaki M., Wada R., Okabe M., and Homma T. Crystallization and gelation of poly(vinylidene fluoride) in organic solvents. J. Appl. Polym. Sci. 65 (1997) 1517
30. Kobayashi M., Tashiro K., and Tadokoro H. Molecular vibrations of three crystal forms of poly(vinylidene fluoride). Macromolecules 8 2 (1975) 158
31. Hasegawa R., Takahashi Y., Chatani Y., and Tadokoro H. Crystal structures of three crystalline forms of poly(vinylidene fluoride). Polym. J. 3 (1972) 600
32. Abbrent S., Tegenfeldt J., Plestil J., Hlavata D., Lindgren J., and Wendsjoc A. Crystallinity and morphology of PVDF-HFP-based gel electrolytes. Polymer 42 (2001) 1407
33. Giovanni M., Puergiorgio V., Mariano P., and Francesco C. FTIR-microspectroscopy and DSC studies of poly(vinylidene fluoride). Polym. Int. 41 (1996) 35
34. Saito Y., Kataoka H., Quartarone E., and Mustarelli P. Carrier migration mechanism of physically cross-linked polymer gel electrolytes based on PVDF membranes. J. Phys. Chem. B 106 (2002) 7200
35. Huang H., and Wunder S.L. Ionic conductivity of microporous PVDF-HFP/PS polymer blends. J. Electrochem. Soc. 148 (2001) A279