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Volumn 8, Issue 14, 2006, Pages 2929-2932

Ni-catalyzed Si-B addition to 1,3-dienes: Disproportionation in lieu of silaboration

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Indexed keywords


EID: 33746602236     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol060765x     Document Type: Article
Times cited : (37)

References (32)
  • 13
    • 33746655584 scopus 로고    scopus 로고
    • note
    • 2 (5 mol %) were dissolved in toluene. DIBALH (10 mol %) was then added at -35 °C to reduce the metal. The reaction mixture was heated at 80 °C (Ni) or 110 °C (Pt) for 24 h.
  • 14
    • 33746587980 scopus 로고    scopus 로고
    • Fleming, I., Ed.; Georg Thieme Verlag: Stuttgart
    • For reviews on hydrosilylation of 1,3-dienes, see: (a) Pietruzka, J. In Science of Synthesis; Fleming, I., Ed.; Georg Thieme Verlag: Stuttgart, 2002; Vol. 4, pp 172-176.
    • (2002) Science of Synthesis , vol.4 , pp. 172-176
    • Pietruzka, J.1
  • 15
    • 33746604558 scopus 로고
    • Marciniec, B., Ed.; Pergamon: Oxford
    • (b) Comprehensive Handbook on Hydrosilylation; Marciniec, B., Ed.; Pergamon: Oxford, 1992; pp 110-114.
    • (1992) Comprehensive Handbook on Hydrosilylation , pp. 110-114
  • 16
    • 33746596357 scopus 로고
    • Patai S., Rappaport, Z., Eds.; Wiley Interscience: New York
    • (c) Ojima, I. In The Chemistry of Organic Silicon Compounds; Patai S., Rappaport, Z., Eds.; Wiley Interscience: New York 1989; Vol. 2, pp 1493-1499.
    • (1989) The Chemistry of Organic Silicon Compounds , vol.2 , pp. 1493-1499
    • Ojima, I.1
  • 19
    • 33746628724 scopus 로고    scopus 로고
    • note
    • 2,4-Hexadiene, tech., 90%, mixture of isomers. Remaining 10% is positional double bond isomers.
  • 20
    • 33746621847 scopus 로고    scopus 로고
    • note
    • As the starting 2,4-hexadiene was only 90% pure the selectivity of the reaction is most probably higher than 93:7. We were not able to separate 7 from the isomeric impurities.
  • 22
    • 33746590908 scopus 로고    scopus 로고
    • note
    • Entry 2: compounds 10 + 11 + 12 = 89%, while 11 + 12 + 13 = 53%.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.