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33748503927
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13
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33746655584
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-
note
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2 (5 mol %) were dissolved in toluene. DIBALH (10 mol %) was then added at -35 °C to reduce the metal. The reaction mixture was heated at 80 °C (Ni) or 110 °C (Pt) for 24 h.
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14
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33746587980
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Fleming, I., Ed.; Georg Thieme Verlag: Stuttgart
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16
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33746596357
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19
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33746628724
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-
note
-
2,4-Hexadiene, tech., 90%, mixture of isomers. Remaining 10% is positional double bond isomers.
-
-
-
-
20
-
-
33746621847
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-
note
-
As the starting 2,4-hexadiene was only 90% pure the selectivity of the reaction is most probably higher than 93:7. We were not able to separate 7 from the isomeric impurities.
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-
-
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22
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33746590908
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-
note
-
Entry 2: compounds 10 + 11 + 12 = 89%, while 11 + 12 + 13 = 53%.
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23
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0028097354
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