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Volumn , Issue 23, 2000, Pages 1263-1271

On the rational synthesis and properties of exchange-coupled heterotrinuclear systems containing [MAMBMB] and [MAMBMC] cores t

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Indexed keywords


EID: 33746549118     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b0057681     Document Type: Article
Times cited : (2)

References (54)
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  • 46
    • 33746561688 scopus 로고    scopus 로고
    • note
    • Using compound 1 as an example, another acceptable solution involves consideration of a small coupling between MA and Mc (<3.0 cm"1). This coupling led to a small decrease of the g values and consequent increase of the separation in the energetic levels from 40 to 52 cm"1 between the ground term |6/2;l/2) and the first excited term |4/2;l/2>. Since |./BC|= 118.6 cm'1 > 1/-41= 19.8 cm"1 > |/AC| = 3.0 cm"1 the last coupling was set to zero in order to avoid overparametrisation and to simplify comparisons among the complexes.


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