New insights into the mechanism of phenolic oxidation with phenyliodonium(in) reagents

Journal of the Chemical Society - Perkin Transactions 1

Volumn , Issue 4, 1999, Pages 379-380

  Kiirti, Lâszlô ^a,c   Herczegh, Pal ^a,b   Visy, Julia ^a,b   Simonyi, Miklös ^b,c   Antus, Sändor ^b,c   Pelter, Andrew ^a,b,c  

^a UNIVERSITY OF DEBRECEN   (Hungary)

^b INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^c SWANSEA UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33746521960     PISSN: 0300922X     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (24)

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21. The general procedure was to dissolve the phenol (5 mmol) in a mixture of dry CH2C12 (10 ml) and the alcohol (100 mmol) and add the phenyliodonium reagent (5 mmol) in dry CH2C12 (40 ml) over 5 min at room temperature. The reaction was stopped after 20 min and worked up in the usual way.
22. Chiral-AGP from Chrom Tech AB (Hägerstrom/Sweden) using 0.01 M phosphate buffer (pH = 7.0) containing 2% (or 4% v/v) propan-2-ol at 360 mm. Retention times for the two isomers of 7a were 2.8 and 5.3 min and for 7b were 11.5 and 27.5 min.
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24. H 5.60 (s, 2H), 6.80-8.00 (m, 15H).