Deoligomerization by cocomplexation: Syntheses and structures of aluminum-calcium alkoxides and aryloxides

Inorganic Chemistry

Volumn 45, Issue 14, 2006, Pages 5302-5306

  Utko, Józef ^a   Ejfler, Jolanta ^a   Szafert, Sławomir ^a   John, Łukasz ^a   Jerzykiewicz, Lucjan B ^a   Sobota, Piotr ^a  

^a UNIVERSITY OF WROC AW   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33746509851     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic051710e     Document Type: Article

References (48)

1. (a) Bradley, D. C.; Mehrotra, D. P.; Gaur, D. P. Metal Akoxides; Academic Press: New York, 1978.
2. (b) Bradley, D. C.; Mehrotra, R. C.; Rothwell, I. P.; Singh, A. Alkoxo and Aryloxo Derivatives of Metals; Academic Press: London, 2001.
3. (c) Turova, N. Ya.; Turevskaya, E. P.; Kessler, V. G.; Yanovskaya, M. I. The Chemistry of Metal Alkoxides; Kluwer: Boston, 2002.
4. (d) Herrmann, W. A.; Huber, N. W.; Runte, O. Angew. Chem., Int. Ed. Engl. 1995, 34, 2187.
5. (a) Bednorz, J. G.; Müller, K. A. Angew. Chem., Int. Ed. Engl. 1988, 27, 735.
6. (b) Hubert-Pfalzgraf, L. G. Appl. Organomet. Chem. 1992, 6, 627.
7. (a) Bradley, D. C. Chem. Rev. 1989, 89, 1317.
8. (b) Mehrotra, R. C.; Singh, A. Chem. Soc. Rev. 1996, 1.
9. (c) Singh, A.; Mehrotra, R. C. Coord. Chem. Rev. 2004, 248, 101.
10. (d) Caulton, K. G.; Hubert-Pfalzgraf, L. G. Chem. Rev. 1990, 90, 969.
11. (a) Chisholm, M. H.; Gallucci, J. C.; Phomphrai, K. Inorg. Chem. 2004, 43, 6717.
12. (b) Puelacher, W. C.; Mooney, D.; Langer, R.; Upton, J.; Vacanti, J. P.; Vacanti, C. A. Biomaterials 1994, 15, 774.
13. (c) Williams, J. M.; Adewunmi, A.; Schek, R. M.; Flanagan, C. L.; Krebsbach, P. H.; Feinberg, S. E.; Hollister, S. J.; Das, S. Biomaterials 2005, 26, 4817.
14. (d) Lin, R.; Ng, L. S.; Wang, C.-H. Biomaterials 2005, 26, 4476.
15. Gryglewicz, S. Appl. Catal. A 2000, 192, 23.
16. Rámila, A.; Balas, F.; Vallet-Regí, M. Chem. Mater. 2002, 14, 542.
17. Introduction to Organic Chemistry, 3rd ed.; Streitwieser, A., Jr., Heathcock, C. H., Eds.; Macmillan: New York, 1995.
18. (a) Hitchcock, P. B.; Lappert, M. F.; Lawless, G. A.; Royo, B. J. Chem. Soc., Chem. Commun. 1990, 1141.
19. (b) Tesh, K. F.; Hanusa, T. P.; Huffman, J. C.; Huffman, C. J. Inorg. Chem. 1992, 31, 5572.
20. (c) Tesh, K. F.; Burkey, D. J.; Hanusa, T. P. J. Am. Chem. Soc. 1994, 116, 2409.
21. (a) Turova, N. Ya.; Turevskaya, E. P.; Kessler, V. G.; Yanovsky, A. I.; Struchkov, Y. T. J. Chem. Soc., Chem. Commun. 1993, 21.
22. Goel, S. C.; Matchett, M. A.; Chiang, M. Y.; Buhro, W. E. J. Am. Chem. Soc. 1991, 113, 1844.
23. Deacon, G. B.; Forsyth, C. M.; Junk, P. C. J. Organomet. Chem. 2000, 607, 112.
24. Utko, J.; Przybylak, Sz.; Jerzykiewicz, L. B.; Szafert, S.; Sobota, P. Chem. Eur. J. 2003, 9, 181.
25. CrysAlisRED Software; Oxford Diffraction: Wrocław, Poland, 1995-2004.
26. Sheldrick, G. M. SHELXTL, ver. 5.10; Bruker AXS, Inc.: Madison, WI.
27. Cromer, D. T.; Waber, J. T. In International Tables for X-ray Crystallography; Ibers, J. A., Hamilton, W. C., Eds.; Kynoch: Birmingham, England, 1974; Vol. 4, pp 72-98, 149-150; Tables 2.2B and 2.3.1.
28. Utko, J.; Szafert, S.; Jerzykiewicz, L. B.; Sobota, P. Inorg. Chem. 2005, 44, 5194.
29. 2 was obtained as described but with the use of toluene instead of hexanes. The non-optimized yield was 81%.
30. (a) Holton, J.; Lappert, M. F.; Ballard, D. G. H.; Pearce, R.; Atwood, J. L.; Hunter, W. E. J. Chem. Soc., Dalton Tans. 1979, 54.
31. (b) Klimpel, M. G.; Eppinger, J.; Sirsch, P.; Scherer, W.; Anwander, R. Organometallics 2002, 21, 4021.
32. (c) Dietrich, H. M.; Raudaschl-Sieber, G.; Anwander, R. Angew. Chem., Int. Ed. 2005, 44, 5303.
33. Elschenbroich, C.; Salzer, A. Organometallics: A Concise Introduction, 2nd ed.; VCH Publishers: New York, 1992; p 85.
34. Fischbach, A.; Herdtweck, E.; Anwander, R.; Eickerling, G.; Scherer, W. Organometallics 2003, 22, 499.
35. Gordon, J. C.; Giesbrecht, G. R.; Brady, J. T.; Clark, D. L.; Keogh, D. W.; Scott, B. L.; Watkin, J. G. Organometallics 2002, 21, 127.
36. Giesbrecht, G. R.; Gordon, J. C.; Brady, J. T.; Clark, D. L.; Keogh, D. W.; Michalczyk, R.; Scott, B. L.; Watkin, J. G. Eur. J. Inorg. Chem. 2002, 723.
37. Bolton, P. D.; Clot, E.; Cowley, A. R.; Mountford, P. Chem. Commun. 2005, 3313.
38. Erker, G.; Albrecht, M.; Krüger, C.; Werner, S.; Binger, P.; Langhauser, F. Organometallics 1992, 11, 3517.
39. Vranka, R. G.; Amma, E. L. J. Am. Chem. Soc. 1967, 89, 3121.
40. Tanner, P. S.; Williams, R. A.; Hanusa, T. P. Inorg. Chem. 1993, 32, 2234.
41. Eaborn, C.; Hawkes, S. A.; Hitchcock, P. B.; Smith, J. D. Chem. Commun. 1997, 1961.
42. (a) Harder, S.; Feil, F.; Weeber, A. Organometallics 2001, 20, 1044.
43. (b) Harder, S.; Müller, S.; Hübner, E. Organometallics 2004, 23, 178.
44. (a) Herrmann, W. A.; Huber, N. W.; Priermeier, T. Angew. Chem., Int. Ed. Engl. 1994, 33, 105.
45. (b) Turevskaya, E. P.; Kessler, V. G.; Turova, Na. Y.; Pisarevsky, A. P.; Yanovsky, A. I.; Struchkov, Y. T. J. Chem. Soc., Chem. Commun. 1994, 2303.
46. Zerger, R.; Stucky, G. J. Organomet. Chem. 1974, 74, 7.
47. 1H NMR spectrum of PLA (see Supporting Information) shows the polymer terminated with 2-methoxyethoxy and hydroxyl groups.
48. Evans, W. J.; Boyle, T. J.; Ziller, J. W. J. Am. Chem. Soc. 1993, 115, 5084.