Synthesis and characteristics of curable siloxane-based organic-inorganic hybrid materials modified with vinyl and isopropenoxy

Journal of Materials Research

Volumn 21, Issue 5, 2006, Pages 1286-1293

  Kang, Eun Seok ^a,b   Takahashi, Masahide ^a,b   Tokuda, Yomei ^a   Yoko, Toshinobu ^a  

^a KYOTO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERIZATION; MOLECULAR STRUCTURE; MOLECULES; POLYMERIZATION; SYNTHESIS (CHEMICAL);

CURABLE ORGANIC-INORGANIC MATERIALS; DIPHENYLSILANEDIOL (DPSD); HYBRID MATERIALS; NONHYDROLYTIC REACTION; VINYLTRIIOSPROPENOXYSILANE (VTIPS);

POLYMERS;

EID: 33746496844     PISSN: 08842914     EISSN: None     Source Type: Journal    
DOI: 10.1557/jmr.2006.0144     Document Type: Article

References (21)

1. C. Sanchez, B. Lebeau, F. Chaput, and J. Boilot: Optical properties of functional hybrid organic-inorganic nanocomposites. Adv. Mater. 23, 1969 (2003).
2. A.O. Karkkainen, J.T. Rantala, A. Maaninen, G.E. Jabbour, and M.R. Desour: Siloxane-based hybrid glass materials for binary and grayscale mask photoimaging. Adv. Mater. 7, 535 (2002).
3. A. Vioux: Nonhydrolytic sol-gel routes to oxides. Chem. Mater. 9, 2292 (1997).
4. M. Mennig, M. Zahnhausen, and H. Schmidt: A novel nonhydrolytic sol-gel route to low -OH and CH-containing organic-inorganic composites, in Organic-Inorganic Hybrid Materials for Photonics, edited by G. Liliane, Hubert Pfalzgraf, and S.I. Najafi (SPIE 3469, San Diego, CA, 1998), p. 68.
5. J.N. Hay and H.N. Raval: Synthesis of organic-inorganic hybrids via the nonhydrolytic sol-gel process. Chem. Mater. 13, 3396 (2001).
6. O.V. Mishechkin, D. Lu, and M. Fallahi: Reliability improvement of hybrid organic-inorganic waveguides by dielectric passivation, in Proceedings of the 16th Annual Meeting of the IEEE Laser and Electro-optics Society, edited by A.E. Willner, L. Esterowitz, P.J. Delfye, H.S. Hinton, M.Y.L. Wisniewski, and N. Dagli (IEEE, Piscataway, NJ, 2003), p. 674.
7. U. Streppel, P. Dannberg, C. Wachter, A. Brauer, L. Frohlich, R. Houbertz, and M. Popall: New wafer-scale fabrication method for stacked optical waveguide interconnects and 3D micro-optic structures using photoresponsive (inorganic-organic hybrid) polymers. Opt. Mater. 21, 475 (2002).
8. E. Wipfelder and K. Hohn: Epoxysiloxane resins by the condensation of 3-glycidyloxypropyltrimethoxysilane with diphenylsilandiol. Die Ang. Makromol. Chem. 218, 111 (1994).
9. R. Buestrich, F. Kahlenberg, and M. Popall: ORMORCERs for optical interconnection technology. J. Sol-Gel Sci. Technol. 20, 181 (2001).
10. Y.J. Eo, J.H. Kim, J.H. Ko, and B.S. Bae: Optical characteristics of photo-curable methacryl-oligosilaxane nano hybrid thick films. J. Mater. Res. 20, 401 (2005).
11. R. Houbertz, G. Domann, C. Cronauer, A. Schmitt, H. Martin, J.U. Park, L. Frohlich, R. Buestich, M. Popall, U. Steppel, P. Dannberg, C. Wachter, and A. Brauer: Inorganic-organic hybrid materials for application in optical devices, in Application, New Markets, Emerging Products, Trends: Optics for Communications, edited by M.A. Aegerter and H.A. Meinema (Proceeding of 4th ICCG, Braunschweig, Germany, 2002), p. 605.
12. S.Y. Kim, S. Augustine, Y.J. Kim, B.S. Bae, S.I. Woo, and J.K. Kang: Mechanism and nanosize products of the sol-gel reaction using diphenylsilanediol and 3-methacryloxypropyltrimethoxysilane as precursors. J. Phys. Chem. B 109, 9397 (2005).
13. M.A. Aramendia, V. Borau, C. Jimenez, J.M. Marinas, J.R. Ruiz, and F.J. Urbano: α-Arylation of diethyl malonate via enolate with bases in a heterogeneous phase. Tetrahedron Lett. 43, 2847 (2002).
14. 1H NMR study of the hydrolysis of vinyl trialkoxysilanes. Mater. Chem. Phys. 64, 45 (2000).
15. D. Hoebbel, T. Reinert, and H. Schmidt: Si-29 NMR investigation of condensation reactions of diphenylsilanediol in presence of Ti-, Zr-, Al-, Sn- and Si-alkoxides. J. Sol-Gel. Sci. Technol. 7, 217 (1996).
16. I. Yoshinaga, N. Yamada, and S. Katayama: Effect of metal alkoxide complexes on condensation reactions of hydrolyzed phenyltriethoxysilane. J. Sol-Gel. Sci. Technol. 28, 65 (2003).
17. Y.J. Eo, T.H. Lee, S.Y. Kim, J.K. Kang, Y.S. Han, and B.S. Bae: Synthesis and molecular structure analysis of nano-sized methacrylgrafted polysiloxane resin for fabrication of nano hybrid materials. J. Polym. Sci. B 43, 827 (2005).
18. F.J. Feher, D.A. Newman, and J.F. Walzer: Silsequioxanes as models for silica surfaces. J. Am. Chem. Soc. 111, 1741 (1989).
19. M.C. Douskey, M.S. Gebhard, A.V. McCormick, B.C. Lange, D.W. Whitman, M.R. Schure, and K. Beshah: Spectroscopic studies of a novel cyclic oligomer with pendant alkoxysilane groups. Prog. Org. Coat. 45, 145 (2002).
20. T. Knoche, L. Muller, R. Klein, and A. Neyer: Low loss polymer waveguides at 1300 and 1550 nm using halogenated acrylates. Electron. Lett. 32, 1284 (1996).
21. M.V. Kunnavakkam, F.M. Houlihan, M. Schlax, J.A. Liddle, P. Kolodner, O. Nalamasu, and J.A. Rogers: Low-cost, low-loss microlens arrays fabricated by soft-lithography replication process. Appl. Phys. Lett. 82, 1152 (2003).