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Volumn 45, Issue 13, 2006, Pages 5179-5186

Molecular structures of tris(dipivaloylmethanato) complexes of the lanthanide metals, Ln(dpm)3, studied by gas electron diffraction and density functional theory calculations: A comparison of the Ln-O bond distances and enthalpies in Ln(dpm)3 complexes and the cubic sesquioxides, Ln2O3

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EID: 33746488418     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060079u     Document Type: Article
Times cited : (23)

References (61)
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    • Moeller, T. The Lanthanides. In Comprehensive Inorganic Chemistry; Bailar, J. C., Emeleus, H. J., Jr., Nyholm, R., Trotman-Dickinson, A. F., Eds.; Pergamon: Oxford, 1973; Vol. 4, pp 23, 88 f.
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    • note
    • 3, Ln = Nd to La, have been expanded accordingly.
  • 56
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    • note
    • In ref 46, Airoldi and co-workers list mean Ln-O bond enthalpies calculated in a similar manner from the standard atomization enthalpies of the sesquichlorides in their most stable forms, which in some cases are hexagonal or monoclinic (both with CN = 7) in others cubic (with CN = 6). Even though the coordination numbers differ, they chose to divide the atomization enthalpy by 7 in every case. More seriously, they seem to have overlooked that the atomization of 1 mol of the formula unit involves the rupture of 12 (or 14) Ln-O bonds.
  • 57
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    • Thermodynamic Properties of the Lanthanide(III) Halides
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.