Complexes of copper(II) with 2-(N-salicylideneamino)- 3-carboxyethyl-4,5,6, 7-tetrahydrobenzo[ b ]thiophene containing different counter anions

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 36, Issue 6, 2006, Pages 441-449

  Mohanan, K ^a   Nirmala Devi, S ^b   Murukan, B ^a  

^a UNIVERSITY OF KERALA   (India)

^b Government College for Women   (India)

Author keywords

2 amino 3 carboxyethyl 4,5,6,7 tetrahydrobenzo b thiophene; Antibacterial activity; Copper(II) complexes; Counter anions; Transesterification; XRD

Indexed keywords

EID: 33746333015     PISSN: 15533174     EISSN: 15533182     Source Type: Journal    
DOI: 10.1080/15533170600777788     Document Type: Article

References (37)

1. Holm, R. H.; Everett, G. W., Jr.; Chakravorty, A. Metal complexes of Schiff bases and beta-ketoamines. Progr. Inorg. Chem. 1966, 7, 83-212.
2. Calligaris, M.; Randaccio, L. Schiff bases as acyclic polydentate ligands. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., Mc Cleverly, J. A., Eds.; Oxford Pergamon press, 1987; Vol. 2, pp. 715-738.
3. Collinson, S. R.; Fenton, D. E. Metal complexes of bibracchial schiff base macrocyclics. Coord. Chem. Rev. 1996, 148, 19-40.
4. Vigato, P. A.; Tamburine, S. The chellange of cyclic and acyclic Schiff bases and their related derivatives. Coord. Chem. Rev. 2004, 248, 1717-2128.
5. Angelici, R. J. Structural aspects of thiophene coordination in transition metal complexes. Coord. Chem. Rev. 1990, 105, 61-76.
6. Singh, K.; Sharma, P. K.; Dubey, S. N. Some Sb(III) and Bi(III) complexes of benzothiozolines derived from heterocyclic aldehydes. Indian J. Chem. 1994, 33A, 266-268.
7. Kavitha, S.; Agarwala, B. V. Studies on some lanthanide complexes of higher coordination number - Synthesis and characterisation. Synth. React. Inorg. Met-Organic Chem. 1996, 26, 473-492.
8. Minati, S.; Pradhan, B. Synthesis and characterisation of copper(II) and nickel(II) complexes with Schiff bases derived from aromatic diamines and heterocyclic aldehydes. J. Indian Chem. Soc. 1998, 75, 518-519.
9. 2. J. Inorg. Biochem. 2005, 99, 467-476.
10. Kellogg, R. M. Thiophene and their benzo derivatives(1) structure. In Comprehensive Heterocyclic Chemistry; Bird, G. V., Cheeseman, Eds.; Pergamon Press: England, 1984; Vol. 4.
11. Gewald, K.; Schinke, E.; Böllcher, H. 2-Amino-thiopheneaus methylenaktiven nitrilen, carbonylerbindungen und Schwefel. Chem. Ber. 1966, 94-99.
12. Offiong, E. O.; Martelli, S. Antibacterial activity of metal complexes of benzil and benzoin thiosemicarbazone. IL Farmaco 1994, 49, 513-518.
13. Geary, W. J. The use of conductivity measurements in organic solvents for the characterisation of coordination compounds. Coord. Chem. Rev. 1971, 7, 81-115.
14. Antonov, L.; Fabian, W. M. F.; Nedelteheva, D.; Kamounah, F. S. Tautomerism of 2-hydroxynaphthaldehyde Schiff bases. J. Chem. Soc. Perkin. Trans. 2000, 2, 1173-1179.
15. Bonnett, R. The optical rotatory dispersion and circular dichroism of azomethines. In The Chemistry of Carbon Nitrogen Double Bond; Patai, S., Ed.; Interscience: New York, 1970; pp. 181-234.
16. Thankarajan, N.; Mohanan, K. Copper(II), iron(II), cobalt(II), nickel(II), manganese(II), zinc(II), iron(III), manganese(III), cobalt(III), vanadium(IV), thorium(IV) and uranium(VI) complexes with N-(2-hydroxy-1- naphthylidene)glycine. J. Indian Chem. Soc. 1986, 63, 861-864.
17. Rao, C. N.R. Chemical Application of Infrared Spectroscopy; Academic press: New York, 1963.
18. Elmer, C. A.; Abdul, M. Synthesis and characterization of some dibasic tridentate Schiff base ligands. Canadian J. Chem. 1975, 53, 939-944.
19. Angoso, A.; Martin-Llorente, J. M.; Manzano, J. L.; Martin, M.; Martin, R.; Rodriguez, E.; Soria, J. Preparation and study of amino acid (DL-Leucine, L-isoleucine, D-histidine) Schiff bases with ethyl-α- ketocyclopentylcarboxylate and the corresponding copper(II) complexes. Inorg. Chim. Acta. 1992, 195, 45-49.
20. Gale, P. A. Anion coordination and anion-directed assembly: highlights from 1997 and 1998. Coord. Chem. Rev. 2000, 199, 181-233.
21. Zhou, J.; Lancaster, S. J.; Walker, D. A.; Beck, S.; Thornton-Peth, M.; Bochmann, M. Synthesis, structures and reactivity of weakly coordinating anions with delocalized borate structure: The assessment of anion effects in metallocene polymerization catalysts. J. Am. Chem. Soc. 2001, 123, 223-237.
22. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds; John Wiley & Sons: New York, 1997.
23. Scholer, R. P.; Merbach, A. E. Raman and infrared study of hexamethyl phosphoramide complexes of lanthanide perchlorates. Inorg. Chim. Acta. 1975, 15, 15-20.
24. 2]. Polyhedron. 1998, 17, 1779-1785.
25. Kharodawala, M. J.; Rana, A. K. Synthesis, characterization and biological activity of some transition metal chelates of 4-acyloximo-2- pyrazolin- 5-ones. Synth. React. Inorg. Met. Org. Chem. 2003, 33, 1483-1504.
26. Nawar, N.; Khattab, M. A.; Hosny, N. M. Some metal(II) complexes of α-aminoacetophenonebenzoylhydrazone - Their preparation, characterization and antimicrobial activity. Synth. Rect. Inorg. Met.-Org. Chem. 1990, 29, 1365-1384.
27. Kamalakannan, D.; Venkappayya, D. Spectral, thermal and antimicrobial studies on the copper(II), zinc(II), cadmium(II) and mercury(II) chelates of a new antimetabolite-5-dimethylaminomethyl-2-thiouracil. Russian J. Coord. Chem. 2002, 28, 423-433.
28. Kivelson, D.; Nieman, R. ESR studies on the bonding copper complexes. J. Chem. Phys. 1961, 35, 149-155.
29. Shetty, S. N.; Murthy, A. S. R.; Timpe, G. L. Synthesisi and spectral characterization of copper(II) complexes of dithiosemicarbazones. Indian J. Chem. 1993, 32A, 318-322.
30. Verter, H. S.; Frost, A. E. Some reactions of the bis-(salicylidene)- Cu(II) chelates. J. Am. Chem. Soc. 1960 (82), 85-89.
31. Gillard, R. D.; Wootton, R. Reactions of some copper(II) complexes of the Schiff bases on amino acid esters. J. Chem. Soc. (B) 1970, 364-371.
32. Jursik, F.; Hajek, B. Transition metal complexes of ligands containing azomethine group V. Stereochemistry and reactivity of four-coordinate nickel(II) complexes derived from (S) - (+) - Cysteine derivatives. Inorg. Chim. Acta. 1975, 13, 169-173.
33. Hentry, N. F. M.; Lipson, H.; Wooster, W. A. Interpretation of X-ray Diffraction Photographs; Macmillan: London, 1951.
34. D'Eye, R. W. M.; Wait, E. X-ray Powder Photography in Inorganic Chemistry; Butterworths: London, 1960.
35. Thimmaiah, K. N.; Lloyd, W. D.; Chandrappa, G. T. Stereochemistry and fungitoxicity of complexes of p-anisaldehydethiosemicarbazone with Mn(II), Fe(II), Co(II) and Ni(II). Inorg. Chim. Acta. 1985, 106, 81-83.
36. Oliva, B.; O'Neill, A.; Wilson, J. M.; O'Hanlon, P. J.; Chopra, I. Antibacterial properties and mode of action of the pyrrothine holomycin. Antibac. Agent Chemother. 2001, 45, 532-539.
37. Petering, D. H. Reaction of copper complexes with Ehrlich cells. In Inorganic and Nutritional Aspects of Cancer; Schrauzer, G. N., Ed.; Plenum Press: New York, 1978, pp. 179-191.