A self-complementary assembly of metallamacrocycles directed by Ru-Cl⋯H-N hydrogen bonds and its reversible dichotomy by halide anions in solution

Angewandte Chemie - International Edition

Volumn 45, Issue 26, 2006, Pages 4290-4294

  Park, Young Jun ^b   Kim, Jik Soo ^b   Youm, Kyoung Tae ^b   Lee, Nam Kyu ^b   Ko, Jaejung ^a   Park, Hye Seo ^b   Jun, Moo Jin ^b  

^a Korea University   (South Korea)

^b Yonsei University   (South Korea)

Author keywords

Coordination modes; Hydrogen bonds; Metal halides; Metallamacrocycles; Self assembly

Indexed keywords

COORDINATION MODES; METAL HALIDES; METALLAMACROCYCLES;

DISSOCIATION; NEGATIVE IONS; PARAFFINS; SELF ASSEMBLY; SOLUTIONS;

HYDROGEN BONDS;

ANION; CHLORINE; HYDROGEN; NITROGEN; RUTHENIUM;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLUTION AND SOLUBILITY; X RAY CRYSTALLOGRAPHY;

ANIONS; CHLORINE; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; HYDROGEN; HYDROGEN BONDING; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; NITROGEN; RUTHENIUM; SOLUTIONS;

EID: 33746312104     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600154     Document Type: Article

References (49)

1. For recent reviews: a) M. Ruben, J. Rojo, F. J. Romero-Salguero, L. H. Uppadine, J.-M. Lehn, Angew. Chem. 2004, 116, 3728;
2. Angew. Chem. Int. Ed. 2004, 43, 3644;
3. b) S. R. Seidel, P. J. Stang, Acc. Chem. Res. 2002, 35, 972;
4. c) G. F. Swiegers, T. J. Malefetse, Coord. Chem. Rev. 2002, 225, 91;
5. d) B. J. Holliday, C. A. Mirkin, Angew. Chem. 2001, 113, 2076;
6. Angew. Chem. Int. Ed. 2001, 40, 2022;
7. e) F. A. Cotton, C. Lin, C. A. Murillo, Acc. Chem. Res. 2001, 34, 759;
8. f) M. Fujita, K. Umemoto, M. Yoshizawa, N. Fujita, T. Kusukawa, K. Biradha, Chem. Commun. 2001, 509;
9. g) S. Leininger, B. Olenyuk, P. J. Stang, Chem. Rev. 2000, 100, 853;
10. h) D. L. Caulder, K. N. Raymond, J. Chem. Soc. Dalton Trans. 1999, 1185;
11. i) D. L. Caulder, K. N. Raymond, Acc. Chem. Res. 1999, 32, 975;
12. j) P. N. W. Baxter, J.-M. Lehn, G. Baum, D. Fenske, Chem. Eur. J. 1999, 5, 102;
13. k) M. Fujita, Chem. Soc. Rev. 1998, 27, 417.
14. For some recent examples: a) H.-J. van Manen, V. Paraschiv, J. J. García-López, H. Schönherr, S. Zapotoczny, G. J. Vancso, M. Crego-Calama, D. N. Reinhoudt, Nano Lett. 2004, 4, 441;
15. b) R. García-Zarracino, H. Höpfl, Angew. Chem. 2004, 116, 1533;
16. Angew. Chem. Int. Ed. 2004, 43, 1507;
17. c) A. Md. Alam, M. Nethaji, M. Ray, Angew. Chem. 2003, 115, 1984;
18. Angew. Chem. Int. Ed. 2003, 42, 1940;
19. d) A. J. Goshe, I. M. Steele, B. Bosnich, J. Am. Chem. Soc. 2003, 125, 444;
20. e) L. J. Childs, N. W. Alcock, M. J. Hannon, Angew. Chem. 2002, 114, 4418;
21. Angew. Chem. Int. Ed. 2002, 41, 4244;
22. f) K. M. Kim, J. S. Park, Y.-S. Kim, Y. J. Jun, T. Y. Kang, Y. S. Sohn, M.-J. Jun, Angew. Chem. 2001, 113, 2524;
23. Angew. Chem. Int. Ed. 2001, 40, 2458;
24. g) S.-Y. Yu, T. Kusukawa, K. Biradha, M. Fujita, J. Am. Chem. Soc. 2000, 122, 2665;
25. h) L. J. Childs, N. W. Alcock, M. J. Hannon, Angew. Chem. 2001, 113, 1113;
26. Angew. Chem. Int. Ed. 2001, 40, 1079.
27. a) T. Steiner, Angew. Chem. 2002, 114, 50;
28. Angew. Chem. Int. Ed. 2002, 41, 48;
29. b) G. Aullón, D. Bellamy, L. Brammer, E. A. Bruton, A. G. Orpen, Chem. Commun. 1998, 653;
30. c) G. P. A. Yap, A. L. Rheingold, P. Das, R. H. Crabtree, Inorg. Chem. 1995, 34, 3474;
31. d) A. Angeloni, P. C. Crawford, A. G. Orpen, T. J. Podesta, B. J. Shore, Chem. Eur. J. 2004, 10, 3783;
32. e) L. Brammer, Chem. Soc. Rev. 2004, 33, 476.
33. a) Z. Qin, M. C. Jennings, R. J. Puddephatt, Inorg. Chem. 2003, 42, 1956;
34. b) Z. Qin, M. C. Jennings, R. J. Puddephatt, Inorg. Chem. 2002, 41, 3967;
35. c) Z. Qin, M. C. Jennings, R. J. Puddephatt, Chem. Commun. 2001, 2676.
36. a) K.-S. Jeong, Y. L. Cho, S.-U. Chang, T.-Y. Park, J. U. Song, J. Org. Chem. 1999, 64, 9459;
37. b) K.-S. Jeong, Y. L. Cho, J. U. Song, H.-Y. Chang, M.-G. Choi, J. Am. Chem. Soc. 1998, 120, 10 982;
38. c) K.-S. Jeong, Y. L. Choi, S.-U. Chang, H.-Y. Chang, Angew. Chem. 2000, 112, 1758;
39. Angew. Chem. Int. Ed. 2000, 39, 1692;
40. d) S.-Y. Chang, H.-Y. Jang, K.-S. Jeong, Chem. Eur. J. 2003, 9, 1535.
41. a) S.-S. Sun, A. J. Lees, Chem. Commun. 2000, 1687;
42. b) P. D. Beer, F. Szemes, V. Balzani, C. M. Sala, M. G. B. Drew, S. W. Dent, M. Maestri, J. Am. Chem. Soc. 1997, 119, 11 864.
43. F. H. Jardine, Prog. Inorg. Chem. 1984, 31, 265.
44. 2 = 0.1793, and GOF = 1.006. CCDC-277154 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
45. A. L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht (Netherlands), 2003.
46. 2 = 0.2535, and GOF = 1.060. CCDC-277155 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
47. 2 in the presence of 8 equivalents of TEACl because the long data-acquisition period and the limited volume of NMR solvent caused crystal formation of the 3·2 TEACl species.
48. J.-M. Lehn, Supramolecular Chemistry, Concepts, and Perspectives, VCH, Weinheim, 1995.
49. 2 into an intractable product was observed.