A biocatalytic Henry reaction - The hydroxynitrile lyase from Hevea brasiliensis also catalyzes nitroaldol reactions

Angewandte Chemie - International Edition

Volumn 45, Issue 21, 2006, Pages 3454-3456

  Purkarthofer, Thomas ^a   Gruber, Karl ^a   Gruber Khadjawi, Mandana ^a   Waich, Kerstin ^a   Skranc, Wolfgang ^b   Mink, Daniel ^c   Griengl, Herfried ^a  

^a RESEARCH CENTRE APPLIED BIOCATALYSIS   (Austria)

^b DSM Fine Chemicals Austria Nfg GmbH & Co KG   (Netherlands)

^c DSM RESEARCH   (Netherlands)

Author keywords

Biocatalysis; Henry reaction; Hydroxynitrile lyase; Molecular modeling; Nitroalcohols

Indexed keywords

BIOCATALYTIC HENRY REACTION; NITROETHANE; NITROMETHANE;

ALCOHOLS; CHEMICAL REACTIONS; ENZYME KINETICS; MATHEMATICAL MODELS; RUBBER; STEREOCHEMISTRY;

BIOCATALYSTS;

ACETONITRILE DERIVATIVE; ALDEHYDE; LYASE; MANDELONITRILE; NITRO DERIVATIVE; S HYDROXYNITRILE LYASE, HEVEA BRASILIENSIS; S-HYDROXYNITRILE LYASE, HEVEA BRASILIENSIS;

ARTICLE; BINDING SITE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; ENZYME ACTIVATION; ENZYME SPECIFICITY;

ACETONITRILES; ALDEHYDE-LYASES; ALDEHYDES; BINDING SITES; CATALYSIS; ENZYME ACTIVATION; MODELS, MOLECULAR; NITRO COMPOUNDS; SUBSTRATE SPECIFICITY;

EID: 33746265821     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200504230     Document Type: Article

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