Comparison of gas-phase acidities of some carbon acids with their rates of hydron exchange in methanolic methoxide

Journal of Physical Organic Chemistry

Volumn 19, Issue 5, 2006, Pages 308-317

  DeTuri, Vincent F ^a   Koch, Heinz F ^a   Koch, Judith G ^a   Lodder, Gerrit ^b   Mishima, Masaaki ^c   Zuilhof, Han ^d   Abrams, Neal M ^a   Anders, Cecily E ^a   Biffinger, Justin C ^a   Han, Patrick ^a   Kurland, Adam R ^a   Nichols, Jason M ^a   Ruminski, Anne M ^a   Smith, Patricia R ^a   Vasey, Karen D ^a  

^a ITHACA COLLEGE   (United States)

^b LEIDEN UNIVERSITY   (Netherlands)

^c KYUSHU UNIVERSITY   (Japan)

^d WAGENINGEN UNIVERSITY   (Netherlands)

Author keywords

GAcid 0 (gas phase); B3LYP 6 31+G(d,p) calculations; Kinetic acidities; Methanolic sodium methoxide

Indexed keywords

BENZENE; ENTROPY; HYDROGEN BONDS; ION EXCHANGE; ISOTOPES; OLEFINS; SODIUM COMPOUNDS;

ΔGACID0 (GAS PHASE); B3LYP/6-31+G(D,P) CALCULATIONS; KINETIC ACIDITIES; METHANOLIC SODIUM METHOXIDES;

INORGANIC ACIDS;

EID: 33746151728     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1057     Document Type: Article

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