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Volumn 9, Issue 8, 2006, Pages 782-784

A trinuclear cobalt(III) phosphate complex with a novel molecular structure: Synthesis and crystal structure of {[Co(en)2]3(PO4)(HPO4)}2(H2PO4)Cl7 · 6H2O

Author keywords

Cobalt(III); Coordination chemistry; Crystal structure; Ethylenediamine; NMR spectroscopy; Phosphate

Indexed keywords


EID: 33745922347     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2006.04.001     Document Type: Article
Times cited : (7)

References (19)
  • 13
    • 33745915037 scopus 로고    scopus 로고
    • note
    • max 603, 304 and 247 nm corresponding to d-d transitions typical for octahedral low spin cobalt(III) salts.
  • 14
    • 33745916517 scopus 로고    scopus 로고
    • note
    • 2 by means of the SHELX-97 package [15]. Non-hydrogen atoms were refined anisotropically. H-atoms of ethylenediamine were introduced in ideal positions whereas those linked to O-atoms were not included in the model. Absolute structure could not be determined, the structure being refined as a twin of both enantiomers with equal contributions. Complete crystallographic data have been deposited at the Cambridge Crystallographic Data Centre (CCDC No. 298942) and may be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.