Limonene epoxidation: Diffusion and reaction over PW-amberlite in a triphasic system

Industrial and Engineering Chemistry Research

Volumn 45, Issue 13, 2006, Pages 4589-4596

  Zapata, R Barrera ^a   Villa, A L ^a   Montes De Correa, C ^a  

^a UNIVERSIDAD DE ANTIOQUIA   (Colombia)

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); DECOMPOSITION; DIFFUSION; HYDROGEN PEROXIDE; MASS TRANSFER; REACTION KINETICS;

EPOXIDE; LIMONENE; PARTICLE SIZES; TRIPHASIC SYSTEM;

TERNARY SYSTEMS;

CONCENTRATION (PROCESS); DECOMPOSITION; DIFFUSION; HYDROGEN PEROXIDE; MASS TRANSFER; REACTION KINETICS; TERNARY SYSTEMS;

EID: 33745841295     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie060098b     Document Type: Article

References (29)

1. Derfer, J. M.; Derfer, M. M. Encyclopedia of Chemical Technology Kirk-Othmer, 3rd ed.; Wiley: New York, 1978; Vol. 22.
2. 2. Top. Catal. 2000, 13, 223.
3. Villa, A. L.; Taborda, F.; Montes de C., C. Kinetics of limonene epoxidation by hydrogen peroxide on PW-Amberlite. J. Mol. Catal., A. 2002, 185, 269.
4. 2 induced triphase catalysis in the oxidation of hydrophobic organic compounds with significant enhancement of activity and para-selectivity. J. Chem. Soc., Chem. Commun. 1995, 3, 349.
5. Bhaumik, A.; Mukherjee, P.; Kumar, R. Triphase catalysis over titanium-silicate molecular sieves under solvent-free conditions. I. Direct hydroxylation of benzene. J. Catal. 1998, 178, 101.
6. 2 system in selective oxidation reactions. Microporous Mesoporous Mater. 1998, 21, 497.
7. Villa, A. L. Epoxidation of Monoterpenes by Homogeneous and Heterogeneous Catalytic Systems. Doctoraatsproefschrift, Nr. 441 aan de Faculteit Landbouwkundige en Toegepaste Biologische Wetenschappen van de Katholieke Universiteit Leuven, Sept 2000.
8. Sainio, T.; Laatikainen, M.; Paatero, E. Phase equilibria in solvent mixture - ion-exchange resin catalyst systems. Fluid Phase Equilib. 2004, 218, 269.
9. National Institute of Standards and Technology Home Page, http://trc.nist.gov/GDC.html (accessed Oct 2005).
10. Chirico, R. D.; Frenkel, M.; Diky, V. V.; Marsh, N. K.; Wilhoit, R. C. ThermoML - An XML-based approach for storage and exchange of experimental and critically evaluated thermophysical and thermochemical property data. 2. Uncertainties. J. Chem. Eng. Data 2003, 48, 1344.
11. Pääkkönen, P. K.; Krause, A. O. Diffusion and chemical reaction in isoamylene etherification within cation-exchange resin. Appl. Catal., A. 2003, 245, 289.
12. Reid, R.; Sherwood, T. The properties of gases and liquids, their estimation and correlation, second ed.; McGraw-Hill: New York, 1968.
13. California Air Resources Board Home Page. http://www.arb.ca.gov/db/ solvents/solvent_pages/Hydrocarbon-HTML/d-limonene.htm (accessed Sept 2005).
14. University of Waterloo Home Page. http://www.science.uwaterloo.ca/ ~cchieh/cact/c123/liquid.html (accessed Aug 2005).
15. Matheson Tri-Gas Home Page. Material Safety Data Sheet; http://www.matheson-trigas.com/msds/MAT00170.pdf (accessed June 2005).
16. Othmer, D. F.; Thakar, M. S. Correlating diffusion coefficient in liquids. Ind. Eng. Chem. 1953, 45, 589.
17. Scheibel, E. G. Correspondence. Liquid diffusivities. Viscosity of gases. Ind. Eng. Chem. 1954, 46, 2007.
18. Fogler, H. S. Elements of chemical reaction engineering, third ed.; Prentice Hall: Upper Saddle River, NJ, 2001.
19. Kooijman, H. A.; Taylor, R. Estimation of diffusion coefficients in multicomponent liquid systems. Ind. Eng. Chem. Res. 1991, 30, 1217.
20. Rehfinger, A.; Hoffmann, U. Kinetics of methyl tertiary butyl ether liquid-phase synthesis catalyzed by ion-exchange resin. II. Macropore diffusion of methanol as rate controlling step. Chem. Eng. Sci. 1990, 45, 1619.
21. Barrera, R.; Villa A. L.; Montes de C., C. Liquid - liquid equilibrium for the water + acetonitrile + limonene system at different temperatures. J. Chem. Eng. Data. 2005, 50, 1353.
22. Hill, C. G. An introduction to chemical engineering kinetics & reactor design; John Wiley & Sons: New York, 1977.
23. Dogu, T.; Dogu, G. A grain model for catalyst tortuosity. Chem. Eng. Commun. 1991, 103, 1.
24. Oktar, N.; Mürtezaoglu, K.; Dogu, T.; Dogu, G. Dynamic analysis of adsorption equilibrium and rate parameters of reactants and products in MTBE, ETBE and TAME production. Can. J. Chem. Eng. 1999, 77, 406.
25. Madon, J. R.; Boudart, M. Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions. Ind. Eng. Chem. Fundam. 1982, 21, 438.
26. Fu, H.; Kaliaguine, S. A kinetic investigation of cosolvent effects in oxyfunctionalization of n-hexane by hydrogen peroxide. J. Catal. 1994, 148, 540.
27. Gallot, J. E.; Fu, H.; Kapoor, M. P.; Kaliaguine, S. Kinetic modeling of n-hexane oxyfunctionalization by hydrogen peroxide on titanium silicalites of MEL structure (TS-2). J. Catal. 1996, 161, 798.
28. Anderson, T. F.; Prausnitz, J. M. Application of the UNIQUAC equation to calculation of multicomponent phase equilibria. 2. Liquid - liquid equilibria. Ind. Eng. Chem. Process Des. Dev. 1978, 17, 561.
29. Sandler, S. I. Chemical and Engineering Thermodynamics, third ed.; John Wiley & Sons: New York, 1999.