Construction of terminal conjugated enynes: Cu-mediated cross-coupling reaction of alkenyldialkylborane with (trimethylsilyl)ethynyl bromide

Synthesis

Volumn , Issue 12, 2006, Pages 1961-1970

  Hoshi, Masayuki ^a   Kawamura, Noritsugu ^a   Shirakawa, Kazuya ^a  

^a KITAMI INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

(Trimethylsilyl)ethynyl bromide; 1,3 bis(trimethylsilyl)alk 3 en 1 yne; Alk 3 en 1 yne; Alkenyldialkylborane; Cross coupling

Indexed keywords

ADDITION REACTIONS; CATALYSIS; CHEMICAL BONDS; COPPER COMPOUNDS; SODIUM COMPOUNDS; STEREOCHEMISTRY;

1,3-BIS(TRIMETHYLSILYL)ALK-3-EN-1-YNE; ALK-3-EN-1-YNE; ALKENYLDIALKYLBORANE; CROSS-COUPLING; ETHYNYL BROMIDE;

BORON COMPOUNDS;

(TRIMETHYLSILYL)ETHYNYL BROMIDE; 1 (TRIMETHYLSILYL)ALK 1 ENYLDICYCLOHEXYLBORANE; 1 (TRIMETHYLSILYL)ALK 3 ENE 1 YNE DERIVATIVE; 1,3 BIS(TRIMETHYLSILYL)ALK 3 ENE 1 YNE; 3 (TRIMETHYLSILYL)ALK 3 ENE 1 YNE; ACETIC ACID DERIVATIVE; ACETYLACETONATE; ALKENE DERIVATIVE; ALKENYLDIALKYLBORANE; BORANE DERIVATIVE; BROMINE DERIVATIVE; COPPER; COPPER IODIDE; CUPRIC ION; HYDROXIDE; IODINE DERIVATIVE; LITHIUM HYDROXIDE MONOHYDRATE; METHOXIDE SODIUM; OXIDE; SODIUM HYDROXIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CONJUGATION; CROSS COUPLING REACTION; DESILYLATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 33745743038     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-942373     Document Type: Article

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