Sulfonated poly(ether ether ketone)/polyaniline composite proton-exchange membrane

Journal of Membrane Science

Volumn 280, Issue 1-2, 2006, Pages 389-396

  Nagarale, R K ^a   Gohil, G S ^a   Shahi, Vinod K ^a  

^a CSIR CENTRAL SALT AND MARINE CHEMICALS RESEARCH INSTITUTE   (India)

Author keywords

Methanol permeability; Polyaniline composite membrane; Proton conductivity; Proton exchange membrane; Sulfonated PEEK

Indexed keywords

CONCENTRATION (PROCESS); FOURIER TRANSFORM INFRARED SPECTROSCOPY; MECHANICAL PERMEABILITY; ORGANIC POLYMERS; PROTONS; SULFONATION;

METHANOL PERMEABILITY; POLYANILINE COMPOSITE MEMBRANE; PROTON CONDUCTIVITY; PROTON-EXCHANGE MEMBRANE; SULFONATED PEEK;

POLYMERIC MEMBRANES;

KETONE DERIVATIVE; METHANOL; POLYANILINE;

CONCENTRATION (PROCESS); FOURIER TRANSFORM INFRARED SPECTROSCOPY; MECHANICAL PERMEABILITY; ORGANIC POLYMERS; POLYMERIC MEMBRANES; PROTONS; SULFONATION;

ARTICLE; COMPOSITE MATERIAL; COST EFFECTIVENESS ANALYSIS; ELECTROCHEMISTRY; INFRARED SPECTROSCOPY; ION EXCHANGE; MEMBRANE PERMEABILITY; MEMBRANE STRUCTURE; PHYSICAL CHEMISTRY; POLYMERIZATION; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; SULFONATION; THERMOGRAVIMETRY; THERMOSTABILITY; WATER TRANSPORT;

EID: 33745728059     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2006.01.043     Document Type: Article

References (27)

1. Ren X., Zelaney P., Thomas S., Davey J., and Gottesfeld S. Recent advances in direct methanol fuel cells at Los Alamos National Laboratory. J. Power Sources 86 (2000) 111
2. Ravikumar M.K., and Shukla A.K. Effect of methanol crossover in a liquid-feed polymer-electrolyte direct methanol fuel cell. J. Electrochem. Soc. 143 (1996) 2601
3. Heinzel A., and Barragan V.M. A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells. J. Power Sources 84 (1999) 70
4. Kerres J., Ullrich A., Haring Th., Preidel W., Baldauf M., and Gebhardt U. Preparation, characterization, and fuel cell application of new acid-base blend membranes. J. New Mater. Electrochem. Syst. 3 (2000) 229
5. Savadogo O. Emerging membranes for electrochemical systems. Part II. High temperature composite membranes for polymer electrolyte fuel cell (PEFC) applications. J. Power Sources 127 (2004) 135
6. Heitner-Wirguin C. Recent advances in perfluorinated ionomer membranes: structure, properties and applications. J. Membr. Sci. 120 (1996) 1
7. Alberti G., Casciola M., and Palombari R. Inorgano-organic proton conducting membranes for fuel cells and sensors at medium temperatures. J. Membr. Sci. 172 (2000) 233
8. Arico A.S., Creti P., Antonucci P.L., and Antonucci V. Comparison of ethanol and methanol oxidation in a liquid-feed solid polymer electrolyte fuel cell at high temperature. Electrchem. Solid-Sate Lett. 1 (1998) 66
9. Yang C., Srinivasan S., Arico A.S., Creti P., Baglio V., and Antonucci V. Composite Nafion/zirconium phosphate membranes for direct methanol fuel cell operation at high temperature. Electrchem. Solid-Sate Lett. 4 (2001) A31
10. Xing P., Robertson G.P., Guiver M.D., Mikhailenko S.D., Wang K., and Kaliaguine S. Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes. J. Membr. Sci. 229 (2004) 95
11. Kerres J. Development of ionomer membranes for fuel cells. J. Membr. Sci. 185 (2001) 3
12. Huang R.Y.M., Shao P., Burns C.M., and Feng X. Sulfonation of poly(ether ether ketone) (PEEK): kinetic study and characterization. J. Appl. Polym. Sci. 82 (2001) 2651
13. Shibuya N., and Porter R.S. A kinetic study of PEEK sulfonation in concentrated sulfuric acid by ultraviolet-visible spectroscopy. Polymer 35 (1994) 3237
14. Daoust D., Devaux J., and Godard P. Mechanism and kinetics of poly(ether ether ketone) (PEEK) sulfonation in concentrated sulfuric acid at room temperature. Part 1. Qualitative comparison between polymer and monomer model compound sulfonation. Polym. Int. 50 (2001) 917
15. Daoust D., Devaux J., and Godard P. Mechanism and kinetics of poly(ether ether ketone) (PEEK) sulfonation in concentrated sulfuric acid at room temperature. Part 2. Qualitative interpretation of model compound sulfonation. Polym. Int. 50 (2001) 925
16. Lai E.K.W., Beattie P.D., Orfino F.P., Simon E., and Holdcroft S. Electrochemical oxygen reduction at composite films of Nafion, polyaniline and Pt. Electrochim. Acta 44 (1999) 2559
17. Prasad K.R., and Munichandraiah N. Electrocatalytic efficiency of polyaniline by cyclic voltammetry and electrochemical impedance spectroscopy studies. Synth. Met. 126 (2002) 61
18. X. Li, D. Chen, D. Xu, C. Zhao, Z. Wang, H. Lu, H. Na, SPEEKK/polyaniline (PANI) composite membranes for direct methanol fuel cell usages, J. Membr. Sci., doi:10.1016/j.memsci.2005.09.018.
19. Bailly C., Williams D.J., Karasz F.E., and Macknight W.J. The sodium salts of sulphonated poly(aryl-ether-ether-ketone) (PEEK): preparation and characterization. Polymer 28 (1987) 1009
20. Shahi V.K., Thampy S.K., and Rangarajan R. Studies on transport properties of surfactant immobilized anion-exchange membrane. J. Membr. Sci. 158 (1999) 77
21. Carretta N., Tricoli V., and Picchioni F. Ionomeric membranes based on partially sulfonated poly(styrene): synthesis, proton conduction and methanol permeation. J. Membr. Sci. 166 (2000) 189
22. Nolte R., Ledjeff K., Bauer M., and Mulhaupt R. Partially sulfonated poly(arylene ether sulfone)-a versatile proton conducting membrane material for modern energy conversion technologies. J. Membr. Sci. 83 (1993) 211
23. Nagarale R.K., Gohil G.S., Shahi V.K., and Rangarajan R. Organic-inorganic hybrid membrane: thermally stable cation-exchange membrane prepared by the sol-gel method. Macromolecules 37 (2004) 10023
24. Shahi V.K., Trivedi G.S., Thampy S.K., and Rangarajan R. Studies on the electrochemical and permeation characteristics of asymmetric charged porous membranes. J. Colloid Interf. Sci. 262 (2003) 566
25. Lakshiminarayaiah N. Transport Phenomena in Membranes (1969), Academic Press, New York
26. Miyatake K., Oyaizu K., Tsuchida E., and Hay A.S. Synthesis and properties of novel sulfonated arylene ether/fluorinated alkane copolymers. Macromolecules 34 (2001) 2065
27. Pivovar B.S., Wang Y., and Cussler E.L. Pervaporation membranes in direct methanol fuel cells. J. Membr. Sci. 154 (1999) 155