Tuning the oxidation properties of vanadium(V) through ligand stoichiometry

Tetrahedron Letters

Volumn 47, Issue 33, 2006, Pages 5923-5926

  Zeng, Wei ^a   Ballard, T Eric ^a   Melander, Christian ^a  

^a NORTH CAROLINA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALDEHYDE DERIVATIVE; ALLYL COMPOUND; HYDROXAMIC ACID; KETONE DERIVATIVE; LIGAND; TERT BUTYL HYDROPEROXIDE; VANADIUM;

ARTICLE; OXIDATION; STOICHIOMETRY;

EID: 33745726179     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.06.051     Document Type: Article

References (19)

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19. 3 (38 μmol, 9 μL) in 6 mL of dry toluene (25 °C, 1 h) were added cinnamyl alcohol (104 mg, 0.776 mmol) and t-BuOOH (1.14 mmol, 228 μL, 5.0 M) at -20 °C under an Ar atmosphere. The solution was stirred at -20 to 0 °C for 4 h, the solution allowed to warm to 25 °C and stirred for 48 h. The reaction was distilled to dryness in vacuum, and chromatography of the residue on silica gel gave 51 mg cinnamyl aldehyde (50% yield).