A new kinetic model for the photopolymerization shrinkage-strain of dental composites and resin-monomers

Dental Materials

Volumn 22, Issue 8, 2006, Pages 785-791

  Atai, Mohammad ^a   Watts, David C ^b  

^a IRAN POLYMER AND PETROCHEMICAL INSTITUTE   (Iran)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Dental composites; Filler; Kinetic model; Kinetics; Photopolymerization; Shrinkage

Indexed keywords

FILLERS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GLASS; MONOMERS; PHOTOPOLYMERIZATION; SHRINKAGE; STRAIN RATE;

RESIN MATRIX; RESIN-MONOMERS; SHRINKAGE-STRAIN RATES;

DENTAL COMPOSITES;

2-(DIMETHYLAMINO)ETHYL METHACRYLATE; BIOMEDICAL AND DENTAL MATERIALS; BISPHENOL A BIS(2 HYDROXYPROPYL) ETHER DIMETHACRYLATE; CAMPHOROQUINONE; GLASS; GLASS FIBER; MACROGOL DERIVATIVE; METHACRYLIC ACID DERIVATIVE; METHACRYLIC ACID DIMETHYLAMINOETHYL ESTER; POLYMER; POLYMETHACRYLIC ACID DERIVATIVE; RESIN; SILANE DERIVATIVE; TERPENE; TRIETHYLENE GLYCOL DIMETHACRYLATE;

ARTICLE; CHEMICAL MODEL; CHEMISTRY; FORECASTING; HUMAN; INFRARED SPECTROSCOPY; KINETICS; LIGHT; MATERIALS TESTING; MECHANICAL STRESS; RADIATION EXPOSURE; SURFACE PROPERTY; TEMPERATURE;

BISPHENOL A-GLYCIDYL METHACRYLATE; COMPOSITE RESINS; DENTAL MATERIALS; FORECASTING; GLASS; HUMANS; KINETICS; LIGHT; MATERIALS TESTING; METHACRYLATES; MODELS, CHEMICAL; POLYETHYLENE GLYCOLS; POLYMERS; POLYMETHACRYLIC ACIDS; SILANES; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; STRESS, MECHANICAL; SURFACE PROPERTIES; TEMPERATURE; TERPENES;

EID: 33745713999     PISSN: 01095641     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.dental.2006.02.009     Document Type: Article

References (51)

1. Ahn K.-D., Chung C.-M., and Kim Y.-H. Synthesis and photopolymerization of multifunctional methacrylates derived from Bis-GMA for dental applications. J Appl Polym Sci 71 (1999) 2033-2037
2. Klee J.E., Neidhart F., Flammersheim H.-J., and Mulhaupt R. Monomers for low shrinking composites, 2a: synthesis of branched methacrylates and their application in dental composites. Macromol Chem Phys 200 (1999) 517-523
3. Chung C.-M., Kim J.-G., Kim M.-S., Kim K.-M., and Kim K.-N. Development of a new photocurable composite resin with reduced curing shrinkage. Dent Mater 18 (2002) 174-178
4. Chung C.-M., Kim M.-S., Kim J.-G., and Jang D.-O. Synthesis and photopolymerization of trifunctional methacrylates and their application as dental monomers. J Biomed Mater Res 62 (2002) 622-627
5. Khatri C.A., Stansbury J.W., Schultheisz C.R., and Antonucci J.M. Synthesis, characterization and evaluation of urethane derivatives of Bis-GMA. Dent Mater 19 (2003) 584-588
6. Kim Y., Kim C.K., Cho B.H., Son H.H., Um C.M., and Kim O.Y. A new resin matrix for dental composite having low volumetric shrinkage. J Biomed Mater Res Part B: Appl Biomater 70B (2004) 82-90
7. Chen M.-H., Chen C.-R., Hsu S.-H., Sun S.-P., and Su W.-F. Low shrinkage light curable nanocomposite for dental restorative material. Dent Mater 22 2 (2006) 138-145
8. Satsangi N., Rawls H.R., and Norling B.K. Synthesis of low-shrinkage polymerizable liquid-crystal monomers. J Biomed Mater Res Part B: Appl Biomater 71B (2004) 153-158
9. Watts D.C., and Al Hindi A. Intrinsic 'soft-start' polymerization shrinkage-kinetics in an acrylate-based resin-composite. Dent Mater 15 (1999) 39-45
10. Lim B.-S., Ferracane J.L., Sakaguchi R.L., and Condon J.R. Reduction of polymerization contraction stress for dental composites by two-step light-activation. Dent Mater 18 (2002) 436-444
11. Condon J.R., and Ferracane J.L. Reduction of composite contraction stress through non-bonded microfiller particles. Dent Mater 14 (1998) 256-260
12. Condon J.R., and Ferracane J.L. Reduced polymerization stress through non-bonded nanofiller particles. Biomaterials 23 (2002) 3807-3815
13. Torstenson B., and Oden A. Effects of bonding agent types and incremental techniques on minimizing contraction gaps around resin composites. Dent Mater 5 4 (1989) 218-223
14. Prati C., and Montanari G. Comparative microleakage study between the sandwich and conventional three-increment techniques. Quintessence Int 20 8 (1989) 587-594
15. Saunders W.P., Strang R., and Ahmad I. Effect of composite resin placement and use of an unfilled resin on the microleakage of two dentin bonding agents. Am J Dent 3 4 (1990) 153-156
16. Krejci I., and Lutz F. Marginal adaptation of Class V restorations using different restorative techniques. J Dent 19 1 (1991) 24-32
17. Crim G.A. Microleakage of three resin placement techniques. Am J Dent 4 2 (1991) 69-72
18. Santini A., Plasschaert A.J., and Mitchell S. Effect of composite resin placement techniques on the microleakage of two self-etching dentin-bonding agents. Am J Dent 14 3 (2001) 132-136
19. St Georges A.J., Wilder Jr. A.D., Perdigao J., and Swift Jr. E.J. Microleakage of Class V composites using different placement and curing techniques: an in vitro study. Am J Dent 15 4 (2002) 244-247
20. Mullejans R., Lang H., Schuler N., Baldawi M.O., and Raab W.H. Increment technique for extended Class V restorations: an experimental study. Oper Dent 28 4 (2003) 352-356
21. Loguercio A.D., Reis A., and Ballester R.Y. Polymerization shrinkage: effect of constraint and filling technique in composite restorations. Dent Mater 20 3 (2004) 236-243
22. Cook W.D. Photopolymerization kinetics of dimethacrylates using the camphorquinone/amine initiator system. Polymer 33 3 (1992) 600-609
23. Maffezzoli A., Della Pietra A., Rengo S., Nicolais L., and Valletta G. Photopolymerization of dental composite matrices. Biomaterials 15 15 (1994) 1221-1228
24. Nie J., Rabek J.F., and Linden L.-A. Photopolymerization of poly (melamine-co-formaldehyde) acrylate for dental restorative resins. Polym Int 48 (1999) 129-136
25. Khudyakov I.V., Legg J.C., Purvis M.B., and Overton B.J. Kinetics of photopolymerization of acrylates with functionality of 1-6. Ind Eng Chem Res 38 (1999) 3354-3359
26. Lee I.B., and Um C.M. Thermal analysis on the cure speed of dual cured resin cements under porcelain inlays. J Oral Rehab 28 (2001) 186-197
27. Stansbury J.W., and Dickens S.H. Network formation and compositional drift during photo-initiated copolymerization of dimethacrylate monomers. Polymer 42 (2001) 6363-6369
28. Atai M., Watts D.C., and Atai Z. Shrinkage strain-rates of dental resin-monomer and composite systems. Biomaterials 26 (2005) 5015-5020
29. Kamal M.R., and Sourour S. Kinetic and thermal characterization of thermoset cure. Polym Eng Sci 13 1 (1973) 59-64
30. Kamal M.R. Thermoset characterization for moldability analysis. Polym Eng Sci 14 3 (1974) 231-239
31. Söderholm K.J.M. Influence of silane treatment and filler fraction on thermal expansion of composite resins. J Dent Res 63 11 (1984) 1321-1326
32. Li Y., Swartz M.L., Philips R.W., Moore B.K., and Roberts T.A. Effect of filler content and size on the properties of composites. J Dent Res 64 12 (1985) 1396-1401
33. Germain S.S.T., Swartz M.L., Philips R.W., Moore B.K., and Roberts T.A. Properties of microfilled composite resins as influenced by filler content. J Dent Res 64 2 (1985) 155-160
34. Chung K.-H., and Greener E.H. Correlation between degree of conversion, filler concentration and mechanical properties of posterior composite resins. J Oral Rehab 17 (1990) 487-494
35. Taylor D.F., Kalachandra S., Sankarapandian M., and McGrath J.E. Relationship between filler and matrix resin characteristics and the properties of uncured composite pastes. Biomaterials 19 (1998) 197-204
36. Kobayashi M., Shinzato S., Kawanabe K., Neo M., Matsushita M., Kokubo T., Kikutani T., and Nakamura T. Alumina powder/Bis-GMA composite: effect of filler content on mechanical properties and osteoconductivity. J Biomed Mater Res 49 (2000) 319-327
37. Lim B.-S., Ferracane J.L., Condon J.R., and Adey J.D. Effect of filler fraction and filler surface treatments on wear of micro filled composites. Dent Mater 18 (2002) 1-11
38. Atai M., Nekoomanesh M., Hashemi S.A., and Amani S. Physical and mechanical properties of an experimental dental composite based on a new monomer. Dent Mater 20 (2004) 663-668
39. Watts D.C., and Cash A.J. Kinetic measurements of photo-polymerization contraction in resins and composites. Meas Sci Technol 2 (1991) 788-794
40. Lovell L.G., Stansbury J.W., Syrpes D.C., and Bowman C.N. Effects of composition and reactivity on the reaction kinetics of dimethacrylate/dimethacrylate copolymerizations. Macromolecules 32 (1999) 3913-3921
41. Andrzejewska E. Photopolymerization kinetics of multifunctional monomers. Prog Polym Sci 26 (2001) 605-665
42. Watts D.C. Reaction kinetics and mechanics in photo-polymerised networks. Dent Mater 21 (2005) 27-35
43. Odian G. Principle of polymerization. 2nd ed. (1981), John Wiley & Sons, Inc.
44. Anseth K.S., Wang C.M., and Bowman C.N. Kinetic evidence of reaction diffusion during the polymerization of multi (meth) acrylate monomers. Macromolecules 27 (1994) 650-655
45. Andrzejewska E., Linden L.-A., and Rabek J.F. Modelling the kinetics of photoinitiated polymerization of di(meth)acrylates. Polymer Int 42 (1997) 179-187
46. Maffezzoli A., and Terzi R. Effect of irradiation intensity on the isothermal photopolymerization kinetics of acrylic resins for stereolithography. Thermochim Acta 321 (1998) 111-121
47. Lecamp L., Youssef B., Bunel C., and Lebaudy P. Photoinitiated polymerization of dimethacrylate oligomers: 2. Kinetic studies. Polymer 40 (1999) 1403-1409
48. Waters D.N., and Paddy J.L. Equations for isothermal differential scanning calorimetric curves. Anal Chem 60 (1988) 53-57
49. Weinmann W., Thalacker C., and Guggenberger R. Siloranes in dental composites. Dent Mater 21 (2005) 68-74
50. Halvorson R.H., Erickson R.L., and Davidson C.L. The effect of filler and silane content on conversion of resin-based composite. Dent Mater 19 (2003) 327-333
51. ®. 5th ed. Germany: Degussa; 1997.