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Volumn , Issue 26, 2006, Pages 2759-2761

Vapor phase inclusion of ferrocene and its derivative in a microporous metal-organic porous material and its structural characterization by single crystal X-ray diffraction

Author keywords

[No Author keywords available]

Indexed keywords

FERROCENE; FERROCENE DERIVATIVE; METAL; ORGANIC COMPOUND;

EID: 33745675492     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b604925g     Document Type: Article
Times cited : (74)

References (53)
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    • J. Solid State Chem., 2005, 178, 2409-2573
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    • 0037119726 scopus 로고    scopus 로고
    • The formation of silver nanoparticles on the surface of metal-organic porous materials has been reported:
    • K. Biradha M. Fujita Angew. Chem., Int. Ed. 2002 41 3392 3395
    • (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 3392-3395
    • Biradha, K.1    Fujita, M.2
  • 45
    • 4544259110 scopus 로고    scopus 로고
    • However, the focus of these studies, which usually involve trivial guests such as water, alcohols and benzene, are on the reversible transformation of framework structures
    • T. K. Maji K. Uemura H.-C. Chang R. Matsuda S. Kitagawa Angew. Chem., Int. Ed. 2004 43 3269 3272
    • (2004) Angew. Chem., Int. Ed. , vol.43 , pp. 3269-3272
    • Maji, T.K.1    Uemura, K.2    Chang, H.-C.3    Matsuda, R.4    Kitagawa, S.5
  • 50
    • 0001174432 scopus 로고
    • The Cp rings of the ferrocene molecule, lying on a crystallographic three-fold axis, are disordered over three sites. Five carbon atoms of the Cp rings were initially located from a difference electron density map and refined isotropically, with a constraint to have a regular pentagon (d = 1.42 Å). Recently, adsorbed hydrogen molecules have been found to occupy a similar site with three-fold symmetry (α site):
    • P. Seiler J. D. Dunitz Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1982 38 1741 1745
    • (1982) Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. , vol.38 , pp. 1741-1745
    • Seiler, P.1    Dunitz, J.D.2
  • 52
    • 33745655438 scopus 로고    scopus 로고
    • The diffraction data clearly revealed the framework of MOF-5 with a = 25.718 (3) Å; however, the guest molecules could not be located due to extensive disorder, which may be due to symmetry-mismatching for the 5 guest molecules residing in a single cube-like pore (having four- and three-fold symmetry)
    • The diffraction data clearly revealed the framework of MOF-5 with a = 25.718 (3) Å; however, the guest molecules could not be located due to extensive disorder, which may be due to symmetry-mismatching for the 5 guest molecules residing in a single cube-like pore (having four- and three-fold symmetry)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.