Effect of interfacial structures on ionic conductivity in particle-dispersed composite electrolytes

Advanced Powder Technology

Volumn 17, Issue 3, 2006, Pages 257-275

  Shirakawa, Yoshiyuki ^a   Konishi, Akira ^a   Kadota, Kazunori ^a   Harada, Satoshi ^a   Shimosaka, Atsuko ^a   Hidaka, Jusuke ^a  

^a DOSHISHA UNIVERSITY   (Japan)

Author keywords

Activation energy; Hetero interface; Ionic conduction; Non equilibrium molecular dynamics

Indexed keywords

ACTIVATION ENERGY; COMPUTER SIMULATION; ELECTROLYTES; INTERFACES (MATERIALS); MOLECULAR DYNAMICS; SODIUM COMPOUNDS;

DIFFUSION CONSTANTS; HETERO-INTERFACE; NON-EQUILIBRIUM MOLECULAR DYNAMICS; VACANCIES;

IONIC CONDUCTION;

EID: 33745648792     PISSN: 09218831     EISSN: None     Source Type: Journal    
DOI: 10.1163/156855206777213429     Document Type: Article

References (28)

1. Y. Tsuchiya, S. Tamaki and Y. Waseda, Structural study of superionic phase of AgI. J. Phys. C: Solid State Phys. 12, 5361-5369 (1979).
2. 2O-LiCl glass, Jpn. J. Appl. Phys. 37, 2808-2811 (1998).
3. C. C. Liang, Conduction characteristics of the lithium iodide-aluminum oxide solid electrolytes. J. Electrochem. Soc. 120, 1289-1292 (1973).
4. T. Jow and J. B. Wagner, Jr.. The effect of dispersed alumina particles on the electrical conductivity of cuprous chloride, J. Electrochem. Soc. 126, 1963-1972 (1979).
5. 3-dispersed AgI. J. Electrochem. Soc. 128, 6-12 (1981).
6. F. W. Poulsen and P. J. Moller, Properties of LiI-alumina composite electrolytes, Solid State Ionics 9/10, 119-122(1983).
7. 3 composite electrolyte, Mater. Res. Bull. 22, 269-274 (1987).
8. 3 composites, J. Electrochem. Soc. 142, 3469-3473 (1995).
9. 2, Solid State Ionics 35. 241-245 (1989).
10. 3, J. Solid State Chem. 109, 15-21 (1994).
11. Y. Shirakawa, M. Satake, A. Shimosaka, J. Hidaka and M. Kusakabe. Electronic properties of hybrid materials consisting of N-type nanocrystals and amorphous selenium matrix, J. Chem. Engng, Japan 35, 63-67 (2002).
12. F. G. Furni and M. P. Tosi, Ionic sizes and Born repulsive parameters in the NaCl-type alkali halides. I. The Huggins-Mayer and Pauling forms, J. Phys. Chem. Solids 25, 31-43 (1964).
13. 3 grain boundaries with Mg, Ca and Si segregation, J. Cerem. Soc., Japan 107, 727-732 (1999).
14. A. Honda, K. Matsunaga and H. Matsubara, Molecular dynamics simulation of an intergranular glass phase in alumina based ceramics, J. Japan Inst. Metals 64, 1113-1119 (2000).
15. 2, Mol. Simul. 6, 239-244 (1991).
16. J. B. Phipps, D. L. Johnson and D. H. Whitmore, Effect of composition and imperfections on ion transport in lithium iodide, Solid State Ionics 5. 393-396 (1981).
17. 2 composites, Solid State Ionics 9/10, 123-130 (1983).
18. N. J. Dudney. Enhancement ionic conductivity in composite electrolytes. Solid State Ionics 28-30, 1065-1072 (1988).
19. W. D. Kingery, H. K. Bowen and D. R. Uhlmann, Introduction to Ceramics, 2nd edn. Wiley. New York (1976).
20. J. M. Ziman, Principle of the Theory of Solids, 2nd edn. Cambridge University Press, Cambridge (1976).
21. M. Kiselev and K. Heinzinger, Molecular dynamics simulation of a chloride ion in water under the influence of an external electric field, J. Chem. Phys. 105, 650-657 (1996).
22. J. Petravic and J. Delhommelle, Conductivity of molten sodium chloride and its supercritical vapour in strong DC electric fields, J. Chem. Phys. 118, 7477-7485 (2003).
23. J. Petravic and J. Delhommelle, Conductivity of molten sodium chloride in an alternating electric field, J. Chem. Phys. 119, 8511-8518 (2003).
24. T. Koishi and S. Tamaki, Partial conductivities of a molten salt based on Langevin equation, J. Phys. Soc., Japan 68, 964-971 (1999).
25. C. Kittel, Introduction to Solid State Physics, 6th edn. Wiley, New York (1986).
26. W. Bollmann, On the geometry of grain and phase boundary I: general theory, Philos. Mag. 16, 363-381 (1967).
27. W. Bollmann, On the geometry of grain and phase boundary II: application of general theory, Philos. Mag. 16, 383-399 (1967).
28. H. Suzuki, H. Matsubara, J. Kishino and T. Kondoh, Simulation of surface and grain boundary properties of alumina by molecular dynamics method, J. Ceram. Soc., Japan 106, 1215-1222 (1998).