The effect of sodium on the solubilities of metals in silicate melts

American Mineralogist

Volumn 91, Issue 5-6, 2006, Pages 762-771

  Borisov, Alexander ^a,c   Lahaye, Yann ^b   Palme, Herbert ^c  

^a INSTITUTE OF GEOLOGY OF ORE DEPOSITS   (Russian Federation)

^b GOETHE UNIVERSITY   (Germany)

^c UNIVERSITY OF COLOGNE   (Germany)

Author keywords

Experimental petrology; Melt properties; New technigue; Thermodynamics

Indexed keywords

COBALT; FELDSPAR; IRON; IRON OXIDES; MELTING; NICKEL; PALLADIUM COMPOUNDS; SILICATES; SODIUM COMPOUNDS; SOLUBILITY; THERMODYNAMICS;

EUTECTIC COMPOSITION; EXPERIMENTAL DEVICES; EXPERIMENTAL PETROLOGY; FIXED TEMPERATURE; MELT PROPERTIES; NEW TECHNIGUE; OXIDIZING CONDITIONS; PARTIAL MELTING;

SODIUM;

PETROLOGY; SILICATE MELT; SODIUM; SOLUBILITY; THERMODYNAMICS;

EID: 33745455489     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2006.1977     Document Type: Article

References (34)

1. Baker, M.B. and Stolper, E.M. (1994) Determining the composition of high-pressure mantle melts using diamond aggregates. Geochimica et Cosmochimica Acta, 58, 2811-2827.
2. Baker, M.B., Hirschmann, M.M., Ghiorso, M.S., and Stolper, E.M. (1995) Composition of near-solidus peridotite melts from experiments and thermodynamic calculations. Nature, 375, 308-311.
3. Borisov, A. (2001) Loop technique: dynamic of metal/melt equilibration. Mineralogy and Petrology, 71, 87-94.
4. Borisov, A. and Palme, H. (2000) Solubilities of noble metals in iron-containing silicate melts as derived from experiments in iron-free systems. American Mineralogist, 85, 1665-1673.
5. Borisov, A., Palme, H., and Spettel, B. (1994) Solubility of palladium in silicate melts: implications for core formation in the Earth. Geochimica et Cosmochimica Acta, 58, 705-716.
6. 2 on Pd, Ni, and Fe solubilities in silicate melts. American Mineralogist, 89, 564-571.
7. Bottinga, Y. and Weill, D.F. (1972) The viscosity of magmatic silicate liquids: a model for calculations. American Journal of Science, 272, 438-475.
8. Chamberlin, L., Beckett, J.R., and Stolper, E. (1994) Pd-oxide equilibration: a new experimental method for the direct determination of oxide activities in melts and minerals. Contributions to Mineralogy and Petrology, 116, 169-181.
9. Corrigan, G. and Gibb, F.G.F. (1979) The loss of Fe and Na from a basaltic melt during experiments using the wire-loop method. Mineralogical Magazine, 43, 121-126.
10. Courtial, P., Gottsmann, J., Holzheid, A., and Dingwell, D.B. (1999) Partial molar volumes of NiO and CoO liquids: implications for the pressure dependence of metal - silicate partitioning. Earth and Planetary Science Letters, 171, 171-183.
11. Darken, L.S. and Gurry, R.W. (1945) The system iron-oxygen. I. The wüstite field and related equilibria. Journal American Chemical Society, 67, 1398-1412.
12. Dingwell, D.B., O'Neill, H.St.C., Ertel, W., and Spettel, B. (1994) The solubility and oxidation state of Ni in silicate melts at low oxygen fugacities: results using a mechanically assisted equilibration technique. Geochimica et Cosmochimica Acta, 58, 1967-1974.
13. Donaldson, C.H., Williams, R.J., and Lofgren, G. (1975) A sample holding technique for study of crystal growth in silicate melts. American Mineralogist, 60, 324-326.
14. 8]-FeO liquids. Geochimica et Cosmochimica Acta, 52, 1827-1834.
15. Draper, D.S. and Green, T.H. (1999) P-T phase relations of silicic, alkaline, aluminous liquids: new results and applications to mantle melting and metasomatism. Earth and Planetary Science Letters, 170, 255-268.
16. Ertel, W., Dingwell, D.B., and O'Neill, H.St.C. (1996) Solubility of tungsten in a haplobasaltic melt as function of temperature and oxygen fugacity. Geochimica et Cosmochimica Acta, 60, 1171-1180.
17. Ertel, W., Dingwell, D.B., and O'Neill, H.St.C., (1997) Compositional dependence of the activity of nickel in silicate melts. Geochimica et Cosmochimica Acta, 61, 4707-4721.
18. Falloon, T.J., Green, D.H., O'Neill, H.St.C., and Ballhaus, C.G. (1996) Quest for low-degree mantle melts (Scientific Correspondence). Nature, 381, 285.
19. Falloon, T.J., Green, D.H., O'Neill, H.St.C., and Hibberson, W.O. (1997) Experimental tests of low degree peridotite partial melt compositions: Implications for the nature of anhydrous near-solidus. Earth and Planetary Science Letters, 152, 149-162.
20. Georges, P., Libourel, G., and Deloule, E. (2000) Experimental constraints on alkali condensation in chondrule formation. Meteoritics and Planetary Science, 35, 1183-1188.
21. Hess, P.C. (1995) Thermodynamic mixing properties and the structure of silicate melts. In J.F.Stebbins, P.F. McMillan, and D.B. Dingwell, Eds., Structure, dynamics and properties of silicate melts, 32, p. 145-189. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
22. Hirschmann, M.M., Baker, M.B., and Stolper, E.M. (1998) The effect of alkalis on the silica content of mantle-derived melts. Geochimica et Cosmochimica Acta, 62, 883-902.
23. Holzheid, A., Palme, H., and Chakraborty, S.(1997) The activities of NiO, CoO, and FeO in silicate melts. Chemical Geology, 139, 21-38.
24. Lewis, R.D., Lofgren, G.E., Franzen, H.F., and Windom, K.E. (1993) The effect of Na vapor on the Na content of chondrules. Meteoritic, 28, 622-628.
25. Mysen, B.O. and Frantz, J.D. (1993) Structure and properties of alkali silicate melts at magmatic temperatures. European Journal of Mineralogy, 5, 393-407.
26. 05 in silicate melts. American Mineralogist, 90, 497-501.
27. 3 in silicate melts. Chemical Geology, 186, 151-181.
28. 4 olivine solid solutions. Contributions to Mineralogy and Petrology, 146, 308-325.
29. Paul, A. and Douglas, R.W. (1965) Ferrous-ferric equilibrium in binary alkali silicate glasses. Physics and Chemistry of Glasses, 6, 207-211.
30. Pretorius, E.B. and Muan, A. (1992) Activity of nickel (II) oxide in silicate melts. Journal of the American Ceramic Society, 75, 1490-1496.
31. 2. Geochimica et Cosmochimica Acta, 49, 637-649.
32. Stebbins, J.F., McMillan, P.F., and Dingwell, D.B., Eds. (1995) Structure, dynamics and properties of silicate melts, 32. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
33. 2+, between olivine and silicate melts: compositional dependence of partition coefficient Geochimica et Cosmochimica Acta, 42, 1829-1844.
34. Tsuchiyama, A., Nagahara, H., and Hushiro, I. (1981) Volatilization of sodium from silicate melt spheres and its application to the formation of chondrules. Geochimica et Cosmochimica Acta, 45, 1357-1367.