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33745446424
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note
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The tip is coated with Apiezon wax using standard procedure to prevent large electrochemical leakage current.
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18
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33745453331
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note
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Following the procedure by Nichols and Schiffrin (ref 8), we have performed 15 s self-assembly from 0.05 mM methanolic solution of a n-thiol or α,ω-alkanedithiol. The samples were subsequently rinsed with methanol and water and transferred to electrochemical cell.
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19
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33244458255
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Li, H.L.1
He, J.2
Hihath, J.3
Xu, B.4
Lindsay, S.M.5
Tao, N.6
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20
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33745445386
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note
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Large faradaic currents were observed for the tip potentials <-1.1V due to hydrogen evolution process thus tunneling measurements were not possible beyond this potential.
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21
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0031439098
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Slowinski, K.; Chamberlain, R. V.: Miller, C. J.; Majda, M. J. Am. Chem. Soc. 1997, 119, 11910.
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Slowinski, K.1
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Majda, M.4
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22
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33745469521
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note
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6-SH 0.7 ± 0.3 nm.
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