Mechanism of the diphenyldisulfone-catalyzed isomerization of alkenes. Origin of the chemoselectivity: Experimental and quantum chemistry studies

Journal of the American Chemical Society

Volumn 128, Issue 24, 2006, Pages 7782-7795

  Marković, Dean ^b   Varela Alvarez, Adrián ^a   Sordo, José Angel ^a   Vogel, Pierre ^b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; IONIZATION; ISOMERIZATION; ORGANIC COMPOUNDS; QUANTUM THEORY; REACTION KINETICS;

METHYLIDENECYCLOPENTANE; QUANTUM CHEMISTRY; TERMINAL ALKENES;

OLEFINS;

1 METHYLCYCLOPENTENE; ALKENE; ALLYL COMPOUND; CYCLOPENTANE DERIVATIVE; CYCLOPENTENE DERIVATIVE; DEUTERIUM; DEUTERIUM OXIDE; DIPHENYLDISULFONE; HYDROGEN; ISOBUTYLENE; METHYLIDENECYCLOPENTANE; POLYSULFONE; PROPYLENE; RADICAL; SULFINIC ACID DERIVATIVE; SULFONE DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL PARAMETERS; CHEMOSELECTIVITY; CONFORMATIONAL TRANSITION; DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; DEUTERIUM HYDROGEN EXCHANGE; ELECTRON TRANSPORT; ELIMINATION REACTION; ENERGY; EXPERIMENTATION; HYDROGEN EXCHANGE; IONIZATION; ISOMERIZATION; KINETIC DEUTERIUM ISOTOPIC EFFECT; KINETICS; PROTON TRANSPORT; QUANTUM CHEMISTRY; REACTION ANALYSIS;

EID: 33745406036     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0579210     Document Type: Article

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