Thermodynamic evaluation and optimization of the Ca-Si system

Journal of Phase Equilibria and Diffusion

Volumn 27, Issue 3, 2006, Pages 220-230

  Heyrman, Matthias ^a   Chartrand, Patrice ^a  

^a ÉCOLE POLYTECHNIQUE DE MONTRÉAL   (Canada)

Author keywords

Ca Si system; Modified Quasichemical Model; Thermodynamic database; Thermodynamic modeling

Indexed keywords

OPTIMIZATION; PHASE DIAGRAMS; PHASE EQUILIBRIA; SPECIFIC HEAT; STOICHIOMETRY; THERMODYNAMIC PROPERTIES; VAPOR PRESSURE;

CA-SI SYSTEM; MODIFIED QUASICHEMICAL MODEL; THERMODYNAMIC DATABASE; THERMODYNAMIC MODELING;

CALCIUM ALLOYS;

EID: 33745351469     PISSN: 15477037     EISSN: None     Source Type: Journal    
DOI: 10.1361/154770306X109755     Document Type: Article

References (48)

1. 1909Tam: S. Tamara, Über Silicium-Calciumiegierungen (Silicon-Calcium Alloys), Z Anorg. Allg. Chem., 1909, 62, p 81-88
2. 1921Pill: N.B. Pilling, Vapor Pressure of Metallic Calcium, Phys. Rev., 1921, 18, p 362-368
3. 1921Woh: L. Wöhler and F. Müller, Calcium silicides, Z. Anorg. Allg. Chem., 1921, 120, p 49-70
4. 1926Woh: L. Wöhler and O. Schliephake, The Silicides of Calcium and Magnesium, Z. Anorg. Allg. Chem., 1926, 151, p 1-11
5. 1929Har: H. Hartmann and R. Schneider, Boiling Temperatures of Magnesium, Calcium, Strontium, Barium and Lithium, Z. Anorg. Allg. Chem., 1929, 180, 275-283, in German
6. 1934Rud: E. Rudberg, The Vapor Pressure of Calcium between 500 and 625°C, Phys. Rev., 1934, 46(9), p 763-767
7. 1947Sch: A. Schneider and H. Stobbe, private communication, 1947, values extracted from 1949Kub
8. 1949Kub: O. Kubaschewski and H. Villa, Heat of Formation of Binary Alkaline Earth Compounds, Z. Elektrochem., 1949, 53, p 32-40, in German
9. 1954Dou: P.E. Douglas, The Vapour Pressure of Calcium: I, Proc. Phys. Soc. (London) B, 1954, 67B(10), p 783-786
10. 1954Pri: Y.A. Priselkov and A.N. Nesmeyanov, Determination of the Vapor Pressures of Calcium and Strontium Below Their Melting Points by the Method of Tagged Atoms, Dokl. Akad. Nauk SSSR, 1954, 95, p 1207-1210, in Russian
11. 1954Tom: D.H. Tomlin, The Vapour Pressure of Calcium: II, Proc. Phys. Soc. (London) B, 1954, 67B(10), p 787-794
12. 1958Han: M. Hansen and K. Anderko, Ca-Si Calcium-Silicon, Constitution of Binary Alloys, 2nd ed., McGraw-Hill, New York, 1958, p 407-409
13. 2, Acta Metall., 1959, 7, p 261-267
14. 1962Shc: S.A. Shchukarev, M.P. Morozova, and G.F. Pron', Enthalpy of Formation of Compounds of Calcium with Elements of the Main Subgroup of Group IV, J. Gen. Chem. USSR, 1962, 32(7), p 2047-2049
15. 1962Smi: J.F. Smith, Determination of Thermodynamic Functions for the Formation of Binary Intermetallic Phases from VapourPressure Measurements, Symposium on Thermodynamics of Nuclear Materials, Vienna, Austria, 1962, IAEA, p 271-284
16. 1965Mas: V.P. Mashovets and L.V. Puchkov, Vapour Pressure of Liquid Magnesium and Calcium, J. Appl. Chem. USSR, 1965, 38(5), p 937-940
17. 1965Mur: V.G. Muradov, Measurement of Vapour Pressure of Solid Calcium by Spectroscopic Analysis of the Condensate, Russ. J. Phys. Chem., 1965, 39(1), p 86-87
18. 1967Boh: J. Bohdansky and H.E.J. Schins, Vapor Pressure of Different Metals in the Pressure Range of 50 to 4000 Torr, J. Phys. Chem., 1967, 71(2), p 215-217
19. 1967Mur: V.G. Muradov, P.V. Gel'd, and P.V. Kocherov, The Vapour Pressure of Calcium-Silicon Solid Solutions, Russ. J. Phys. Chem., 1967, 41(5), p 547-550
20. 1968Zvi: G.M. Zviadadze and M.V. Kereselidze, Thermodynamics of Formation of Calcium Bisilicide, Akad. Nauk Gruzinskoi SSR, 1968, 15, p 88-90, in Russian
21. 1969Bog: S.S. Bogoslovskii, V.K. Kulifeev, A.N. Stikhin, G.A. Ukhlinov, and A.N. Krestovnikov, Saturated Vapor Pressure of Calcium), Izv. Vyss. Uchebn. Zaved., Tsvetn. Metall., 1969, 12(6), p 52-55, in Russian
22. 1971Sch: H.E.J. Schins, R.W.M. van Wijk, and B. Dorpema, The Heat-Pipe Boiling-Point Method and the Vapor Pressure of Twelve Metallic Elements in the Range 10-104 Torr, Z. Metallk., 1971, 62(4), p 330-336
23. 1971Wyn: J.R. Wynnyckyj and L.M. Pidgeon, Activities in the Ca-Si System, Metall. Trans., 1971, 2, p 975-978
24. 1972Pet: V.S. Petrov and A.A. Shmykov, Vapor Pressure and Condensation Coefficient of Solid Calcium, Izv. Vyss. Uchebn. Zaved., Tsvetn. Metall., 15(6), p 74-78, in Russian
25. 1972Wyn1: J.R. Wynnyckyj and L.M. Pidgeon, Investigations on the Constitution of the Calcium-Silicon System, High Temp. Sci., 1972, 4, p 192-204
26. 1972Wyn2: J.R. Wynnyckyj, Correlations Between Temperature/ Composition and Pressure/Temperature Equilibrium Diagrams, High Temp. Sci., 1972, 4, p 205-211
27. 1974Mar: G. de Maria and V. Piacente, Vapor Pressures of Calcium and Strontium by Transpiration Method, J. Chem. Thermodynam., 1974, 6, p 1-7
28. 1974Sch1: E. Schürmann, H. Litterscheidt, and P. Fünders, Investigations of the Melting Equilibria of the Phase-Equilibrium Diagram Calcium-Silicon, Arch. Eisenhüttenwes., 1974, 45(6), p 367-371, in German
29. 1974Sch2: E. Schürmann, P. Fünders, and H. Litterscheidt, Vapour Pressure Curve of Liquid Calcium, Arch. Eisenhüttenwes., 1974, 45(7), p 433-436, in German
30. 1975Sch: E. Schürmann, P. Fünders, and H. Litterscheidt, Vapor Pressure of Calcium above Calcium-Silicon- and Calcium-Aluminum Melts and also above Calcium-Aluminum-Silicon Alloys, Arch. Eisenhüttenwes., 1975, 46(8), p 473-476, in German
31. 1982Sig: H. Sigmund, Solubilities of Magnesium and Calcium in Silicon, J. Electrochem. Soc.: Solid-State Sci. Technol. 1982, 129(12), p 2809-2812
32. 1985Cha: M.W. Chase, Jr., C.A. Davies, J.R. Downey, Jr., D.J. Frurip, R.A. McDonald, and A.N. Syverud, JANAF Thermochemical Tables, 3rd Ed., J. Phys. Chem. Ref. Data., 14, Suppl. 1, 1985
33. 1985Esi: Y.O. Esin, A.S. Demin, and P.V. Gel'd, Enthalpies of Formation of Liquid Alloys of the Systems Ca-(Si, Ge, Sn), Abstracts of Papers at the Fifth All-Union Conference on Thermodynamics of Metal Alloys (Moscow), 1985, p 18, in Russian
34. 1986Lee: Y.E. Lee, Calculation of Thermodynamic Properties of Ca-Si from the Phase Diagram, User Applications of Alloy Phase Diagrams, 1st ed., L. Kaufman, Ed., ASM International, 1986, p 97-104
35. 1986Pel: A.D. Pelton and M. Blander, Thermodynamic Analysis of Ordered Liquid Solutions by a Modified Quasichemical Approach - Application to Silicate Slags, Metall. Trans. B, 1986, 17B(4), p 805-815
36. 1988Sud: V.S. Sudavstsova and G.I. Batalin, Thermodynamic Properties of Binary Melts of the Systems Ca-Si(Sn), Inorg. Mater., 1988, 24(9), p 1352-1354
37. 1991Din: A.T. Dinsdale, SGTE Data for Pure Elements, Calphad, 1991, 15(4), p 317-425
38. 1994Ang: J.C. Anglezio, C. Servant, and I. Ansara, Contribution to the Experimental and Thermodynamic Assessment of the Al-Ca-Fe-Si system-I. Al-Ca-Fe, Al-Ca-Si, Al-Fe-Si and CaFe-Si Systems, Calphad, 1994, 18(3), p 273-309
39. 14Si,9 - A Zintl Phase with a Novel Two Dimensional Silicon Framework, Z. Anorg. Allg. Chem., 1996, 622, p 501-508
40. 1998Aff: M. Affronte, O. Laborde, G.L. Olcese, and A. Palenzona, Low Temperature Properties of Calcium Mono- and Disilicides, J. Alloys Compd., 1998, 274, p 68-73
41. 2000Can: F. Canepa, M. Napoletano, P. Manfrinetti, and A. Palenzona, Heat Capacity and Thermodynamic Properties of Some Ca Silicides, J. Alloys Compd, 2000, 299, p 20-23
42. 2000Man: P. Manfrinetti, M.L. Fornasini, and A. Palenzona, The Phase Diagram of the Ca-Si System, Intermetallics, 2000, 8, p 223-228
43. 2000Pel: A.D. Pelton, S.A. Degterov, G. Eriksson, C. Robelin, and Y. Dessureault, The Modified Quasichemical Model I-Binary Solutions, Metall. Trans. B, 2000, 31B, p 651-659
44. 2001Bru: S. Brutti, A. Ciccioli, G. Balducci, G. Gigli, P. Manfrinetti, and M. Napoletano, Thermodynamic Stabilities of Intermediate Phases in the Ca-Si System, J. Alloys Compd., 2001, 317-318, p 525-531
45. 2001Pel: A.D. Pelton and P. Chartrand, The Modified Quasi-Chemical Model: Part II. Multicomponent Solutions, Metall. Trans. A, 2001, 32A, p 1355-1360
46. 2002Bal: C.W. Bale, P. Chartrand, S.A. Decterov, G. Eriksson, K. Hack, R. Ben Mahfoud, J. Melançon, A.D. Pelton and S. Pe tersen, FactSage Thermochemical Software and Databases, Calphad, 2002, 26, p 189-228
47. 2003Gro: J. Gröbner, I. Chumak, and R. Schmid-Fetzer, Experimental Study of Ternary Ca-Mg-Si Phase Equilibria and Thermodynamic Assessment of Ca-Si and Ca-Mg-Si Systems, Intermetallics, 2003, 11, p 1065-1074
48. 2005Dro: J. Drowart, C. Chatillon, J. Hastie, and D. Bonnell, High-Temperature Mass Spectrometry: Instrumental Techniques, Ionization Cross-Sections, Pressure Measurements, and Thermodynamic Data, Pure Appl. Chem., 2005, 77(4), p 683-737