Interaction of the azole N-sodium derivatives with Freon-113: Synthesis of N-(2,2-dichlorotrifluoroethyl)azoles

Synthetic Communications

Volumn 36, Issue 14, 2006, Pages 1967-1972

  Petko, K ^a   Yagupolskii, L ^a  

^a INSTITUTE OF HYDROBIOLOGY   (Ukraine)

Author keywords

2,2 diclorotrifluoroethylation; Azoles; Freon 113

Indexed keywords

1,1,2 TRICHLORO 1,2,2 TRIFLUOROETHANE; N (2,2 DICHLOROTRIFLUOROETHYL)AZOLE DERIVATIVE; NITROGEN; PYRROLE DERIVATIVE; SODIUM DERIVATIVE; TETRABUTYLAMMONIUM; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL INTERACTION; REACTION ANALYSIS; SYNTHESIS;

EID: 33745300176     PISSN: 00397911     EISSN: 15322432     Source Type: Journal    
DOI: 10.1080/00397910600634050     Document Type: Article

References (8)

1. Leroux, F.; Jescke, P.; Schlosser, M. α-Fluorinated ethers, thioethers and amines: Anomerically biased species. Chem. Rev. 2005, 195, 827-853.
2. Yagupolskii, L. M.; Fedyuk, D. V.; Petko, K. I.; Rudyk, V. I.; Rudyuk, V. V. N-Trihalomethyl derivatives of benzimidazole, benzotriazole and indazole. J. Fluorine Chem. 2000, 106, 181-187.
3. Bissky, G.; Roschenthaler, G.-V.; Lork, E.; Barten, J.; Medebielle, M.; Staninets, V. I.; Kolomeitsev, A. A. Generation of heteroarylium-N- difluoromethylides and heteroaryl-N-difluoromethyl anions and their reactions with electrofiles: Heteroaryl and heteroarylium-N-difluoromethyl trimethylsilanes and a new heteroaryl-N-trifluoromethane. J. Fluorine Chem. 2001, 109, 173-181.
4. Petko, K. I.; Sokolenko, T. M.; Bezdudnii, A. V.; Yagupolskii, L. M. N-(2-bromotetrafluoroethyl) derivatives of five-membered nitrogen-containing heterocycles. J. Fluorine Chem. 2005, 126, 1342-1346.
5. Xiao, J.-C.; Chen, Q.-Y. Reaction of imidazole anion with difluorodiiodomethane and their products conversion in sulfiatodehalogenation system. Chinese J. Chem. 2003, 21, 1349-1355.
6. Li, X.-Y.; Ran, H.-Q.; Jiang, X.-K. N-Perhalofluoroalkylation of secondary amines by the reaction of amines and amides with perhalofluoroalkanes: Halophylic attack of nitrogen nucleophyle on C-Br bond. Tetrahedron Lett. 1987, 28, 3699-3703.
7. Wakselman, C.; Tordeux, M. Chemistry of haloperfluoroalkanes: Synthesis of fluorinated ethers or thioethers via radical or anionic intermediates. J. Org. Chem. 1985, 50, 4047-4051.
8. Clavel, J.-L.; Langlois, B.; Nantermet, R.; Tordeux, M.; Wakselman, C. Reactions of bromotrifluoromethane and related halides, part 12: Transformation of disulfides into perfluoroalkylsulfides in the presence of sulfoxylate anion radical precursors. J. Chem. Soc., Perkin Trans. 1 1992, 3371-3375.