X-ray photoelectron spectroscopic studies of dolomite surfaces exposed to undersaturated and supersaturated aqueous solutions

Geochimica et Cosmochimica Acta

Volumn 70, Issue 13, 2006, Pages 3342-3350

  Hu, Xiaoming ^a   Joshi, Pratik ^b   Mukhopadhyay, Sharmila M ^b   Higgins, Steven R ^a  

^a WRIGHT STATE UNIVERSITY   (United States)

^b Wright State University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL COMPOSITION; DOLOMITE; STOICHIOMETRY; X-RAY SPECTROSCOPY;

EID: 33745221009     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2006.04.022     Document Type: Article

References (43)

1. Ainsworth C.C., Friedrich D.M., Gassman P.L., Wang Z., and Joly A.G. Characterization of salicylate-alumina surface complexes by polarized fluorescence spectroscopy. Geochim. Cosmochim. Acta 62 4 (1998) 595-612
2. Arvidson R.S., and Mackenzie F.T. Tentative kinetic model for dolomite precipitation rate and its application to dolomite distribution. Aquatic Geochem. 2 (1997) 273-298
3. Baer D.R., Marmorstein A.M., Williford R.E., and Blanchard D.L. Comparison spectra for calcite by XPS. Surf. Sci. Spectra 1 (1993) 80-86
4. Baer D.R., and Moulder J.F. High resolution XPS spectrum of calcite (CaCO3). Surf. Sci. Spectra 2 (1993) 1-7
5. Brady P.V., Krumhansl J.L., and Papenguth H.W. Surface complexation clues to dolomite growth. Geochim. Cosmochim. Acta 60 (1996) 727-731
6. Brady P.V., Papenguth H.W., and Kelly J.W. Metal sorption to dolomite surfaces. Applied Geochem. 14 (1999) 569-579
7. Brown G.E., Henrich V.E., Casey W.H., Clark D.L., Eggleston C., Felmy A., Goodman D.W., Gratzel M., Maciel G., McCarthy M.I., Nealson K.H., Sverjensky D.A., Toney M.F., and Zachara J.M. Metal oxide surfaces and their interactions with aqueous solutions and microbial organisms. Chem. Rev. 99 1 (1999) 77-174
8. 2+ as an impurity in calcite growth. Science 290 (2000) 1134-1137
9. De Boer R.B. Stability of Mg-Ca carbonates. Geochim. Cosmochim. Acta 41 (1977) 265-270
10. De Leeuw N.H. Surface structures, stabilities, and growth of magnesian calcite: a computational investigation from the perspective of dolomite formation. Am. Mineral. 87 (2002) 679-689
11. Deelman J.C. Studies on irreversible geochemical reactions. No. 5. Dolomite formation: why thermodynamics failed. Neues Jahrbuch fuer Mineralogie, Abhandlungen 141 (1981) 30-58
12. El-Mofty S.E., Somasundaran P., and Viswanathan K.V. Ca/Mg enrichment of dolomite surface in aqueous solutions: solid/liquid ratio and mixing time effects. Miner. Metall. Process. 6 (1989) 96-99
13. Fenter P., Geissbuhler P., DiMasi E., Srajer G., Sorensen L.B., and Sturchio N.C. Surface speciation of calcite observed in situ by high-resolution X-ray reflectivity. Geochim. Cosmochim. Acta 64 7 (2000) 1221-1228
14. Gaines A.M. Protodolomite synthesis at 100 °C and atmospheric pressure. Science 183 (1974) 178-182
15. 3 materials. Mater. Res. Bull. 37 (2002) 1323-1332
16. Graf D.L., and Goldsmith J.R. Some hydrothermal syntheses of dolomite and protodolomite. J. Geol. 64 (1956) 173-186
17. Hartman P. On the growth of dolomite and kaolinite crystals. Neues jahrbuch fuer Mineralogie, Monatshefte 2 (1982) 84-92
18. Higgins S.R., Bosbach D., Eggleston C.M., and Knauss K.G. Kink dynamics and step growth on barium sulfate (001): a hydrothermal scanning probe microscopy study. J. Phys. Chem. B 104 30 (2000) 6978-6982
19. Higgins S.R., and Hu X. Self-limiting growth on dolomite: experimental observations with in-situ atomic force microscopy. Geochim. Cosmochim. Acta 69 (2005) 2085-2094
20. Hu X., Grossie D.A., and Higgins S.R. Growth and dissolution kinetics at the dolomite-water interface: an in-situ scanning probe microscopy study. Am. Mineral. 90 (2005) 963-968
21. 2 in the aqueous phase. Langmuir 10 (1994) 3587-3597
22. 3, an experimental study at 252-295 degrees C. Geochim. Cosmochim. Acta 41 2 (1977) 297-308
23. Knipe S.W., Mycroft J.R., Pratt A.R., Nesbitt H.W., and Bancroft G.M. X-ray photoelectron spectroscopic study of the water adsorption on iron sulphide minerals. Geochim. Cosmochim. Acta 59 6 (1995) 1079-1090
24. Lumsden D.N., Shipe L.G., and Lloyd R.V. Mineralogy and Mn geochemistry of laboratory-synthesized dolomite. Geochim. Cosmochim. Acta 53 (1989) 2325-2329
25. Nordstrom D.K., Plummer L.N., Langmuir D., Busenberg E., and May H.M. Revised chemical equilibrium data for major water-mineral reactions and their limitations. In: Melchior D.C., and Bassett R.L. (Eds). Chemical Modelling of Aqueous Systems II vol. 416 (1990), American Chemical Society 398-413
26. Pokrovsky O.S. Precipitation of calcium and magnesium carbonates from homogeneous supersaturated solutions. J. Cryst. Growth 186 (1998) 233-239
27. Pokrovsky O.S., and Schott J. Kinetics and mechanism of dolomite dissolution in neutral to alkaline solutions revisited. Am. J. Sci. 301 7 (2001) 597-626
28. Pokrovsky O.S., and Schott J. Surface chemistry and dissolution kinetics of divalent metal carbonates. Environ. Sci. Tech. 36 3 (2002) 426-432
29. Pokrovsky O.S., Schott J., and Thomas F. Dolomite surface speciation and reactivity in aquatic systems. Geochim. Cosmochim. Acta 63 19/20 (1999) 3133-3143
30. Powell C.J., Jablonski A., and Salvat F. NIST databases with electron elastic-scattering cross sections, inelastic mean free paths, and effective attenuation lengths. Surf. Interface Anal. 37 (2005) 1068-1071
31. Reeder R.J. Crystal growth effects in sedimentary carbonate minerals. Estudios Geol. 38 (1982) 179-183
32. Risthaus P., Bosbach D., Becker U., and Putnis A. Barite scale formation and dissolution at high ionic strength studied with Atomic Force Microscopy. Colloids Surf. A 191/3 (2001) 201-214
33. Rosenberg P.E., Burt D.M., and Holland H.D. Calcite-dolomite-magnesite stability relations in solutions: the effect of ionic strength. Geochim. Cosmochim. Acta 31 (1967) 391-396
34. Rosenberg P.E., and Holland H.D. Calcite-dolomite-magnesite stability relations in solutions at elevated temperatures. Science 145 (1964) 700-701
35. Scofield J.H. Hartree-Slater subshell photoionization cross-sections at 1254 and 1487 eV. J. Electron Spectrosc. 8 (1976) 129-137
36. Seah M.P., Gilmore I.S., and Spencer S.J. Quantitative XPS I. Analysis of X-ray photoelectron intensities from elemental data in a digital photoelectron database. J. Electron Spectrosc. 120 (2001) 93-111
37. Sibley D.F. Unstable to stable transformations during dolomitization. J. Geol. 98 (1990) 739-748
38. 2+ uptake by calcite, solid-state diffusion, and the formation of solid-solution: interface processes observed with near-surface sensitive techniques (XPS, LEED, and AES). Geochim. Cosmochim. Acta 56 (1992) 1941-1954
39. Smekal W., Werner W.S.M., and Powell C.J. Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy. Surf. Interface Anal. 37 (2005) 1059-1067
40. Teng H.H., Dove P.M., and De Yoreo J.J. Kinetics of calcite growth: surface processes and relationships to macroscopic rate laws. Geochim. Cosmochim. Acta 64 13 (2000) 2255-2266
41. Titiloye J.O., De Leeuw N.H., and Parker S.C. Atomistic simulation of the differences between calcite and dolomite surfaces. Geochim. Cosmochim. Acta 62 (1998) 2637-2641
42. Tribble J.S., Arvidson R.S., Lane III M., and Mackenzie F.T. Crystal chemistry, and thermodynamic and kinetic properties of calcite, dolomite, apatite, and biogenic silica: applications to petrologic problems. Sediment. Geol. 95 1-2 (1995) 11-37
43. 2+ on the kinetics of calcite precipitation and calcite crystal morphology. Chem. Geol. 163 (2000) 129-138