Experimental study of germanium adsorption on goethite and germanium coprecipitation with iron hydroxide: X-ray absorption fine structure and macroscopic characterization

Geochimica et Cosmochimica Acta

Volumn 70, Issue 13, 2006, Pages 3325-3341

  Pokrovsky, O S ^a   Pokrovski, G S ^a   Schott, J ^a   Galy, A ^b  

^a Environmental Research Observatory (ORE) HYBAM Centre IRD d'Ile de France   (France)

^b UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; GERMANIUM; GOETHITE; IRON HYDROXIDE; PRECIPITATION (CHEMISTRY);

EID: 33745205680     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2006.04.012     Document Type: Article

References (84)

1. Allison, J.D., Brown, D.S., Novo-Gradac, K.J., 1991. MINTEQA2/PRODEFA2, A geochemical assessment model for environmental systems: version 3.0 user's manual. U.S. EPA, Athens, GA, 106 p.
2. Anders A.M., Sletten R.S., Derry L.A., and Hallet B. Germanium/silicon ratios in the Copper River Basin, Alaska: weathering and partitioning in periglacial versus glacial environments. J. Geophys. Res. 108 No. F1 (2003) 6005
3. Ankudinov A.L., Ravel B., Rehr J.J., and Conradson S.D. Real-space multiple-scattering calculation and interpretation of X-ray-absorption near-edge structure. Phys. Rev. B58 (1998) 7565-7576
4. Baes Jr. C.F., and Mesmer R.E. The Hydrolysis of Cations (1976), Wiley
5. 9, the germanate analogue of the silicate mineral melanotekite. Acta Cryst. C54 (1998) 2-5
6. 2 and a comparison with other rutile-type structures. Acta Cryst. B27 (1971) 2133-2139
7. Bernstein L.R. Germanium geochemistry and mineralogy. Geochim. Cosmochim. Acta 49 (1985) 2409-2422
8. Bernstein L.R., and Waychunas G.A. Germanium crystal chemistry in hematite and goethite from the Apex Mine, Utah, and some new data on germanium in aqueous solution and in stottite. Geochim. Cosmochim. Acta 51 (1987) 623-630
9. Bibak A., and Borggaard O.K. Molybdenum adsorption by aluminum and iron oxides and humic acid. Soil Sci. 158 (1994) 323-328
10. Combes J.M., Manceau A., Calas G., and Bottero J.-Y. Formation of ferric oxides from aqueous solutions: a polyhedral approach by X-ray absorption spectroscopy: I. Hydrolysis and formation of ferric gels. Geochim. Cosmochim. Acta 53 (1989) 583-594
11. Cornell R.M., and Schwertmann U. The Iron: Structure, Properties, Reactions, Occurrences and Uses (1996), VCH, Weinheim
12. Cotton F.A., and Wilkinson G. Advanced Inorganic Chemistry (1966), Wiley
13. Davis C.C., Chen H.-W., and Edwards M. Modeling silica sorption to iron hydroxide. Environ. Sci. Technol. 36 (2002) 582-587
14. Derry L.A., Kurtz A.C., Ziegler K., and Chadwick O.A. Biological control of terrestrial silica cycling and export fluxes to watersheds. Nature 433 (2005) 728-731
15. Derry L.A., Pett-Ridge J.C., Kurtz A.C., and Troester J.W. Ge/Si and 87Sr/86Sr traces of weathering reactions and hydrological pathways in a tropical granitoid system. J. Geochem. Explor. 88 (2006) 271-274
16. Dietzel M. Interaction of polysilicic and monosilicic acid with mineral surfaces. In: Stober I., and Bucher K. (Eds). Water-Rock Interaction (2002), Kluwer Academic Publishers 207-235
17. Dzombak D.A., and Morel F.M.M. Surface Complexation Modeling-Hydrous Ferric Oxide (1990), Wiley
18. Elderfield H., and Schultz A. Mid-ocean ridge hydrothermal fluxes and the chemical composition of the ocean. Ann. Rev. Earth Planet. Sci. 24 (1996) 191-224
19. Farquhar M.L., Charnock J.M., Livens F.R., and Vaughan D.J. Mechanisms of arsenic uptake from aqueous solution by interaction with goethite, lepidocrocite, mackinawite, and pyrite: an X-ray absorption spectroscopy study. Environ. Sci. Technol. 36 (2002) 1757-1762
20. Fendorf S., Eick M.J., Grossl P., and Sparks D.L. Arsenate and chromate retention mechanisms on goethite. 1. Surface structure. Environ. Sci. Technol. 31 (1997) 315-320
21. Filippelli G.M., Carnahan J.W., Derry L.A., and Kurtz A. Terrestrial paleorecords of Ge/Si cycling derived from lake diatoms. Chem. Geol. 168 (2000) 9-26
22. Filius J.D., Hiemstra T., and Van Riemsdijk W.H. Adsorption of small weak organic acids on goethite: modeling of mechanisms. J. Colloid Interface Sci. 195 (1997) 368-380
23. Froelich P.N., Hambrick G.A., Andreae M.O., Mortlock R.A., and Edmond J.M. The geochemistry of inorganic germanium in natural waters. J. Geophys. Res. 90 (1985) 1133-1141
24. Froelich P.N., Blanc V., Mortlock R.A., Chilrud S.N., Dunstan W., Udomkit A., and Peng T.H. River fluxes of dissolved silica to the ocean were higher during glacials: Ge/Si in diatoms, rivers, and oceans. Paleoceanography 7 (1992) 739-767
25. Fuller C.C., Dadis J.A., and Waychunas G.A. Surface chemistry of ferrihydrite: Part 2. Kinetics of arsenate adsorption and coprecipitation. Geochim. Cosmochim. Acta 57 (1993) 2271-2282
26. Galy A., Pokrovsky O.S., Schott J. (2002) Ge-isotopic fractionation during its sorption on goethite: an experimental study. Abstracts of the VM Goldschmidt Conference. August 18-23, 2002, Davos, Switzerland. Suppl. Geochim. Cosmochim. Acta, 66 p. A259.
27. Glasauer S., Friedl J., and Schwertmann U. Properties of goethites prepared under acidic and basic conditions in the presence of silicate. J. Colloid Interface Sci. 216 (1999) 106-115
28. Goldberg S., Forster H.S., and Godfrey C.L. Molybdenum adsorption on oxides, clay minerals and soils. Soil Sci. Soc. Am. J. 60 (1996) 425-432
29. Goldschmidt V.M. Geochemistry (1958), Oxford University Press
30. Grafe M., Eick M.J., and Grossl P.R. Adsorption of arsenate(V) and arsenite(III) on goethite in the presence and absence of dissolved organic carbon. Soil Sci. Soc. Am. J. 65 (2001) 1680-1687
31. Harrison J.B., and Berkheiser V.E. Anion interactions with freshly prepared hydrous iron oxides. Clays Clay Minerals 30 (1982) 97-102
32. Hiemstra T., and Van Riemsdijk W.H. Surface structural ion adsorption modeling of competitive binding of oxyanions by metal (hydr)oxides. J. Colloid Interface Sci. 210 (1999) 182-193
33. 2. J. Appl. Phys. 49 (1978) 5473-5478
34. King S.L., Froelich P.N., and Jahnke R.A. Early diagenesis of germanium in sediments of the Antartic South Atlantic: in search of the missing Ge sink. Geochim. Cosmochim. Acta 64 (2000) 1375-1390
35. Kurtz A.C., Derry L.A., and Chadwick O.A. Germanium-silicon fractionation in the weathering environment. Geochim. Cosmochim. Acta 66 (2002) 1525-1537
36. Machesky M.L., Brian L., Bischoff B.L., and Anderson M.A. Calorimetric investigation of anion adsorption onto goethite. Environ. Sci. Technol. 23 (1989) 580-587
37. Machesky M.L., Wilson O., Andrade W.O., and Rosea A.W. Adsorption of gold(III)-chloride and gold(I)-thiosulfate anions by goethite. Geochim. Cosmochim. Acta 55 (1991) 769-776
38. 6 edges. Geochim. Cosmochim. Acta 59 (1995) 3647-3653
39. Manceau A., and Combes J.M. Structure of Mn and Fe oxides and oxy-hydroxides: a topological approach by EXAFS. Phys. Chem. Minerals 15 (1988) 283-295
40. Manceau A., and Charlet L. The mechanism of selenate adsorption on goethite and hydrous ferric oxide. J. Colloid Interface Sci. 168 (1994) 87-93
41. Manning B.A., Fendorf S.E., and Goldberg S. Surface structures and stability of arsenic(III) on goethite: Spectroscopic evidence for inner-sphere complexes. Environ. Sci. Technol. 32 (1998) 2383-2388
42. McManus J., Hammond D.E., Cummins K., Klinkhammer G.K., and Berelson W.M. Diagenetic Ge-Si fractionantion in continental margin environments: further evidence for a nonopal Ge sink. Geochim. Cosmochim. Acta 67 (2003) 4545-4557
43. Mortlock R.A., and Froelich P.N. Continental weathering of germanium: Ge/Si in the global river discharge. Geochim. Cosmochim. Acta 51 (1987) 2075-2082
44. Mortlock R.A., Froelich P.N., Feely R.A., Massoth G.J., Butterfield D.A., and Lupton J.E. Silica and germanium in Pacific Ocean hydrothermal vents and plumes. Earth Planet. Sci. Lett. 119 (1993) 365-378
45. Munoz M., Argoul P., and Farges F. Continuous Cauchy wavelet transform analyses of EXAFS spectra: a qualitative approach. Am. Miner. 88 (2003) 694-700
46. Murname R.J., Leslie B., Hammond D.E., and Stallard R.F. Germanium geochemistry in the southern California borderlands. Geochim. Cosmochim. Acta 53 (1989) 2873-2882
47. Murname R.J., and Stallard R.F. Germanium and silicon in rivers of the Orinoco drainage basin. Nature 344 (1990) 749-752
48. Newville M. IFEFFIT: interactive XAFS analysis and FEFF fitting. J. Synchrotron Radiat. 8 (2001) 322-324
49. Nishi F., and Takéuchi Y. The nature and variation of Ge-O bonding in germanates. Zeit. Kristallogr. 202 (1992) 251-259
50. O'Reilly S.E., Strawn D.G., and Sparks D.L. Residence time effects on arsenate adsorption/desorption mechanisms on goethite. Soil Sci. Soc. Am. J. 65 (2001) 67-77
51. Pazenkova N.I. Germaniferous limonite-forming mechanism. Doklady Acad. Sci. USSR, Earth Sci. Sections 173 (1967) 204-206 English translation
52. Pivovarov S. Surface structure and site density of the oxide-solution interface. J. Colloid Interface Sci. 196 (1997) 321-323
53. Poiarkova A.V. (1999) X-ray absorption fine structure Debye-Waller factors. Ph.D. thesis, University of Washington.
54. Poiarkova A.V., and Rehr J.J. Multiple-scattering X-ray-absorption fine-structure Debye-Waller factor calculations. Phys. Rev. B 59 (1999) 948-957
55. Pokrovski G.S., and Schott J. Thermodynamic properties of aqueous Ge(IV) hydroxide complexes from 25 to 350 °C: implications for the behavior of germanium and the Ge/Si ratio in hydrothermal fluids. Geochim. Cosmochim. Acta 62 (1998) 1631-1642
56. Pokrovski G.S., and Schott J. Experimental study of the complexation of silicon and germanium with aqueous organic species: implications for germanium and silicon transport and Ge/Si ratio in natural waters. Geochim. Cosmochim. Acta 62 (1998) 3413-3428
57. Pokrovski G.S., Martin F., Hazemann J.-L., and Schott J. An X-ray absorption fine structure spectroscopy study of germanium-organic ligand complexes in aqueous solution. Chem. Geol. 163 (2000) 151-165
58. Pokrovski G.S., Schott J., Farges F., and Hazemann J.-L. Iron(III)-silica interactions in aqueous solution: insights from X-ray absorption fine structure spectroscopy. Geochim. Cosmochim. Acta 67 (2003) 3559-3573
59. Pokrovski G.S., Roux J., Hazemann JL., and Testemale D. An X-ray Absorption spectroscopy study of argutite solubility and germanium aqueous speciation in hydrothermal fluids to 500 °C and 400 bar. Chem. Geol. 217 (2005) 127-145
60. Pokrovsky O.S., and Schott J. Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia). Chem. Geol. 190 (2002) 141-179
61. Pokrovsky O.S., Pokrovski G.S., and Schott J. Gallium(III) adsorption on carbonates and oxides: X-ray absorption fine structure spectroscopy and surface complexation modelling. J. Colloid Interface Sci. 279 (2004) 314-325
62. Pokrovsky O.S., Pokrovski G.S., Gélabert A., Schott J., and Boudou A. Speciation of zinc associated with diatoms using X-ray absorption spectroscopy. Environ. Sci. Technol. 39 (2005) 4490-4498
63. Pokrovsky O.S., Schott J., and Dupré B. Basalt weathering and trace elements migration in boreal Arctic zone. J. Geochem. Explor. 88 (2006) 304-307
64. Ravel B., and Newville M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchronron Radiat. 12 (2005) 537-541
65. Rietra R.P.J.J., Hiemstra T., Willem H., and Van Riemsdijk W.H. Comparison of selenate and sulfate adsorption on goethite. J. Colloid Interface Sci. 240 (2001) 384-390
66. 6. Am. Miner. 73 (1988) 657-661
67. Rustad J.R., and Hay B.P. A molecular dynamics study of solvated orthosilicic acid and orthosilicate anion using parameterized potentials. Geochim. Cosmochim. Acta 59 (1995) 1251-1257
68. Savenko A.V. Coprecipitation of phosphorus with iron hydroxide formed during mixing of submarine hydrothermal fluids with seawater. Geochem. Int. No. 9 (1995) 1383-1389
69. Savenko A.V. Aluminum behavior during the process of hydrothermal solutions mixing with the seawater: data of experimental modeling. Oceanology 3 No 5 (1996) 735-740
70. Savenko A.V. Coprecipitation of phosphorus, arsenic and vanadium with iron hydroxide in hydrothermal plumes. Dokl. Acad. Sci. Russ. 36 No 5 (1998) 679-681
71. 3-) with iron hydroxide in hydrothermal plumes. Geochem. Int. No. 3 (1999) 281-288
72. Savenko A.V. On the mechanism of mercury accumulation in metalliferous oceanic sediments. Geochem. Int. No. 9 (1999) 1022-1024
73. Savenko A.V. On the mechanism of boron accumulation in metalliferous oceanic sediments. Oceanology 4 No. 2 (2000) 217-220
74. Savenko A.V., and Volkov I.I. On the abiogenic precipitation of silica in the modern ocean. Geochem. Int. No. 6 (2003) 676-680
75. 2 solutions. Clay Minerals 11 (1976) 189-200
76. Shemesh A., Mortlock R.A., and Froelich P.N. Late Cenozoic Ge/Si record of marine biogenic opal: Implications for variations in riverine fluxes to the ocean. Paleoceanography 4 (1989) 221-234
77. Tréguer P., Nelson D.M., van Bennekom A.J., DeMaster D.J., Laynaert A., and Quéguiner B. The silica balance in the world ocean: a re-estimate. Science 268 (1995) 375-379
78. Vempati R.K., and Loeppert R.H. Influence of structural and adsorbed Si on the transformation of synthetic ferrihydrite. Clays Clay Minerals 37 (1989) 273-279
79. Viers J., Dupré B., Polvé M., Schott J., Dandurand J.-L., and Braun J.-J. Chemical weathering in in the drainage basin of a tropical watershed (Nsimi-Zoétélé site, Cameroon). Chem. Geol. 140 (1997) 181-206
80. Viollier R., Inglett P.W., Hunter K., Roychoudhury A.N., and Van Cappellen P. The ferrozine method revisited: Fe(II)/Fe(III) determination in natural waters. Appl. Geochem. 15 (2000) 785-790
81. Waychunas G.A., Rea B.A., Fuller C.C., and Davis J.A. Surface chemistry of ferrihydrate: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate. Geochim. Cosmochim. Acta 57 (1993) 2251-2269
82. Wyckoff R.W.G. (1963) Crystal Structures. vol. 1, second ed.. Interscience Publishers, New York, pp. 290-295.
83. 2 polymorphs. J. Synchrotron Radiat. 6 (1999) 1051-1058
84. Zhou L., and Kyte F.T. Are there any significant sinks in the marine Ge cycle other than biogenic opal?. Eos 72 (1991) 263-264 (abstr.)