The effect of very bulky groups on the equilibrium of penta- and hexa-coordinated phosphoranes

Phosphorus, Sulfur and Silicon and the Related Elements

Volumn 181, Issue 7, 2006, Pages 1493-1511

  Chandrasekaran, A ^a   Timosheva, Natalya V ^a   Holmes, Robert R ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

Cyclic sulfonyl derivatives; Hexacoordination; Phosphoranes; Steric effects; X ray crystallography

Indexed keywords

EID: 33745100829     PISSN: 10426507     EISSN: 15635325     Source Type: Journal    
DOI: 10.1080/10426500600683126     Document Type: Article

References (30)

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2. (b) For part 143, see N. V. Timosheva, A. Chandrasekaran, and R. R. Holmes, Inorg. Chem., 45, 3113 (2006).
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4. (b) R. R. Holmes, Acc. Chem. Res., 31, 535 (1998).
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19. (c) Y. Kimura, T. Kokura, and T. Saegusa, J. Org. Chem., 48, 3815 (1983).
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22. (b) N. V. Timosheva, T. K. Prakasha, A. Chandrasekaran, R. O. Day, and R. R. Holmes, Inorg. Chem., 34, 4525 (1995).
23. (a) P. Kommana, N. S. Kumar, (b) J. J. Vittal, E. G. Jayasree, E. D. Jemmis, and K. C. K. Swamy Organic Lett., 6, 145 (2004);
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28. (a) A. Chandrasekaran, P. Sood, and R. R. Holmes, Inorg. Chem., 37, 459 (1998);
29. (b) Many associative mechanisms are supported for phosphorus reactions proceeding through pentacoordinated excited states, see R. R. Holmes, Pentacoordinated Phosphorus - Reaction Mechanisms, Vol. II, ACS Monograph 176 (American Chemical Society, Washington, D.C., 1980);
30. (c) Structural aspects of these classes of compounds are summarized in the following: R. R. Holmes, Pentacoordinated Phosphorus - Structure and Spectroscopy, Volume I, ACS Monograph 175 (American Chemical Society, Washington, D.C., 1980).