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Volumn 47, Issue 29, 2006, Pages 5177-5180

Reactivity of γ-chloro-gem-trichloroalkanes with chromous chloride

Author keywords

Carbene; Chromium; Nozaki Hiyama allylation; Trichloroalkane

Indexed keywords

ALDEHYDE; ALKANE DERIVATIVE; ALLYL ALCOHOL; CHROMIUM CHLORIDE;

EID: 33745031820     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.05.045     Document Type: Article
Times cited : (4)

References (31)
  • 14
    • 33745017298 scopus 로고    scopus 로고
    • note
    • 2 as a grey powder was used for further reaction.
  • 15
    • 33745017547 scopus 로고    scopus 로고
    • note
    • 3), δ 142.8, 140.4, 138.5, 129.6, 127.4, 113.3, 74.1, 44.7, 30.4, 27.4, 27.1, 23.5, 21.6 ppm.
  • 16
    • 33745032405 scopus 로고    scopus 로고
    • note
    • Crystallographic data have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication numbers CCDC 295551. Copies of the data can be obtained free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: +44 (0) 1223 336033 or e-mail: deposit@ccdc.cam.ac.uk].
  • 17
    • 33745033434 scopus 로고    scopus 로고
    • note
    • 3J = 6.8 Hz).
  • 18
    • 33745039576 scopus 로고    scopus 로고
    • note
    • +).
  • 22
    • 33745041606 scopus 로고    scopus 로고
    • note
    • Alternatively the rehybridization may occur because the adjacent carbon is disubstituted and therefore more crowded than a simple methylene.
  • 25
    • 33745019720 scopus 로고    scopus 로고
    • note
    • For an example of a rehybridization induced by the coordination of a β oxygen atom to the metal, and the formation of a Fischer carbene complex, see Ref. 2d.
  • 26
    • 33745012221 scopus 로고    scopus 로고
    • note
    • +).
  • 27
    • 33745028249 scopus 로고    scopus 로고
    • note
    • +).
  • 29
    • 22244481029 scopus 로고    scopus 로고
    • Via a Zimmerman-Traxler 6-membered transition state; see:. Overman L.E. (Ed), John Wiley & Sons
    • Via a Zimmerman-Traxler 6-membered transition state; see:. Takai K. In: Overman L.E. (Ed). Organic Reactions Vol. 64 (2004), John Wiley & Sons 253-612
    • (2004) Organic Reactions , vol.64 , pp. 253-612
    • Takai, K.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.