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Volumn 41, Issue 8, 2006, Pages 1697-1724

The influence of the alkyl chain length and steric effect on stability constants and extractability of Co(II) complexes with 1-Alkyl-4(5)- methylimidazoles

Author keywords

1 alkyl 4 5 methylimidazoles; Co(II) complexes; Partition constants; Stability constants; Tetrahedral complexes

Indexed keywords

ALCOHOLS; COMPLEXATION; EXTRACTION; SOLUTIONS; TOLUENE;

EID: 33745015041     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390600675031     Document Type: Article
Times cited : (7)

References (35)
  • 1
    • 0034234167 scopus 로고    scopus 로고
    • Hydrometallurgy of strategic metals
    • Cote, G. (2000) Hydrometallurgy of Strategic Metals. Solvent Extr. Ion Exc., 18 (4): 703-727.
    • (2000) Solvent Extr. Ion Exc. , vol.18 , Issue.4 , pp. 703-727
    • Cote, G.1
  • 2
    • 0032666437 scopus 로고    scopus 로고
    • Extraction studies of cobalt(II) and nickel(II) from hydrochloric acid solutions using Na-cyanex 272: Separation of Co(II)/Ni(II) by the sodium salts of D2EHPA, PC-88A and cyanex 272 and their mixtures
    • Sarangi, K., Reddy, B.R., and Das, R.P. (1999) Extraction Studies of Cobalt(II) and Nickel(II) from Hydrochloric Acid Solutions using Na-Cyanex 272: Separation of Co(II)/Ni(II) by the Sodium Salts of D2EHPA, PC-88A and Cyanex 272 and their Mixtures. Hydrometallurgy, 52: 253-265.
    • (1999) Hydrometallurgy , vol.52 , pp. 253-265
    • Sarangi, K.1    Reddy, B.R.2    Das, R.P.3
  • 3
    • 0030148485 scopus 로고    scopus 로고
    • Extraction an selective stripping of molybdenum(VI) and vanadium(IV) from sulfuric acid solution containing aluminium(II), cobalt(II), nickel (II) and iron(II) by LIX 63 in exxsol D80
    • Zhang, P. and Inoue, K. (1996) Extraction an Selective Stripping of Molybdenum(VI) and Vanadium(IV) from Sulfuric Acid Solution Containing Aluminium(II), Cobalt(II), Nickel (II) and Iron(II) by LIX 63 in Exxsol D80. Hydrometallurgy, 41: 45-53.
    • (1996) Hydrometallurgy , vol.41 , pp. 45-53
    • Zhang, P.1    Inoue, K.2
  • 4
    • 0019928019 scopus 로고
    • Extraction of nickel, cobalt and other metals [Cu, Zn, Fe(III)] with a commercial b-diketone extradant
    • Przeszlakowski, S. and Wydra, H. (1982) Extraction of Nickel, Cobalt and Other Metals [Cu, Zn, Fe(III)] with a Commercial b-Diketone Extradant. Hydrometallurgy, 8: 49-64.
    • (1982) Hydrometallurgy , vol.8 , pp. 49-64
    • Przeszlakowski, S.1    Wydra, H.2
  • 5
    • 0034287997 scopus 로고    scopus 로고
    • Solvent extraction separation of zinc and cadmium from nickel and cobalt using aliquat 336, a strong base anion exchanger, in the chloride and thiocyanate forms
    • Wassink, B., Dreisinger, D., and Howard, J. (2000) Solvent Extraction Separation of Zinc and Cadmium From Nickel and Cobalt Using Aliquat 336, a Strong Base Anion Exchanger, in the Chloride and Thiocyanate Forms. Hydrometallurgy, 57: 235-252.
    • (2000) Hydrometallurgy , vol.57 , pp. 235-252
    • Wassink, B.1    Dreisinger, D.2    Howard, J.3
  • 6
    • 0031212847 scopus 로고    scopus 로고
    • A pyridyne-based chelating solvent extraction system for selective extraction of nickel and cobalt
    • Zhou, T. and Pesic, B. (1997) A Pyridyne-based Chelating Solvent Extraction System for Selective Extraction of Nickel and Cobalt. Hydrometallurgy, 46: 37-53.
    • (1997) Hydrometallurgy , vol.46 , pp. 37-53
    • Zhou, T.1    Pesic, B.2
  • 7
    • 33745017753 scopus 로고    scopus 로고
    • N-Imidazole Compounds and Their Complex Metal Derivatives. U.S. Patent. 3,843,667, October 22
    • Cupery, M.E. N-Imidazole Compounds and Their Complex Metal Derivatives. U.S. Patent. 3,843,667, October 22.
    • Cupery, M.E.1
  • 8
    • 33745038091 scopus 로고    scopus 로고
    • Solvent Extraction Mixture Comprising Substituted Imidazole or Benzimidazole for Purification of Groups of Base Metals. U.S. Patent 2004/0208808 A1, October 21
    • Schaekers, J.M.; Dupreez, J.G.H. (2004) Solvent Extraction Mixture Comprising Substituted Imidazole or Benzimidazole for Purification of Groups of Base Metals. U.S. Patent 2004/0208808 A1, October 21.
    • (2004)
    • Schaekers, J.M.1    Dupreez, J.G.H.2
  • 9
    • 0006132108 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solution. Part XI. A study on complex formation between N-butylimidazole and Co(II), Ni(II), Cu(II) and Zn(II)
    • Lenarcik, B., Barszcz, B., and Kulig, J. (1977) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solution. Part XI. A Study on Complex Formation Between N-Butylimidazole and Co(II), Ni(II), Cu(II) and Zn(II). Roczniki Chem., 51: 1315-1322.
    • (1977) Roczniki Chem. , vol.51 , pp. 1315-1322
    • Lenarcik, B.1    Barszcz, B.2    Kulig, J.3
  • 10
    • 0001490429 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solution. Part XIV. Complex formation between N-methylimidazole and Co(II), Ni(II), Cu(II) and Zn(II)
    • Lenarcik, B. and Barszcz, B. (1977) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solution. Part XIV. Complex Formation Between N-Methylimidazole and Co(II), Ni(II), Cu(II) and Zn(II). Roczniki Chem., 51: 1849-1855.
    • (1977) Roczniki Chem. , vol.51 , pp. 1849-1855
    • Lenarcik, B.1    Barszcz, B.2
  • 11
    • 0000081086 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solution. Part XIX. Structural effects during complexation of Co(II), Ni(II), Cu(II) and Zn(II) with 1-ethylimidazole and 1-propylimidazole
    • Lenarcik, B. and Barszcz, B. (1979) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solution. Part XIX. Structural Effects During Complexation of Co(II), Ni(II), Cu(II) and Zn(II) with 1-Ethylimidazole and 1-Propylimidazole. Polish J. Chem., 53: 963-971.
    • (1979) Polish J. Chem. , vol.53 , pp. 963-971
    • Lenarcik, B.1    Barszcz, B.2
  • 12
    • 0001325293 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solutions. Part XXIII. Effect of the position of methyl substituents on the complex-forming capacity of imidazoles
    • Lenarcik, B. and Kurdziel, K. (1981) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solutions. Part XXIII. Effect of the Position of Methyl Substituents on the Complex-Forming Capacity of Imidazoles. Polish J. Chem., 55: 737-745.
    • (1981) Polish J. Chem. , vol.55 , pp. 737-745
    • Lenarcik, B.1    Kurdziel, K.2
  • 13
    • 0000357373 scopus 로고
    • Research for optimum conditions for extraction of metal complexes by alkylimidazoles. Part IV. The influence of steric effect on the extraction of the complexes of 2-Ethylimidazole with Co(II), Ni(II), Zn(II) and Cd(II)
    • Lenarcik, B., Czopek, R., and Kurdziel, K. (1991) Research for Optimum Conditions for Extraction of Metal Complexes by Alkylimidazoles. Part IV. The Influence of Steric Effect on the Extraction of the Complexes of 2-Ethylimidazole with Co(II), Ni(II), Zn(II) and Cd(II). Polish J. Chem., 65: 837-843.
    • (1991) Polish J. Chem. , vol.65 , pp. 837-843
    • Lenarcik, B.1    Czopek, R.2    Kurdziel, K.3
  • 14
    • 0018292015 scopus 로고
    • Search for optimum conditions of extraction of transition metal complexes with alkylimidazoles. I. Extraction of the Co(II), Ni(II) and Zn(II) complexes of 1-methylimidazole and of the Co(II) and Zn(II) complexes of 2-methylimidazole
    • Lenarcik, B., Głowacki, J., and Rzepka, M. (1979) Search for Optimum Conditions of Extraction of Transition Metal Complexes with Alkylimidazoles. I. Extraction of the Co(II), Ni(II) and Zn(II) Complexes of 1-Methylimidazole and of the Co(II) and Zn(II) Complexes of 2-Methylimidazole. Sep. Sci. Technol., 14: 37-54.
    • (1979) Sep. Sci. Technol. , vol.14 , pp. 37-54
    • Lenarcik, B.1    Głowacki, J.2    Rzepka, M.3
  • 15
    • 0033473688 scopus 로고    scopus 로고
    • The influence of steric effect and alkyl chain length on extraction of the complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 1-alkyl-2-methylimidazoles
    • Lenarcik, B., Adach, A., and Radzymińska-Lenarcik, E. (1999) The Influence of Steric Effect and Alkyl Chain Length on Extraction of the Complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 1-alkyl-2-Methylimidazoles. Polish J. Chem., 73: 1273-1281.
    • (1999) Polish J. Chem. , vol.73 , pp. 1273-1281
    • Lenarcik, B.1    Adach, A.2    Radzymińska-Lenarcik, E.3
  • 16
    • 0000511760 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solution. Part II. 2-methylimidazole complexes of Co(II), Cu(II) and Zn(II)
    • Lenarcik, B., Kulig, J., and Laidler, P. (1974) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solution. Part II. 2-Methylimidazole Complexes of Co(II), Cu(II) and Zn(II). Roczniki Chem., 48: 1151-1157.
    • (1974) Roczniki Chem. , vol.48 , pp. 1151-1157
    • Lenarcik, B.1    Kulig, J.2    Laidler, P.3
  • 17
    • 0006099306 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solutions. Part XV. A Study on complex formation between 4-methylimidazole and Co(II), Ni(II) and Zn(II)
    • Lenarcik, B. and Obła̧k, K. (1977) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solutions. Part XV. A Study on Complex Formation between 4-Methylimidazole and Co(II), Ni(II) and Zn(II). Roczniki Chem., 51: 2079-2087.
    • (1977) Roczniki Chem. , vol.51 , pp. 2079-2087
    • Lenarcik, B.1    Obła̧k, K.2
  • 18
    • 0346919433 scopus 로고
    • Stability and structure of transition-metal complexes of azoles in aqueous solution. Part 21. A comparison of the complex-forming capacity of 1,2-dimethylimidazole with that of other 1,3-diazoles
    • Lenarcik, B. and Barszcz, B. (1980) Stability and Structure of Transition-Metal Complexes of Azoles in Aqueous Solution. Part 21. A Comparison of the Complex-Forming Capacity of 1,2-Dimethylimidazole with that of Other 1,3-Diazoles. J. Chem. Soc. Dalton Trans, 24-28.
    • (1980) J. Chem. Soc. Dalton Trans , pp. 24-28
    • Lenarcik, B.1    Barszcz, B.2
  • 19
    • 0001376036 scopus 로고
    • Stability and structure of transition metal complexes of azoles in aqueous solution. Part XXVIII. The steric effect in the complex formation of 2-n-propylimidazole and 2-isopropylimidazole
    • Lenarcik, B., Kurdziel, K., and Czopek, R. (1991) Stability and Structure of Transition Metal Complexes of Azoles in Aqueous Solution. Part XXVIII. The Steric Effect in the Complex Formation of 2-n-Propylimidazole and 2-Isopropylimidazole. Polish J. Chem., 65: 815-820.
    • (1991) Polish J. Chem. , vol.65 , pp. 815-820
    • Lenarcik, B.1    Kurdziel, K.2    Czopek, R.3
  • 20
    • 0000742080 scopus 로고
    • Stability and structure of transition metal complexes with azoles in aqueous solution. Part XXIX. The influence of the size and structure of the alkyl group on the formation of 2-alkylimidazole complexes
    • Lenarcik, B., Kurdziel, K., and Czopek, R. (1991) Stability and Structure of Transition Metal Complexes with Azoles in Aqueous Solution. Part XXIX. The Influence of the Size and Structure of the Alkyl Group on the Formation of 2-Alkylimidazole Complexes. Polish J. Chem., 65: 1235-1241.
    • (1991) Polish J. Chem. , vol.65 , pp. 1235-1241
    • Lenarcik, B.1    Kurdziel, K.2    Czopek, R.3
  • 21
    • 0034731836 scopus 로고    scopus 로고
    • Evaluation of intramolecular equilibria in complexes formed between substituted imidazole ligands and nickel(II), copper(II) or zinc(II)
    • Sigel, H., Saha, A., Saha, N., Carloni, P., Kapinos, L.E., and Griesser, R. (2000) Evaluation of Intramolecular Equilibria in Complexes Formed Between Substituted Imidazole Ligands and Nickel(II), Copper(II) or Zinc(II). J. Inorg. Biochem., 78: 129-137.
    • (2000) J. Inorg. Biochem. , vol.78 , pp. 129-137
    • Sigel, H.1    Saha, A.2    Saha, N.3    Carloni, P.4    Kapinos, L.E.5    Griesser, R.6
  • 22
    • 0036095906 scopus 로고    scopus 로고
    • The Influence of the size and position of the alkyl groups in alkylimidazole molecules on their acid ± base properties
    • Lenarcik, B. and Ojczenasz, P. (2002) The Influence of the Size and Position of the Alkyl Groups in Alkylimidazole Molecules on Their Acid ± Base Properties. J. Heterocyclic Chem., 39: 287-290.
    • (2002) J. Heterocyclic Chem. , vol.39 , pp. 287-290
    • Lenarcik, B.1    Ojczenasz, P.2
  • 23
    • 1342279382 scopus 로고    scopus 로고
    • Investigation of the stability of Co(II) complexes with a homologous series of 1-alkylimidazoles in aqueous solutions by using a partition method with several solvents
    • Lenarcik, B. and Ojczenasz, P. (2004) Investigation of the Stability of Co(II) Complexes with a Homologous Series of 1-alkylimidazoles in Aqueous Solutions by Using a Partition Method with Several Solvents. Sep. Sci. Technol., 39: 199-226.
    • (2004) Sep. Sci. Technol. , vol.39 , pp. 199-226
    • Lenarcik, B.1    Ojczenasz, P.2
  • 24
    • 3042685020 scopus 로고    scopus 로고
    • The influence of alkyl chain length and on stability constants of Zn(II) complexes with 1-alkylimidazoles in aqueous solutions and their partition between aqueous phase an organic solvent
    • Lenarcik, B. and Kierzkowska, A. (2004) The Influence of Alkyl Chain Length and on Stability Constants of Zn(II) Complexes with 1-alkylimidazoles in Aqueous Solutions and Their Partition Between Aqueous Phase an Organic Solvent. Solvent Extr. Ion Exch., 22 (4): 449-471.
    • (2004) Solvent Extr. Ion Exch. , vol.22 , Issue.4 , pp. 449-471
    • Lenarcik, B.1    Kierzkowska, A.2
  • 25
    • 7444262836 scopus 로고    scopus 로고
    • The influence of alkyl chain length on extraction equilibria of Ni(II) complexes with 1-alkylimidazoles in aqueous solution/organic solvent system
    • Lenarcik, B. and Rauckyte, T. (2004) The Influence of Alkyl Chain Length on Extraction Equilibria of Ni(II) Complexes with 1-alkylimidazoles in Aqueous Solution/Organic Solvent System. Sep. Sci. Technol., 14: 3353-3372.
    • (2004) Sep. Sci. Technol. , vol.14 , pp. 3353-3372
    • Lenarcik, B.1    Rauckyte, T.2
  • 26
    • 9144245850 scopus 로고    scopus 로고
    • The influence of alkyl chain length and steric effect on stability constants and extractability of Zn(II) complexes with 1-alkyl-4-methylimidazoles
    • Lenarcik, B. and Kierzkowska, A. (2004) The Influence of Alkyl Chain Length and Steric Effect on Stability Constants and Extractability of Zn(II) Complexes with 1-alkyl-4-methylimidazoles. Sep. Sci. Technol., 39 (15): 3485-3508.
    • (2004) Sep. Sci. Technol. , vol.39 , Issue.15 , pp. 3485-3508
    • Lenarcik, B.1    Kierzkowska, A.2
  • 27
    • 0345002798 scopus 로고
    • Principles of solubility and solutions
    • Rydberg, J., Musikas, C. and Choppin, G.R. (eds.), Marcel Dekker, Inc: New York
    • Marcus, Y. (1992) Principles of solubility and solutions. In Principles and Practices of Solvent Extraction; Rydberg, J., Musikas, C. and Choppin, G.R. (eds.), Marcel Dekker, Inc: New York; Vol. 1, 22-24.
    • (1992) Principles and Practices of Solvent Extraction , vol.1 , pp. 22-24
    • Marcus, Y.1
  • 29
    • 33745039836 scopus 로고
    • Kolicestvennyj Analiz Nieorganiceskich Sojedinenij: Chimija, Moskva; Vol. 27999
    • Scharlo, G. (1962) Metody Analityceskoj Chimiji. Kolicestvennyj Analiz Nieorganiceskich Sojedinenij: Chimija, Moskva; Vol. 27999,910;
    • (1962) Metody Analityceskoj Chimiji , pp. 910
    • Scharlo, G.1
  • 31
    • 84948850207 scopus 로고
    • Potentiometric apparatus and technique for the pH-metric measurement of metal-complex equilibrium constants
    • Braibanti, A., Ostacoli, G., Paoletti, P., Pettit, L.D., and Sammartano, S. (1987) Potentiometric Apparatus and Technique for the pH-metric Measurement of Metal-Complex Equilibrium Constants. Pure Applied Chem., 59: 1721-1728.
    • (1987) Pure Applied Chem. , vol.59 , pp. 1721-1728
    • Braibanti, A.1    Ostacoli, G.2    Paoletti, P.3    Pettit, L.D.4    Sammartano, S.5
  • 33
    • 0002101550 scopus 로고
    • On the complex formation between thorium and acetylacetone
    • Rydberg, J. (1950) On the Complex Formation Between Thorium and Acetylacetone. Acta Chem.Scand., 4: 1503-1522.
    • (1950) Acta Chem.Scand. , vol.4 , pp. 1503-1522
    • Rydberg, J.1
  • 35
    • 84963160161 scopus 로고
    • Search for optimum conditions of extraction of metal complexes with alkylimidazoles. III. Structure-extractability relationship for 1,4-dimethylimidazole complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II)
    • Lenarcik, B., Kurdziel, K., Czopek, R. (1986) Search for Optimum Conditions of Extraction of Metal Complexes with Alkylimidazoles. III. Structure-Extractability Relationship for 1,4-Dimethylimidazole Complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II). Solvent Extr. Ion Exch., 4: 165-182.
    • (1986) Solvent Extr. Ion Exch. , vol.4 , pp. 165-182
    • Lenarcik, B.1    Kurdziel, K.2    Czopek, R.3


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