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2
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0003965854
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W. M. Horspool and F. Lenci, CRC Press, Boca Raton, FL, 2nd edn, Review:
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P. J. Wagner, in CRC Handbook of Organic Photochemistry and Photobiology, ed., W. M. Horspool, and, F. Lenci,, CRC Press, Boca Raton, FL, 2nd edn, 2004, ch. 58
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(2004)
CRC Handbook of Organic Photochemistry and Photobiology, Ed.
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Wagner In, P.J.1
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3
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0003965854
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W. M. Horspool and F. Lenci, CRC Press, Boca Raton, FL, 2nd edn
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P. J. Wagner and P. Klán, in CRC Handbook of Organic Photochemistry and Photobiology, ed., W. M. Horspool, and, F. Lenci,, CRC Press, Boca Raton, FL, 2nd edn, 2004, ch. 52
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(2004)
CRC Handbook of Organic Photochemistry and Photobiology, Ed.
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Wagner, P.J.1
Klán In, P.2
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4
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85028579626
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W. M. Horspool and F. Lenci, CRC Press, Boca Raton, FL, 2nd edn
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J. R. Scheffer and C. Scott, in CRC Handbook of Organic Photochemistry and Photobiology, ed., W. M. Horspool, and, F. Lenci,, CRC Press, Boca Raton, FL, 2nd edn, 2004, ch. 54
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(2004)
CRC Handbook of Organic Photochemistry and Photobiology, Ed.
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Scheffer, J.R.1
Scott In, C.2
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7
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79955668125
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Y. Inoue and V. Ramamurthy, Marcel Dekker, New York, NY
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and J. R. Scheffer, in Molecular and Supramolecular Photochemistry, Vol. 11: Chiral Photochemistry, ed., Y. Inoue, and, V. Ramamurthy,, Marcel Dekker, New York, NY, 2004, ch. 12
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(2004)
Molecular and Supramolecular Photochemistry, Vol. 11: Chiral Photochemistry, Ed.
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Scheffer, J.R.1
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8
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33745011026
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Typical primary/secondary/tertiary rate ratios for γ-hydrogen atom abstraction of γ-substituted butyrophenones are approximately 1 : 30 : 200 per hydrogen2
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2) was 0.124 (all data)
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9
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33745040133
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Prolonged irradiation of compound 3b in acetonitrile gave rise to a myriad of type I and type II products that we did not bother to characterize fully
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Prolonged irradiation of compound 3b in acetonitrile gave rise to a myriad of type I and type II products that we did not bother to characterize fully
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10
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33745021509
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Molecular mechanics calculations were carried out using HyperChem/ChemPlus version 5.11/2.0
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Molecular mechanics calculations were carried out using HyperChem/ChemPlus version 5.11/2.0
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11
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33745029970
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For comparable studies on 2-methyl-1-phenylbutan-1-one, see
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Ratio based on GC uncorrected for detector response at low conversion (5%)
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12
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0001732887
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2) was 0.357 (all data). CCDC reference numbers 297457 and 297458. For crystallographic data in CIF or other electronic format see DOI: For a description of the solid state photolysis and workup technique, see
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F. D. Lewis T. A. Hilliard J. Am. Chem. Soc. 1972 94 3852
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(1972)
J. Am. Chem. Soc.
, vol.94
, pp. 3852
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Lewis, F.D.1
Hilliard, T.A.2
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14
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33745045336
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In this case and the others summarized in Table 1, a small amount of cleavage was detectable by GC when the solid state photolyses were carried out at room temperature
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In this case and the others summarized in Table 1, a small amount of cleavage was detectable by GC when the solid state photolyses were carried out at room temperature
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15
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33745039359
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The absolute configurations were not determined experimentally but are based on the known absolute conformation of the starting salt and the assumed mechanism, which is abstraction of Ha followed by least motion biradical cyclization with retention of configuration at the carbonyl carbon. This leads to the experimentally observed Z cyclobutanol (OH and ethyl groups cis)
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The absolute configurations were not determined experimentally but are based on the known absolute conformation of the starting salt and the assumed mechanism, which is abstraction of Ha followed by least motion biradical cyclization with retention of configuration at the carbonyl carbon. This leads to the experimentally observed Z cyclobutanol (OH and ethyl groups cis)
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