Chronoamperometric behaviour of a CE process with fast chemical reactions at spherical electrodes and microelectrodes. Comparison with a catalytic reaction

Electrochemistry Communications

Volumn 8, Issue 6, 2006, Pages 1062-1070

  Molina, Ángela ^a   Morales, Isabel ^a   López Tenés, Manuela ^a  

^a UNIVERSITY OF MURCIA   (Spain)

Author keywords

Catalytic mechanism; CE mechanism; Diffusion layer thickness; Fast chemical reaction; Microelectrodes; Reaction layer thickness; Spherical electrodes; Steady state

Indexed keywords

CATALYSIS; DIFFUSION; MICROELECTRODES;

CATALYTIC MECHANISM; CE MECHANISM; DIFFUSION LAYER THICKNESS; FAST CHEMICAL REACTION; REACTION LAYER THICKNESS; SPHERICAL ELECTRODES; STEADY STATE;

ELECTRODES;

EID: 33744934232     PISSN: 13882481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elecom.2006.04.011     Document Type: Article

References (18)

1. Molina A., and Morales I. J. Electroanal. Chem. 583 (2005) 193
2. Budevskii E., and Desimirov G. Dokladi Akad. Nauk SSSR 149 (1963) 120
3. Delmastro J.R., and Smith D.E. J. Phys. Chem. 71 (1967) 2138
4. Fleischmann M., Lasserre F., Robinson J., and Swan D. J. Electroanal. Chem. 177 (1984) 97
5. Oldham K.B. J. Electroanal. Chem. 313 (1991) 3
6. Zhuang Q., and Chen H. J. Electroanal. Chem. 346 (1993) 29
7. Zhuang Q., and Chen H. J. Electroanal. Chem. 346 (1993) 471
8. van Leeuwen H.P., and Pinheiro J.P. J. Electroanal. Chem. 471 (1999) 55
9. Galceran J., Puy J., Salvador J., Cecília J., and van Leeuwen H.P. J. Electroanal. Chem. 505 (2001) 85
10. Lovric M., and Tur'yan Y.I. Croat. Chem. Acta 76 (2003) 189
11. Pinheiro J.P., Minor M., and van Leeuwen H.P. J. Electroanal. Chem. 587 (2006) 284
12. Koutecký J. Chem. Listy 47 (1953) 323
13. Koutecký J. Coll. Czech. Chem. Commun. 18 (1953) 597
14. Heyrovský J., and Kuta J. Principles of Polarography (1966), Academic Press, New York
15. Galus Z. Fundamentals of Electrochemical Analysis. second ed. (1994), Ellis Horwood, Chichester
16. Bard A.J., and Faulkner L.R. Electrochemical Methods, Fundamental and Applications. second ed. (2001), Wiley, New York
17. Serna C., López-Tenés M., González J., and Molina A. Electrochim. Acta 46 (2001) 2699
18. Koutecký J., and Brdicka R. Coll. Czech. Chem. Commun. 12 (1947) 337