Cycloisomerization of activated (2E,4Z)-heptatrienoate and its relevance to crispatene (bio)synthesis. A case of concerted and stepwise uncertainty

Journal of Organic Chemistry

Volumn 71, Issue 12, 2006, Pages 4497-4501

  López, Carlos Silva ^a   Faza, Olalla Nieto ^a   Álvarez, Rosana ^a   De Lera, Ángel R ^a  

^a UNIVERSITY OF VIGO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BARRIERLESS CYCLOPROPANE; CRISPATENE; CYCLOISOMERIZATION; HEXENE DERIVATIVES;

ACTIVATION ANALYSIS; ISOMERIZATION; REACTION KINETICS; SYNTHESIS (CHEMICAL);

STEREOCHEMISTRY;

ACID; ALKADIENE; ALKENE DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; CRISPATENE; CYCLOHEXENE DERIVATIVE; CYCLOPROPANE; ESTER; HEPTATRIENAL; HEPTATRIENOIC ACID; LEWIS ACID; METHYL ESTER; NATURAL PRODUCT; PENTADIENE; PROTIC ACID; UNCLASSIFIED DRUG;

ARTICLE; BIOSYNTHESIS; CHEMICAL STRUCTURE; CYCLOISOMERIZATION; ENERGY; ISOMERIZATION; REACTION ANALYSIS; RING CLOSURE; STEREOCHEMISTRY;

ALKADIENES; ALKENES; BICYCLO COMPOUNDS; BIOLOGICAL PRODUCTS; CYCLIZATION; CYCLOPROPANES; PYRONES; STEREOISOMERISM;

EID: 33744930835     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0603274     Document Type: Article

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