Preparation of hydrido(vinyl)iridium(III) complexes from functionalized olefins by C-H activation

Canadian Journal of Chemistry

Volumn 84, Issue 2, 2006, Pages 205-213

  Papenfuhs, Bernd ^a   Dirnberger, Thomas ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

C H activation; Hydrido complexes; Iridium; Phosphine complexes; Vinyl complexes

Indexed keywords

OLEFINS; PHASE EQUILIBRIA; PHOSPHORUS COMPOUNDS; SILVER COMPOUNDS; SYNTHESIS (CHEMICAL);

C-H ACTIVATION; HYDRIDO COMPLEXES; PHOSPHINE COMPLEXES; VINYL COMPLEXES;

IRIDIUM COMPOUNDS;

ALKENE DERIVATIVE; CARBON; CATION; HYDROGEN; IRIDIUM COMPLEX; LIGAND; METAL; NITROGEN; PHOSPHINE DERIVATIVE; VINYL DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; ISOMER; OXIDATION;

EID: 33744924232     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/V05-234     Document Type: Article

References (25)

1. M. Schulz and H. Werner. Organometallics, 11, 2790 (1992).
2. H. Werner, T. Dirnberger, and M. Schulz. Angew. Chem. Int. Ed. Engl. 27, 948 (1988).
3. (a) P.O. Stoutland and R.G. Bergman. J. Am. Chem. Soc. 107, 4581 (1985);
4. (b) P.O. Stoutland and R.G. Bergman. J. Am. Chem. Soc. 110, 5732 (1988).
5. (a) D.M. Haddleton and R.N. Perutz. J. Chem. Soc. Chem. Commun. 1734 (1986);
6. (b) T.W. Bell, S.-A. Brough, M.G. Partridge, R.N. Perutz, and A.D. Rooney. Organometallics, 12, 2933 (1993).
7. H. Werner, B. Papenfuhs, and P. Steinert. Z. Anorg. Allg. Chem. 627, 1807 (2001).
8. J.P. Collman and J.W. Kang. J. Am. Chem. Soc. 88, 3459 (1966).
9. R. Castarlenas, M.A. Esteruelas, M. Martín, and L.A. Oro. J. Organomet. Chem. 564, 241 (1998).
10. A.N. Nesmeyanov, M.I. Rybinskaya, L.V. Rybin, V.S. Kaganovich, and P.V. Petrovskii. J. Organomet. Chem. 31, 257 (1971).
11. H. Werner, M. A. Esteruelas, and H. Otto. Organometallics, 5, 2295 (1986).
12. M. Schulz. Ph.D. thesis, Universität Würzburg, Würzburg, Germany. 1991.
13. L. Vaska and J.W. Di Luzio. J. Am. Chem. Soc. 83, 2784 (1961).
14. T. Dirnberger. Ph.D. thesis, Universität Würzburg, Würzburg, Germany. 1990.
15. M. Masamoto. Nippon Kagaku Kaishi, 5, 825 (1976).
16. J. Peone and L. Vaska. Angew. Chem. Int. Ed. Engl. 10, 511 (1971).
17. Reviews: (a) N.M.N. Gowda, S.B. Naikar, and G.K.N. Reddy. Adv. Inorg. Chem. Radiochem. 28, 255 (1984);
18. (b) W. Beck and K.H. Sünkel. Chem. Rev. 88, 1405 (1988);
19. (c) S.H. Strauss. Chem. Rev. 93, 927 (1993).
20. For the isomerization of alkyne iridium(I) to vinylidene iridium(I) complexes, see: (a) F.J. Garcia Alonso, A. Höhn, J. Wolf, H. Otto, and H. Werner. Angew. Chem. Int. Ed. Engl. 24, 406 __ (1985);
21. (b) A. Höhn and H. Werner. Angew. Chem. Int. Ed. Engl. 25, 737 (1986);
22. (c) A. Höhn and H. Werner. J. Organomet. Chem. 382, 255 (1990);
23. (d) H. Werner, R.W. Lass, O. Gevert, and J. Wolf. Organometallics, 16, 4077 (1997).
24. H. Werner, A. Höhn, and M. Dziallas. Angew. Chem. Int. Ed. Engl. 25, 1090 (1986).
25. H. Möhrle, T. Platzek, R. Wille, and D. Wendisch. Z. Naturforsch. B: Chem. Sci. 40b, 524 (1985).