The 2-oxocyclobutanecarboxylic acid keto-enol system in aqueous solution: A remarkable acid-strengthening effect of the cyclobutane ring

Journal of Organic Chemistry

Volumn 71, Issue 12, 2006, Pages 4460-4467

  Chang, J A ^a   Chiang, Y ^a   Keeffe, J R ^b   Kresge, A J ^a   Nikolaev, V A ^c   Popik, V V ^a  

^a UNIVERSITY OF TORONTO   (Canada)

^b SAN FRANCISCO STATE UNIVERSITY   (United States)

^c ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CARBOXYLIC ACIDS; CHEMICAL BONDS; HYDRATION; KETONES; SOLUTIONS;

2-OXOCYCLOBUTANECARBOXYLIC ACID KETO-ENOL SYSTEM; ACID-STRENGTHENING EFFECT; CYCLOBUTANE RING; KETO FORM;

TERNARY SYSTEMS;

2 DIAZOCYCLOPENTANE 1,3 DIONE; 2 OXOCYCLOBUTANE CARBOXYLIC ACID; 2 OXOCYCLOBUTANECARBOXYLIC ACID; 2 OXOCYCLOBUTYLIDENEKETENE; ACID; ALCOHOL; BASE; BROMINE; BUFFER; CARBOCYCLIC RING; CARBOXYLIC ACID DERIVATIVE; CYCLOBUTANE; CYCLOPENTANE DERIVATIVE; FUNCTIONAL GROUP; KETENE DERIVATIVE; KETONE; OXOACID; UNCLASSIFIED DRUG;

ACIDITY; AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; CHEMICAL PHENOMENA; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; DOUBLE BOND; ENOLIZATION; EQUILIBRIUM CONSTANT; FLASH PHOTOLYSIS; HYDRATION; IONIC STRENGTH; ISOMERIZATION; KETO ENOL SYSTEM; PHOTOLYSIS; SCAVENGING SYSTEM;

EID: 33744915257     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo060253w     Document Type: Article

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