Metallic transport in polyaniline

Nature

Volumn 441, Issue 1, 2006, Pages 65-68

  Lee, Kwanghee ^a,b   Cho, Shinuk ^a   Sung, Heum Park ^a   Heeger, A J ^b   Lee, Chan Woo ^c   Lee, Suck Hyun ^c  

^a Pusan National University   (South Korea)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c Ajou University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC CONDUCTIVITY; FREQUENCIES; METALLIC COMPOUNDS; ORGANIC POLYMERS; POLYMERIZATION; TRANSPORT PROPERTIES; DISPERSIONS; INFRARED RADIATION; NATURAL FREQUENCIES; THERMAL EFFECTS;

CONDUCTING POLYMERS; FREQUENCY DEPENDENT CONDUCTIVITY; METALLIC RESISTIVITY; METALLIC POLYMERS; POLYANILINE; ROOM-TEMPERATURE CONDUCTIVITIES;

NITROGEN COMPOUNDS;

CAMPHOR; CAMPHOR SULFONIC ACID; METAL; POLYANILINE; SULFONIC ACID DERIVATIVE; UNCLASSIFIED DRUG; POLYMER;

ALLOY; ELECTRICAL CONDUCTIVITY; ELECTRICAL RESISTIVITY; MATERIAL CULTURE; POLYMER; CONDUCTIVITY; INFRARED RADIATION; NUMERICAL MODEL; POLYMERIZATION; TEMPERATURE EFFECT;

ARTICLE; DIRECT CURRENT; DISPERSION; ELECTRIC CONDUCTIVITY; ENERGY; FILM; LOW TEMPERATURE; MATERIALS; MICHAEL ADDITION; PARAMETER; POLYMERIZATION; PREDICTION; PRIORITY JOURNAL; ROOM TEMPERATURE; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION; FREQUENCY ANALYSIS; INFRARED RADIATION; MEASUREMENT; MOLECULAR STABILITY; SAMPLE; SYNTHESIS; THEORETICAL MODEL; THEORY; TRANSPORT KINETICS;

EID: 33744807792     PISSN: 00280836     EISSN: 14764687     Source Type: Journal    
DOI: 10.1038/nature04705     Document Type: Article

References (27)

1. Heeger, A. J. Nobel Lecture: Semiconducting and metallic polymers: The fourth generation of polymeric materials. Rev. Mod. Phys. 73, 681-700 (2001).
2. Menon, R., Yoon, C. O., Moses, D. & Heeger, A. J. in Handbook of Conducting Polymers 2nd edn (eds Skotheim, T. A., Elsenbaumer, R. L. & Reynolds, J. R.) 27-84 (Marcel Dekker, New York, 1998).
3. Heeger, A. J. The critical regime of the metal-insulator transition in conducting polymers: experimental studies. Phys. Scr. T102, 30-35 (2002).
4. Kaiser, A. B. Systematic conductivity behaviour in conducting polymers: effects of heterogeneous disorder. Adv. Mater. 13, 927-941 (2001).
5. Kiebooms, R., Menon, R. & Lee, K. in Handbook of Advanced Electronic and Photonic Materials and Devices Vol. 8 (ed. Nalwa, H. S.) 1-102 (Academic, San Diego, 2001).
6. Kohlman, R. S., Joo, J. & Epstein, A. J. in Physical Properties of Polymers Handbook (ed. Mark, J. E.) 453-478 (AIP, New York, 1996).
7. Lee, K. in Encyclopedia of Nanoscience and Nanotechnology Vol. 5 (ed. Nalwa, H. S.) 537-549 (American Scientific Publishers, San Diego, 2004).
8. Lee, S.-H., Lee, D.-H., Lee, K. & Lee, C.-W. High-performance polyaniline prepared via polymerization in a self-stabilized dispersion. Adv. Funct. Mater. 15, 1495-1500 (2005).
9. Ashcroft, N. W. & Mermin, N. D. Solid State Physics (Saunders College, New York, 1976).
10. Landau, L. D. The theory of a Fermi liquid. Sov. Phys. JETP 3, 920-925 (1957).
11. Pines, I. D. & Nozieres, P. The Theory of Quantum Liquids (Benjamin, Menlo Park, 1966).
12. Mott, N. F. Metal-insulator Transitions (Taylor & Francis, London, 1990).
13. Anderson, P. W. The Fermi glass: theory and experiment. Comments Solid State Phys. 2, 193-198 (1970).
14. Fite, C., Cao, Y. & Heeger, A. J. Magnetic susceptibility of one-dimensional metallic chains in solution. Solid State Commun. 73, 607-609 (1990).
15. Park, Y. W., Choi, E. S. & Suh, D. S. Metallic temperature dependence of resistivity in perchlorate doped polyacetylene. Synth. Met. 96, 81-86 (1998).
16. Moses, D., Denenstein, A., Pron, A., Heeger, A. J. & MacDiarmid, A. G. Specific heats of pure and doped polyacetylene. Solid State Commun. 36, 219-224 (1980).
17. Reghu, M., Cao, Y., Moses, D. & Heeger, A. J. Counterion-induced processibility of polyaniline: transport at the metal-insulator boundary. Phys. Rev. B 47, 1758-1764 (1993).
18. 6. Phys. Rev. B 49, 10851-10863 (1994).
19. Wang, Z. H., Scherr, E. M., MacDiarmid, A. G. & Epstein, A. J. Transport and EPR studies of polyaniline: a quasi one-dimensional conductor with three dimensional "metallic" states. Phys. Rev. B 45, 4190-4202 (1992).
20. Lee, K., Heeger, A. J. & Cao, Y. Reflectance of polyaniline protonated with camphor sulfonic acid: disordered metal on the metal-insulator boundary. Phys. Rev. B 48, 14884-14891 (1993).
21. Lee, K. et al. Nature of the metallic state in conducting polypyrrole. Adv. Mater. 10, 456-459 (1998).
22. Kohlman, R. S. et al. Limit for metallic conductivity in conducting polymers. Phys. Rev. Lett. 78, 3915-3918 (1995).
23. 6-doped polypyrrole. Phys. Rev. B 60, 13479-13483 (1999).
24. Tzamalis, G., Zaidi, N. A., Homes, C. C. & Monkman, A. P. Doping-dependent studies of the Anderson-Mott localization in polyaniline at the metal-insulator boundary. Phys. Rev. B 66, 085202 (2002).
25. Lee, K. & Heeger, A. J. Optical investigation of intra and interchain charge dynamics in conducting polymers. Synth. Met. 128, 279-282 (2002).
26. MacDiarmid, A. G. & Epstein, A. J. Secondary doping in polyaniline. Synth. Met. 69, 85-92 (1995).
27. Yan, H., Ohta, T. & Toshima, N. Stretched polyaniline films doped by (±)-10-camphorsulfonic acid: anisotropy and improvement of thermoelectric properties. Macromol. Mater. Eng. 286, 139-142 (2001).