Polypyrrole-montmorillonite nanocomposite: A composite fast ion conductor

Journal of Composite Materials

Volumn 40, Issue 11, 2006, Pages 1009-1021

  Krishantha, D M M ^a   Rajapakse, R M G ^a   Tennakoon, D T B ^a   Dias, H V R ^b  

^a UNIVERSITY OF PERADENIYA   (Sri Lanka)

^b UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

Author keywords

Cu(I) polypyrrole montmorillonite nanocomposite; Fast ion conductor; Mixed conductor

Indexed keywords

ACTIVATION ENERGY; ELECTRIC CONDUCTIVITY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ION EXCHANGE; POLYMERIZATION; POLYPYRROLES; THERMAL EFFECTS;

ARRHENIUS BEHAVIOR; CU(I)-POLYPYRROLE-MONTMORILLONITE NANOCOMPOSITE; FAST-ION CONDUCTORS; MIXED CONDUCTORS;

NANOSTRUCTURED MATERIALS;

EID: 33744784018     PISSN: 00219983     EISSN: 1530793X     Source Type: Journal    
DOI: 10.1177/0021998305056388     Document Type: Article

References (27)

1. Kanazawa, K. K., Diaz, A. F., Geiss, R. H., Gill, W. D., Kwak, J. F., Logan, J. A., Rabolt, J. F. and Street, G. B. (1979). 'Organic Metals': Polypyrrole, a Stable Synthetic 'Metallic' Polymer, J. Chem. Soc. Chem. Commun., 19: 854-855.
2. Scrosati, B. (1993). Applications of Electroactive Polymers, Chaomann Hall, London.
3. Yurtsever, E. and Yurtsever, M. (1999). A Theoretical Study of Structural Defects in Conjugated Polymers, Synthetic Metals, 101 (1-3). 335-336.
4. Bein, T. and Enzel, P. (1993). Inclusion of Conducting Polymers in Inorganic Hosts: Towards Conducting Nanostructures, In: NATO ASI Series, Series E: Applied Sciences (A Review on Intrinsically Conducting Polymers: An Emerging Technology), Vol. 246, pp. 51-60.
5. Leroux, F. and Besse, J.-P. (2001). Polymer Interleaved Layered Double Hydroxide: A New Emerging Class of Nanocomposites, Chem. Mater., 13 (10). 3507-3515.
6. LeBaron, P. C., Wang, Z. and Pinnavaia, T. J. (1999). Polymer-layered Silicate Nanocomposites: An Overview, Applied Clay Science, 15 (1-2). 11-29.
7. Zeng, Q. H., Wang, D. Z., Yu, A. B. and Lu, G. Q. (2002). Synthesis of Polymer-montmorillonite Nanocomposites by in situ Intercalative Polymerization, Nanotechnology, 13 (5). 549-553.
8. Bandara, W. M. A. T., Krishantha, D. M. M., Perera, J. S. H. Q., Rajapakse, R. M. G. and Tennakoon, D. T. B. (2005). Preparation, Characterization and Conducting Properties of Nanocomposites of Successively Intercalated Polyaniline (PANI) in Montmorillonite (MMT), J. Composite Materials, 39 (9). 759-775.
9. Toshima, T., Yan, H. and Ishiwatari, M. (1994). Catalytic Polymerization of Aniline and its Derivatives by using Copper(II) Salts and Oxygen. New Type of Polyaniline with Branched Structure, Bull. Chem. Soc. Jpn., 67 (7). 1947-1953.
10. Porter, T. L., Eastman, M. P., Zhang, D. Y. and Hagerman, M. E. (1997). Surface Polymerization of Organic Monomers on Copper(II)-exchanged Hectorite, J. Phys. Chem. B, 101 (51). 11106-11111.
11. Eastman, M. P., Hagerman, M. E., Porter, T. L., Parnell, R. A., Attuso, J. L., Bradely, M. and Thompson, D. (1997). Electrical and Surface Properties of Clay Conducting Polymer Composites, In: Proceedings of SPIE-The International Society for Optical Engineering, 3227 (Interactive Paper), pp. 58-77.
12. Porter, T. L., Hagerman, M. E. and Eastman, M. P. (1996). Surface and Intergallry Polymerization Reactions of Organic Monomers on Layered Silicate Hosts, Recent Research Developments in Polymer Science, 1: 1-17.
13. Ren, X. and Pickup, P. G. (1997). An Impedance Study of Electron Transport and Electron Transfer in Composite Pyrrole + Polystyrenesulphonate Films, J. Electroanal. Chem., 420 (1-2). 251-257.
14. Ren, X. and Pickup, P. G. (1995). Impedance Measurement of Ionic Conductivity as a Probe of Structure in Electrochemically Deposited Polypyrrole Films, J. Electroanal. Chem., 396 (1-2). 359-364.
15. Moore, D. and Reynolds, R. C. (1989). Structure and Properties of Clay Minerals, In: X-Ray Diffraction and the Identification and Analysis of Clay Minerals, 1st edn, p. 104, Oxford University Press, Oxford, UK.
16. Madejova, J. (2003). FTIR Techniques in Clay Mineral Studies, Vibrational Spectroscopy, 31 (1). 1-10.
17. Katritzky, A. R. (1963). Monocyclic Aromatic Ring without Carbonyl, In: Physical Methods in Heterocyclic Chemistry, Vol. 2, p. 201, Academic Press, New York and London.
18. Pasquier, A. U., Orrsini, F., Gozdz, A. S. and Tarascon, J. M. (1999). Electrochemical Behaviour of LiMnO4-PPY Composite Cathodes in the 4-V Region, J. Power and Sources, 81-82: 601-607.
19. Turcu, R., Grecu, R., Brie, M., Peter, T., Bot, A. and Graupner, W. (2001). Spectroscopic Investigation of the Delocalization and Molecular Conformational Changes in Polypyrrole Induced by Different Doping Ions, Studia Universitatis Babes-Bolyal, Physica, Special Issue: 216-222.
20. Can, M., Ozaslam, H., Pekmez, N. O. and Yildiz, A. (2003). Chemical Synthesis of Thiophenepolypyrrole Copolymer, Acta Chim. Slov., 50: 741-750.
21. Plocharski, J. and Wycislik, H. (2000). Mixed Conductivity in Poly(p-phenylene) Doped with Iron Chloride, Solid States Ionics, 127 (3-4). 337-344.
22. Dissanayake, M. A. K. L. (1988). Electrical Conductivity of Li2WO4, Solid States Ionics, 27 (1-2). 109-111.
23. Karthikeyn, A., Vinatier, P. and Levasseur, A. (2000). Study of Lithium Glassy Solid Electrolyte/Electrode Interface by Impedance Analysis, Bull. Mater. Sci., 23 (3). 179-183.
24. Katritzkey, A. R. (1985). Electrophilic Attack on Carbon: Specific Reactions, In: Handbook of Heterocyclic Chemistry, Vol. 1, p. 250, Pergamon Press, New York.
25. Wang, W. and Lin, F. (1990). Behaviour of Liquid-like Conduction for Solid State Electrolyte on Montmorillonite, Solid States Ionics, 40/41 (1). 125-130.
26. Bychko, V. B., Bolotov, A., Grushko, Y., Vlasov and Wortmann, G. (1996). Ionic Diffusion and Local Hopping in Copper Chalcohalide Glass Measured using 64Cu Tracer and 129 I-Mossbauer Spectroscopy, Solid States Ionics, 90 (1-4). 289-284.
27. Rajapakse, R.M.G., Krishantha, D.M.M., Tennakoon, D.T.B. and Dias, H.V.R. (2005). Unpublished Results.