Preparation of proton-conducting sulfonated poly(ether ether ketone)/boron phosphate composite membranes by an in situ sol-gel process

Journal of Membrane Science

Volumn 279, Issue 1-2, 2006, Pages 220-229

  Krishnan, Palanichamy ^a   Park, Jin Soo ^a   Kim, Chang Soo ^a  

^a Korea Institute of Energy Research (KIER)   (South Korea)

Author keywords

Boron phosphate; Composite membranes; PEM fuel cells; Sol gel process; SPEEK; Sulfonated poly(ether ether ketone)

Indexed keywords

CRYSTALLINE MATERIALS; DEPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; FUEL CELLS; PROTONS; SOL-GELS; X RAY DIFFRACTION ANALYSIS;

BORON PHOSPHATE; COMPOSITE MEMBRANES; SOL-GEL PROCESS; SULFONATED POLY(ETHER ETHER KETONE) (SPEEK);

POLYMERIC MEMBRANES;

BORIC ACID; BORON DERIVATIVE; KETONE; PHOSPHORIC ACID; SULFONIC ACID DERIVATIVE; WATER;

CRYSTALLINE MATERIALS; DEPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; FUEL CELLS; POLYMERIC MEMBRANES; PROTONS; SOL-GELS; X RAY DIFFRACTION ANALYSIS;

ARTICLE; CHEMICAL PROCEDURES; COMPOSITE MATERIAL; CONDUCTANCE; CRYSTALLIZATION; DIFFERENTIAL SCANNING CALORIMETRY; HUMIDITY; INFRARED SPECTROSCOPY; PRIORITY JOURNAL; PROTON TRANSPORT; SCANNING ELECTRON MICROSCOPY; THERMOGRAVIMETRY; THERMOSTABILITY; X RAY DIFFRACTION;

EID: 33744532623     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2005.12.010     Document Type: Article

References (32)

1. Tseng P., Lee J., and Friley P. A hydrogen economy: opportunities and challenges. Energy 30 (2005) 2703-2720
2. Johnston B., Mayo M.C., and Khare A. Hydrogen: the energy source for the 21st century. Technovation 25 (2005) 569-585
3. 2 mitigation-case studies in Japan by multi-objective models. Int. J. Hydrogen Energy 30 (2005) 943-952
4. Jin X., Bishop M.T., Ellis T.S., and Karasz F.B. A sulfonated poly(aryl-ether-ketone). Br. Polym. J. 17 (1985) 4-10
5. Xing P., Robertson G., Guiver M.D., Mikhailenko S.D., Wang K., and Kaliaguine S. Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes. J. Membr. Sci. 229 (2004) 95-106
6. Karlsson L.E., and Jannasch P. Polysulfone ionomers for proton-conducting fuel cell membranes. 2. Sulfophenylated polysulfones and polyphenylsulfones. Electrochim. Acta 50 (2005) 1939-1946
7. Ma Y.L., Wainright J.S., Litt M.H., and Savinell R.F. Conductivity of PBI membranes for high-temperature polymer electrolyte fuel cells. J. Electrochem. Soc. 151 (2004) A8-A16
8. Alberti G., and Casciola M. Composite membranes for medium-temperature PEM fuel cells. Annu. Rev. Mater. Res. 33 (2003) 129-154
9. Bonnet B., Jones D.J., Roziere J., Tchicaya L., Alberti G., Casciola M., Massinelli L., Bauer B., Peraio A., and Ramunni E. Hybrid organic-inorganic membranes for a medium temperature fuel cell. J. New Mater. Electrochem. Syst. 3 (2000) 87-92
10. Zaidi S.M., Mikhailenko S.D., Robertson G.P., Guiver M.D., and Kaliaguine S. Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications. J. Membr. Sci. 173 (2000) 17-34
11. Mikhailenko S.D., Zaidi S.M., and Kaliaguine S. Sulfonated polyether ether ketone based composite polymer electrolyte membranes. Catal. Today 67 (2001) 225-236
12. Zaidi S.M. Preparation and characterization of composite membranes using blends of SPEEK/PBI with boron phosphate. Electrochim. Acta 50 (2005) 4771-4777
13. Bouckary L.T., Jones D.J., and Roziere J. Hybrid polyarylether ketone membranes for fuel cell applications. Fuel Cells 2 (2002) 40-45
14. Alberti G., Casciola M., Pica M., Tarpanelli T., and Sganappa M. New preparation methods for composite membranes for medium temperature fuel cells based on precursor solution of insoluble inorganic compounds. Fuel Cells 5 (2005) 366-374
15. Mauritz K.A. Organic-inorganic hybrid materials: perflourinated ionomers as sol-gel polymerization templates for inorganic alkoxides. Mater. Sci. Eng. C 6 (1988) 121-133
16. Wilhelm F.G., Pünt I.G.M., van der Vegt N.F.A., Strathmann H., and Wessling M. Cation permeable membranes from blends of sulfonated poly(ether ether ketone) and poly(ether sulfone). J. Membr. Sci. 199 (2002) 167-176
17. Moffat J.B., and Neeleman J.F. The preparation and some properties of high surface area boron phosphate. J. Catal. 31 (1973) 274-277
18. Woo Y., Oh S.Y., Kang Y.S., and Jung B. Synthesis and characterization of sulfonated polyimide membranes for direct methanol fuel cell. J. Membr. Sci. 220 (2003) 31-45
19. 40)/directly polymerized sulfonated poly(arylene ether sulfone) copolymer composite membranes for high temperature fuel cell applications. J. Membr. Sci. 212 (2003) 263-282
20. 4 thin films. Surf. Coat. Technol. 94-95 (1997) 451-455
21. Mikhailenko S.D., Zaidi J., and Kaliaguine S. Electrical conductivity of boron orthophosphate in presence of water. J. Chem. Soc., Faraday Trans. 94 (1998) 1613-1618
22. Moffat J.B., Chao E.E., and Nott B. Temperature programmed desorption studies on boron phosphate. J. Colloid Interface Sci. 67 (1978) 240-246
23. Arico A.S., Baglio V., Blasi A.D., and Antonucci V. FTIR spectroscopic investigation of inorganic fillers for composite DMFC membranes. Electrochem. Commun. 5 (2003) 862-866
24. Cao J., Su W., Wu Z., Kitayama T., and Hatada K. Synthesis and properties of poly(ether ether ketone)-poly(ether sulfone) block copolymers. Polymer 35 (1994) 3549-3556
25. Gebel G., Aldebert P., and Pineri M. Structural and related properties of solution-cast perfluorosulfonated ionomer films. Macromolecules 20 (1987) 1425-1428
26. Park H.S., Kim Y.J., Hong W.H., Choi Y.S., and Lee H.K. Influence of morphology on the transport properties of perfluorosulfonate ionomers/polypyrrole composite membrane. Macromolecules 38 (2005) 2289-2295
27. Carbone A., Pedicini R., Portale G., Longo A., D'llario L., and Passalacqua E. Sulfonated poly(ether ether ketone) membranes for fuel cell application: thermal and structural characterization, PBFC-2. Second International Conference on Polymer Batteries and Fuel Cells. Las Vegas, Neveda, June 12-17 (2005) (Abstract 87)
28. Xie J., Duan R.G., Han Y., and Kerr J.B. Morphological, rheological and electrochemical studies of poly(ethylene oxide) electrolytes containing fumed silica nanoparticles. Solid State Ionics 175 (2004) 755-758
29. Lage L.G., Delgado P.G., and Kawano Y. Vibrational and thermal characterization of Nafion membranes substituted by alkaline earth cations. Eur. Polym. J. 40 (2004) 1309-14316
30. Stefanithis I.D., and Mauritz K.A. Microstructural evolution of a silicon oxide phase in a perfluorosulfinic acid ionomer by an in situ sol-gel reaction. Macromolecules 23 (1990) 2397-2402
31. Rikukawa K., and Sanui K. Proton conducting polymer electrolyte membranes based on hydrocarbon polymers. Prog. Polym. Sci. 25 (2000) 1463-1502
32. Kim J.D., and Honma I. Proton conducting polydimethylsiloxane/zirconium oxide hybrid membranes added with phosphotungstic acid. Electrochim. Acta 48 (2003) 3633-3638