Hydrolysis of functional monomers in a single-bottle self-etching primer - Correlation of 13C NMR and TEM findings

Journal of Dental Research

Volumn 85, Issue 5, 2006, Pages 422-426

  Nishiyama, N ^a   Tay, F R ^b,c   Fujita, K ^a   Pashley, D H ^b   Ikemura, K ^d   Hiraishi, N ^b   King, N M ^b  

^a NIHON UNIVERSITY   (Japan)

^b MEDICAL COLLEGE OF GEORGIA   (United States)

^c UNIVERSITY OF HONG KONG   (Hong Kong)

^d Shofu Inc   (Japan)

Author keywords

4 MET; Hydrolysis; Nuclear magnetic resonance; Self etching; Single bottle

Indexed keywords

4 METHACRYLOXYETHYLTRIMELLITIC ACID ANHYDRIDE; 4-METHACRYLOXYETHYLTRIMELLITIC ACID ANHYDRIDE; METHACRYLIC ACID DERIVATIVE; RESIN CEMENT; UNIFIL BOND;

ARTICLE; CHEMISTRY; DENTAL ACID ETCHING; DRUG STABILITY; HUMAN; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; TRANSMISSION ELECTRON MICROSCOPY;

ACID ETCHING, DENTAL; DRUG STABILITY; HUMANS; HYDROLYSIS; MAGNETIC RESONANCE SPECTROSCOPY; METHACRYLATES; MICROSCOPY, ELECTRON, TRANSMISSION; RESIN CEMENTS;

EID: 33744494298     PISSN: 00220345     EISSN: None     Source Type: Journal    
DOI: 10.1177/154405910608500505     Document Type: Article

References (18)

1. Bedran-de-Castro AK, Pereira PN, Pimenta LA, Thompson JY (2004). Effect of thermal and mechanical load cycling on nanoleakage of Class II restorations. J Adhes Dent 6:221-226.
2. Brown HC, McDaniel DH, Häfliger O (1955). Dissociation constants. In: Determination of organic structures by physical methods. Braude, EA, Nachod FC, eds. New York: Academic Press, pp. 567-589.
3. Carvalho RM, Chersoni S, Frankenberger R, Pashley DH, Prati C, Tay FR (2005). A challenge to the conventional wisdom that simultaneous etching and resin infiltration always occur in self-etch adhesives. Biomaterials 26:1035-1042.
4. Fujisawa S, Ito S (1999). 1H-NMR studies of the interaction of dental adhesive monomer, 4-META with calcium. Dent Mater J 18:54-62.
5. Fujita K, Nishiyama N (2006a). 13C NMR analysis of the etching efficacy of acidic monomers in self-etching primers. J Dent 34:123-133.
6. Fujita K, Nishiyama N (2006b). Alteration mechanisms and effects on self-etching primers effectuated by the primer's storage period. Am J Dent (in press).
7. Kazantsev OA, Shirshin KV, Sivokhin AP, Tel'nov SV, Zhiganov IV, Kuznetsov AE, et al. (2003). Hydrolysis of 2-hydroxyethyl methacrylate in concentrated aqueous solutions. Russian J Appl Chem 76:1296-1298.
8. Li H, Burrow MF, Tyas MJ (2003). The effect of concentration and pH of silver nitrate solution on nanoleakage. J Adhes Dent 5:19-25.
9. Moszner N, Zeuner F, Fischer UK, Rheinberger V (1999). Monomers for adhesive polymers, 2. Synthesis and radical polymerization of hydrolytically stable acrylic phosphonic acids. Macromol Chem Phy 200:1062-1067.
10. Moszner N, Zeuner F, Angermann J, Fischer UK, Rheinberger V (2003). Monomers for adhesive polymers, 4. Macromol Mater Eng 288:621-628.
11. Moszner N, Salz U, Zimmermann J (2005). Chemical aspects of self-etching enamel-dentin adhesives: a systematic review. Dent Mater 21:895-910.
12. Nishiyama N, Suzuki K, Yoshida H, Teshima H, Nemoto K (2004). Hydrolytic stability of methacrylamide in acidic aqueous solution. Biomaterials 25:965-969.
13. Okazaki K (2000). A study of light-cured resins, influence of storage temperature of adhesive system on bond strength to bovine dentin. Jpn J Conserv Dent 43:1187-1196 (in Japanese).
14. Salz U, Zimmermann J, Zeuner F, Moszner N (2005). Hydrolytic stability of self-etching adhesive systems. J Adhes Dent 7:107-116.
15. Shono Y, Ogawa T, Terashita M, Carvalho RM, Pashley EL, Pashley DH (1999). Regional measurement of resin-dentin bonding as an array. J Dent Res 78:699-705.
16. Tay FR, Pashley DH (2003). Have dentin adhesives become too hydrophilic? J Can Dent Assoc 69:726-731.
17. Tay FR, Moulding KM, Pashley DH (1999). Distribution of nanofillers from a simplified-step adhesive in acid-conditioned dentin. J Adhes Dent 1:103-117.
18. Tay FR, Pashley DH, Yoshiyama M (2002). Two modes of nanoleakage expression in single-step adhesives. J Dent Res 81:472-476.