Measurement and correlation of the thermal conductivity of pentafluoroethane (R125) from 190 K to 512 K at pressures to 70 MPa

Journal of Chemical and Engineering Data

Volumn 51, Issue 3, 2006, Pages 898-904

  Perkins, Richard A ^a   Huber, Marcia L ^a  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DILUTE GAS; PENTAFLUOROETHANE (R125); PRIMARY DATA SETS;

CORRELATION THEORY; THERMAL CONDUCTIVITY; UNCERTAIN SYSTEMS; VAPOR PRESSURE;

AROMATIC COMPOUNDS;

EID: 33744494070     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je050372t     Document Type: Article

References (39)

1. Perkins, R. A.; Roder, H. M.; Nieto de Castro, C. A. A high-temperature transient hot-wire thermal conductivity apparatus for fluids. J. Res. Natl. Inst. Stand. Technol. 1991, 96, 247-269.
2. Roder, H. M. A transient hot wire thermal conductivity apparatus for fluids. J. Res. Natl. Bur. Stand. 1981, 86, 457-493.
3. Healy, J.; DeGroot, J. J.; Kestin, J. The theory of the transient hot-wire method for measuring the thermal conductivity. Physica 1976, C82, 392-408.
4. Assael, M. J.; Karagiannidis, L.; Richardson, S. M.; Wakeham, W. A. Compression work using the transient hot-wire method. Int. J. Thermophys. 1992, 13, 223-235.
5. Taxis, B.; Stephan, K. The measurement of the thermal conductivity of gases at low density by the transient hot-wire technique. High Temp.-High Pressures 1994, 15, 141-153.
6. Li, S. F. Y.; Papadaki, M.; Wakeham, W. A. The measurement of the thermal conductivity of gases at low density by the transient hot-wire technique. High Temp.-High Pressures 1993, 25, 451-458.
7. Li, S. F. Y.; Papadaki, M.; Wakeham, W. A. Thermal conductivity of low-density polyatomic gases. In Thermal Conductivity 22; Tong, T. W., Ed.; Technomic Publishing: Lancaster, PA, 1994; pp 531-542.
8. Cabral, B. J. C.; Guedes, R. C.; Pai-Panandiker, R. S.; Nieto de Castro, C. A. Hydrogen bonding and internal rotation of hydrofluorocarbons by density functional theory. Phys. Chem. Chem. Phys. 2001, 3 (19), 4200-4207.
9. Perkins, R. A.; Laesecke, A.; Nieto de Castro, C. A. Polarized transient hot wire thermal conductivity measurements. Fluid Phase Equilib. 1992, 80, 275-286.
10. Lemmon, E. W.; Jacobsen, R. T. A new functional form and new fitting techniques for equations of state with application to pentafluoroethane (HFC-125). J. Phys. Chem. Ref. Data 2005, 34, 69-108.
11. Perkins, R. A. Measurement and correlation of the thermal conductivity of isobutane from 114 K to 600 K at pressures to 70 MPa. J. Phys. Chem. Ref. Data 2002, 47 (5), 1272-1279.
12. Perkins, R. A.; Ramires, M. L. V.; de Castro, C. A. N.; Cusco, L. Measurement and correlation of the thermal conductivity of butane from 135 K to 600 K at pressures to 70 MPa. J. Chem. Eng. Data 2002, 47(5), 1263-1271.
13. Marsh, K. N.; Perkins, R. A.; Ramires, M. L. V. Measurement and correlation of the thermal conductivity of propane from 86 to 600 K at pressures to 70 MPa. J. Chem. Eng. Data 2002, 47 (4), 932-940.
14. Huber, M. L.; Laesecke, A.; Perkins, R. A. Transport properties of n-dodecane. Energy Fuels 2004, 18, 968-975.
15. Olchowy, G. A.; Sengers, J. V. Crossover from regular to singular behavior of the transport properties of fluids in the critical region. Phys. Rev. Lett. 1988, 61, 15-18.
16. Olchowy, G. A.; Sengers, J. V. A simplified representation for the thermal conductivity of fluids in the critical region. Int. J. Thermophys. 1989, 10 (2), 417-426.
17. Krauss, R.; Weiss, V. C.; Edison, T. A.; Sengers, J. V.; Stephan, K. Transport properties of 1,1-difluoroethane (R152a). Int. J. Thermophys. 1996, 17(4), 731-757.
18. Huber, M. L.; Laesecke, A. Correlation for the viscosity of pentafluoroethane (R125) from the triple point to 500 K at pressures up to 60 MPa. Ind. Eng. Chem. Res. In press.
19. Asambaev, A. Z. Thermal conductivity of liquid and gaseous freons and their mixtures. Ph.D. Thesis, St. Petersburg, USSR, 1992.
20. Assael, M. J.; Malamataris, N.; Karagiannidis, L. Measurements of the thermal conductivity of refrigerants in the vapor phase. Int. J. Thermophys. 1997, 18 (2), 341-352.
21. Assael, M. J.; Karagiannidis, L. Measurements of the thermal-conductivity of liquid R32, R124, R125, and R141b. Int. J. Thermophys. 1995, 16 (4), 851-865.
22. Bivens, D. B.; Yokozeki, A.; Geller, V. Z.; Paulaitis, M. E. In Transport Properties and Heat Transfer of Alternatives for R502 and R22; ASHRAE/NIST Refrigerants Conference, Gaithersburg, MD, August 19-20, 1993; ASHRAE: Gaithersburg, MD, 1993; pp 73-84.
23. Fellows, B. R.; Richard, R. G.; Shankland, I. R. In Thermal Conductivity Data for Some Environmentally Acceptable Fluorocarbons; Cremers, C. J., Fine, H. A., Eds.; Thermal Conductivity 21; Plenum Press: New York, 1990; pp 311-325.
24. Shankland, I. R. Transport properties of CFC alternatives. Presented at the AIChE Spring National Meeting, Orlando, FL, 1990.
25. Gao, X.; Yamada, T.; Nagasaka, Y.; Nagashima, A. The thermal conductivity of CFC alternatives HFC-125 and HCFC-141b in the liquid phase. Int. J. Thermophys. 1996, 17 (2), 279-292.
26. Grebenkov, A. J.; Kotelevsky, Y. G.; Saplitza, V. V.; Beljaeva, O. V.; Zajatz, T. A.; Timofeev, B. D. In Experimental Study of Thermal Conductivity of Some Ozone Safe Refrigerants and Speed of Sound in their Liquid Phase, CFCs: The Day After; Joint Meeting of IIR Commissions B1, B2, E1, and E2, Padova, Italy, September 21-23, 1994; IIR: Padova, Italy, 1994; pp 419-429.
27. Gross, U.; Song, Y. W. Thermal conductivities of new refrigerants R125 and R32 measured by the transient hot-wire method. Int. J. Thermophys. 1996, 17 (3), 607-619.
28. Ro, S. T.; Kim, M. S.; Jeong, S. U. Liquid thermal conductivity of binary mixtures of difluoromethane (R32) and pentafluoroethane (R125). Int. J. Thermophys. 1997, 18 (4), 991-999.
29. Kraft, K.; Leipertz, A. Thermal diffusivity and ultrasonic velocity of saturated R125. Int. J. Thermophys. 1994, 15 (3), 387-399.
30. Le Neindre, B.; Garrabos, Y. Measurements of the thermal conductivity of HFC-125 in the temperature range from 300 to 515 K and at pressures up to 53 MPa. Int. J. Thermophys. 1999, 20 (5), 375-399.
31. Papadaki, M.; Wakeham, W. A. Thermal-conductivity of R32 and R125 in the liquid-phase at the saturation vapor-pressure. Int. J. Thermophys. 1993, 14 (6), 1215-1220.
32. Pitschmann, M.; Straub, J. The thermal diffusivity of refrigerants R32, R125, and R143a. Int. J. Thermophys. 2002, 23 (4), 877-904.
33. Sun, L.-Q.; Zhu, M.-S.; Han, L.-Z.; Lin, Z.-Z. Thermal conductivity of gaseous difluoromethane and pentafluoroethane near the saturation line. J. Chem. Eng. Data 1997, 42 (1), 179-182.
34. Tanaka, Y.; Matsuo, S.; Taya, S. Gaseous thermal conductivity of difluoromethane (HFC-32), pentafluoroethane (HFC-125), and their mixtures. Int. J. Thermophys. 1995, 16 (1), 121-131.
35. Tsvetkov, O. B.; Laptev, Y. A.; Asambaev, A. G. Thermal conductivity of refrigerants R123, R134a, and R125 at low-temperatures. Int. J. Thermophys. 1994, 15 (2), 203-214.
36. Tsvetkov, O. B.; Kletski, A. V.; Laptev, Y. A.; Asambaev, A. J.; Zausaev, I. A. Thermal conductivity and PVT measurements of pentafluorethane (refrigerant HFC-125). Int. J. Thermophys. 1995, 16 (5), 1185-1192.
37. Wilson, L. C.; Wilding, W. V.; Wilson, G. M.; Rowley, R. L.; Felix, V. M.; Chisolm-Carter, T. Thermophysical properties of HFC-125. Fluid Phase Equilib. 1992, 80, 167-177.
38. Yata, J.; Hori, M.; Kobayashi, K.; Minamiyama, T. Thermal conductivity of alternative refrigerants in the liquid phase. Int. J. Thermophys. 1996, 17(3), 561-571.
39. Boggs, P. T.; Byrd, R. H.; Rogers, J. E.; Schnabel, R. B. ODRPACK, Software for Orthogonal Distance Regression; NISTIR 4834; National Institute of Standards and Technology: Gaithersburg, MD, 1992.