Preparation and properties of RMgN< compounds having coordinating oxygen atoms in the amino component

Organometallics

Volumn 25, Issue 10, 2006, Pages 2465-2469

  Squiller, Edward P ^a   Pajerski, Anthony D ^a   Whittle, Robert R ^b   Richey Jr , Herman G ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

^b AAIPharma Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACCIDENTAL COMPONENTS; BENZENE SOLUTIONS; DIMERIC STRUCTURES; FOUR-MEMBERED RINGS; NEOPENTYLS;

AMINO ACIDS; ATOMS; BENZENE; CRYSTAL STRUCTURE; DIMERS; MOLECULAR WEIGHT; ORGANIC SOLVENTS; OXYGEN;

MAGNESIUM COMPOUNDS;

EID: 33744457054     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om058057n     Document Type: Article

References (31)

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2. Lindsell, W. E. In Comprehensive Organometallic Chemistry 11; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 1, Chapter 3.
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4. 1 now includes information from EXAFS and LAXS techniques: Ertel, T. S.; Bertagnolli, H. In Grignard Reagents: New Developments; Richey, H. G., Jr., Ed.; Wiley: Chichester, 2000; Chapter 10.
5. Examples are listed in ref 2.
6. This differs from extensive studies in which coordinating groups are part of the R group of the organomagnesium compound. Gruter, G.-J. M.; van Klink, G. P. M,; Akkerman, O. S.; Bickelhaupt, F. Chem. Rev. 1995, 95, 2405.
7. Some data are given in the Supporting Information.
8. 2Mg.
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10. 6
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23. 2Mg vapor.
24. The plot of peak intensities versus time indicated the presence of another component that began to distill from the probe within 2 min and reached a maximum at ca. 13 min. The highest significant mass peak was m/e 288, consistent with this component being 1-Mg-1.
25. 2Mg.
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