Synthesis and structure of K3Mg20In14, a stuffed variant of the BaHg11 structure type with a magnesium-indium network

Inorganic Chemistry

Volumn 45, Issue 10, 2006, Pages 3861-3863

  Li, Bin ^a   Corbett, John D ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33646945941     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060215v     Document Type: Article

References (41)

1. (a) Corbett, J. D. In Chemistry, Structure and Bonding of Zintl Phases and Ions; Kauzlarich, S., Ed.; VCH Publishers: New York, 1996; Chapter 3.
2. (b) Corbett, J. D. Angew. Chem., Int. Ed. 2000, 39, 670.
3. (c) Belin, C. H. E.; Charbonnel, M. Prog. Solid State Chem. 1993, 22, 59.
4. Dong, Z.-C.; Corbett, J. D. J. Am. Chem. Soc. 1994, 116, 3429.
5. Sevov, S. C.; Corbett, J. D. Inorg. Chem. 1993, 23, 1612.
6. Dong, Z.-C.; Corbett, J. D. J. Am. Chem. Soc. 1995, 117, 6447.
7. Li, B.; Corbett, J. D. Inorg. Chem. 2002, 41, 3944.
8. (a) Seo, D.-K.; Corbett, J. D. J. Am. Chem. Soc. 2000, 122, 9621.
9. (b) Seo, D.-K.; Corbett, J. D. J. Am. Chem. Soc. 2001, 123, 4512.
10. Bobev, S.; Sevov, S. C. Inorg. Chem. 2001, 40, 5361.
11. Elding-Ponten, M.; Lidin, S. J. Solid State Chem. 1995, 115, 270.
12. Chi, L.-S.; Corbett, J. D. J. Solid State Chem. 2001, 162, 327.
13. Lee, C.-S.; Miller, G. Inorg. Chem. 2001, 40, 338.
14. Nesper, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 58.
15. Li, B.; Corbett, J. D., manuscript in preparation.
16. Li, B.; Corbett, J. D. Inorg. Chem. 2006, 45, 156.
17. Li, B.; Corbett, J. D. J. Am. Chem Soc. 2005, 127, 926.
18. 14 (by powder pattern) was synthesized from stoichiometric amounts of the elements in a Ta container, which was sealed by are-welding under Ar and enclosed in an evacuated silica tube. The samples were allowed to react at 500°C for 6 h, slowly cooled (3°C/h) to 350°C, held for 10 days, and then slowly cooled (3°C/h) to room temperature. The compound has a metallic luster and is air-sensitive.
19. 19 The full-matrix least-squares refinement converged at R1/wR2 [I > 2σ(I)] = 0.0267/0.0790 and R1/wR2 (all data) = 0.0322/0.0812 with 303 reflections and 17 variables (see the Supporting Information).
20. (a) IPDS II; Stoe and Cie Gmbh: Darmstadt, Germany, 2002.
21. (b) XSHAPE, Crystal Optimization for Numerical Absorption Correction, revision 2.03; Stoe and Cie Gmbh: Darmstadt, Germany, 2003.
22. STOE WinXPOW 2.10; Stoe and Cie GmbH: Darmstadt, Germany, 2004.
23. SHELXTL; Bruker AXS, Inc.: Madison, WI, 2000.
24. Lin, Q.-S.; Corbett, J. D. Inorg. Chem. 2003, 42, 8762.
25. Lin, Q.-S.; Corbett, J. D. Inorg. Chem. 2005, 44, 512.
26. Teslyuk, M. Y.; Krypyakevich, P. I. Dopov. Akad. Nauk Ukr: RSR 1961, 8, 1039.
27. Peyronel, G. Gazz. Chim. Ital. 1952, 82, 679.
28. Latturner, S. E.; Kanatzidis, M. G. Inorg. Chem. 2004, 43, 2.
29. Gladyshevskii, R. E.; Cenzual, K. J. Alloys Compd. 1996, 240, 266.
30. 28
31. van Schilfgarde, M.; Paxton, T. A.; Jepsen, O.; Andersen, O. K.; Krier, G. Program TB-LMTO; Max-Plank-Institut fur Festkorperforschung: Stuttgart, Germany, 1994.
32. Jepsen, O.; Andersen, O. K. Z. Phys. B 1995, 97, 35.
33. 298 value is about 32.5 μΩ·cm (see the Supporting Information).
34. Zhao, J. T.; Corbett, J. D. Inorg. Chem. 1995, 34, 378.
35. 32b
36. (a) Ren, J.; Liang, W.; Whangbo, M.-H. CAESAR for Windows; Prime-Color Software, Inc., North Carolina State University: Raleigh, NC, 1998.
37. (b) Canadell, E.; Eisenstein, O.; Rubio, J. Organometallics 1984, 3, 759.
38. Samson, S. Acta Chem. Scand. 1949, 3, 835.
39. Lin, Q. S.; Li, B.; Corbett, J. D., unpublished results.
40. Samson, S. Acta Chem. Scand. 1949, 3, 809.
41. Lee, C.-S.; Miller, G. J. J. Am. Chem. Soc. 2000, 122, 4937.