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Because the DSC measurements were carried out in the range of -65 to 60°C, only the glass-transition temperature corresponding to the poly (SOC1) segment (-59°C) could be detected. The glass-transition temperature corresponding to the poly(OX) segment (-71°C), which was reported by Perez et al. (Polym Bull 1988, 20, 291), could not be detected.
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33646865826
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-
note
-
A plausible initiating species is a proton contained in BF3OEt2 or produced during the initial oligomerization process (see ref. 9). Because the initiation efficiency is constant, the lower initiation efficiency can be ascribed to neither the impurities in the solvent or SOC1 nor the protons on glassware.
-
-
-
-
28
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33646891418
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note
-
The observed pseudo-first-order polymerization rate constant (kobs) was calculated according to -d[M]/dt = k[P*][M] = kobs[M], where [P*] is the concentration of the propagating end and [M] is the concentration of the monomer.
-
-
-
-
29
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33646895550
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note
-
There is a possibility that some of the precursor, poly(OX), is still present in the copolymer (trace b). However, because of the small change in the molecular weight distribution during the copolymerization, the amount of poly(OX) is considered to be small. Therefore, the properties of the obtained copolymers might not be affected so much by the remaining poly(OX).
-
-
-
-
30
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33646869810
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note
-
The fact that the copolymer compositions are 54:46 and 57:43 for the pseudo block and triblock copolymers, respectively, whereas the feed ratio is 50:50, can be ascribed to the formation of the oligomers of OX in the early stages of the copolymerization. Because the oligomers can be removed by precipitation with hexane, the resulting copolymers do not include the oligomers.
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0027113171
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